WEBVTT - TechStuff Classic: How Hydrogen Fuel Works: Part One

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<v Speaker 1>Welcome to tech Stuff, a production from my Heart Radio.

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<v Speaker 1>Hey there, and welcome to tech Stuff. I am your host,

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<v Speaker 1>Jonathan Strickland. I'm an executive producer with I Heart Radio

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<v Speaker 1>and I love all things tech. It is time for

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<v Speaker 1>a classic episode of tech Stuff. This episode originally published

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<v Speaker 1>April twenty third, two thousand fourteen. It is titled How

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<v Speaker 1>Hydrogen Fuel Works, Part one. Yep, this was back when

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<v Speaker 1>we would say part one or part two in our episodes,

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<v Speaker 1>and I don't really do that anymore now. I give

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<v Speaker 1>each episode a different title. But yes, as the title reveals,

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<v Speaker 1>this is the first half of a two parter about

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<v Speaker 1>hydrogen fuel. Fascinating stuff. And you know, there were a

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<v Speaker 1>lot of people who were predicting a hydrogen fuel based

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<v Speaker 1>economy probably about two decades ago, and we're still not

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<v Speaker 1>there yet. So we're gonna learn more about this fuel

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<v Speaker 1>source and what it is and how it works and

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<v Speaker 1>why we don't actually have hydrogen fuel fueling everything these days.

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<v Speaker 1>So let's take a listen. We're going to describe everything

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<v Speaker 1>about hydrogen and how it's being used in multiple ways. Yeah,

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<v Speaker 1>because hydrogen is a really simple element with a huge

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<v Speaker 1>amount of potential. Simplest element in the universe one proton,

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<v Speaker 1>one electron. That is it, get yourself a proton, get

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<v Speaker 1>yourself electron and let them make friends. You've got a hydrogen.

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<v Speaker 1>So it's also the most abundant element in the universe.

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<v Speaker 1>It's it's everywhere. This is the stuff that the Sun

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<v Speaker 1>fuses into helium at a temperature of millions of degrees. Yeah,

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<v Speaker 1>we have had to put that in there. Uh yeah,

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<v Speaker 1>so so it's technically fueling well everything, I suppose once

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<v Speaker 1>you've got it working in the sun. Yeah. Yeah, pretty

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<v Speaker 1>much everything on Earth, life as we know it exists

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<v Speaker 1>because of hydrogen being built into helium in the sun.

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<v Speaker 1>There are some exceptions, like you could look at some

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<v Speaker 1>extreme of files in Earth where they're living off chemicals

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<v Speaker 1>that are being produced by the gases and things being

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<v Speaker 1>released in deep undersea fissures. But most of life, the

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<v Speaker 1>vast majority of it, depends at least in some part

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<v Speaker 1>on light. Yes, and hydrogen. Although we have only known

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<v Speaker 1>about its existence as an element for a relatively short

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<v Speaker 1>period of time, has has been kind of theorized about. Yeah,

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<v Speaker 1>there's been people who have worked with what they called

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<v Speaker 1>like they had various words for it, inflammable air, being

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<v Speaker 1>a popular one because they realized, hey, there's the stuff

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<v Speaker 1>that when you do things to other things happens. And

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<v Speaker 1>then if you put a fire near it, it blows up, right,

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<v Speaker 1>inflammable meaning inflammable meaning inflammable, Yes, exactly able to be

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<v Speaker 1>set fire to. Right, And in this case, it's not

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<v Speaker 1>just that it burns, it's exclusive. So the word hydrogen's

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<v Speaker 1>actually combination of two words from Greek hydro and genus,

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<v Speaker 1>which together mean water forming. And once you know about

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<v Speaker 1>hydrogen and you know what water is, it's H two O.

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<v Speaker 1>Makes perfect sense. You've gotta have hydrogen or you don't

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<v Speaker 1>have water. Of course, if you don't have oxygen, you

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<v Speaker 1>still don't have water. And while this hydrogen stuff is everywhere,

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<v Speaker 1>I mean, it's the most abundant element in the universe,

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<v Speaker 1>it isn't often found on it's lonesome. That's because it

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<v Speaker 1>makes friends really easily. Yeah, it's it's kind of like

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<v Speaker 1>the opposite of me. It actually gets real buddy buddy

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<v Speaker 1>really fast, and and and the buddies like it. See

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<v Speaker 1>I got half that equation. But anyway, hydrogen forms compounds readily, right,

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<v Speaker 1>you get compounds and all sorts of stuff. You get

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<v Speaker 1>water being a big example at hydrogen bonds with oxygen.

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<v Speaker 1>You have water, you have lots of hydrocarbons, you've got um.

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<v Speaker 1>You even have occlusion, which is molecular condensation inside igneous rocks.

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<v Speaker 1>The point is is that it's bound up with other stuff.

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<v Speaker 1>It's not just out there its own. So if we

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<v Speaker 1>want to harvest hydrogen to use as fuel, you gotta

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<v Speaker 1>think a little outside the box. You can't just go

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<v Speaker 1>to the hydrogen store by it. Yeah, it doesn't grow

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<v Speaker 1>on any hydrogen trees. Now you have to you have

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<v Speaker 1>to do something to something else generally in order to

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<v Speaker 1>get some of it exactly, which means you've got to

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<v Speaker 1>expend energy in order to get this fuel. And that's

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<v Speaker 1>one of the things that's really important about any sort

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<v Speaker 1>of fuel. It's not just hydrogen. We're talking about any

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<v Speaker 1>kind of fuel where you're planning on getting energy out.

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<v Speaker 1>If it requires you to put more energy into it

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<v Speaker 1>to get the fuel, then you're getting as a benefit

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<v Speaker 1>of the fuel. Is a losing proposition, right. Although there

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<v Speaker 1>are lots of different ways to to produce hydrogen um.

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<v Speaker 1>You can use light to split water molecules, you can

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<v Speaker 1>gasify biomass waste, you can even just kind of let

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<v Speaker 1>a bunch of microbes do the work for you as

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<v Speaker 1>part of their normal metabolism. Um. But one of the

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<v Speaker 1>most popular ones right now anyway, what accounts for about

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<v Speaker 1>of the hydrogen in the United States is something called performing,

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<v Speaker 1>in which a carbon based fuels like natural gas typically methane,

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<v Speaker 1>are reacted with steam at high pressures and temperatures. That

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<v Speaker 1>produces hydrogen, a little bit of carbon dioxide and carbon monoxide,

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<v Speaker 1>that last of which is then reacted to produce more

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<v Speaker 1>hydrogen and carbon dioxide. UM. You will note that that

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<v Speaker 1>both of these do produce greenhouse gases, so it's a

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<v Speaker 1>little bit less friendly than something like electrolysis, although you

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<v Speaker 1>have to pump a whole lot of energy into electrolysis.

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<v Speaker 1>We'll talk a little bit more about that later. Overall,

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<v Speaker 1>reforming does have the potential to overall reduce our carbon

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<v Speaker 1>footprint if it could provide the hydrogen for like a

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<v Speaker 1>whole fleet of fuel cell vehicles. Right That's one of

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<v Speaker 1>the big things about hydrogen. We'll talk about that in

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<v Speaker 1>just a second, about how it does not give off

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<v Speaker 1>greenhouse gases in ideal cases. Uh, keep in mind we're

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<v Speaker 1>talking ideal cases because it all depends on how you're

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<v Speaker 1>using the hydrogen. So, uh yeah. I also read that

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<v Speaker 1>there have been some studies of algae that give off hydrogen, which,

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<v Speaker 1>you know, if we were ever able to make an

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<v Speaker 1>algae farm that was efficient enough, that would be a

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<v Speaker 1>great way. But there are a lot of people who

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<v Speaker 1>question whether or that that's practical. It may not ever

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<v Speaker 1>be something that generates enough hydrogen for it to be

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<v Speaker 1>worth the amount of effort it would take. Again that

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<v Speaker 1>sort of energy losing proposition night. So some other things

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<v Speaker 1>about hydrogen. It has a low ignition energy. That means

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<v Speaker 1>you don't have to apply a lot of energy to

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<v Speaker 1>it to get it to ignite. That makes sense, you know,

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<v Speaker 1>it doesn't take much to set it on fire, essentially,

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<v Speaker 1>is what we're talking about here. It actually requires an

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<v Speaker 1>order of magnitude less energy to ignite hydrogen than it

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<v Speaker 1>does to ignite gasoline. Yeah, so that means that gasoline

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<v Speaker 1>is pretty pretty flammable, pretty or inflammable. Yeah. Kids, let's

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<v Speaker 1>not play with the stuff at home, shall we, or

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<v Speaker 1>anywhere else for that matter. Let's treat it like serious business.

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<v Speaker 1>But it's both a good and bad thing, right because

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<v Speaker 1>the hydrogen stance it's easy to ignite, means that you

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<v Speaker 1>can easily implement that in an engine. Uh does it

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<v Speaker 1>very efficiently. You don't have to spend a lot of

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<v Speaker 1>energy to make it do what you wanted to do.

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<v Speaker 1>On the other hand, because it has such a low

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<v Speaker 1>ignition point, it's also a challenge engineering wise, because if

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<v Speaker 1>your engine gets hot enough, the engine itself could cause

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<v Speaker 1>the hydrogen to ignite prematurely before it gets into the

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<v Speaker 1>operative fits right, and then it could make everything inoperative.

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<v Speaker 1>You would get an operative right quick. So that's you

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<v Speaker 1>know that there's a there's a good and bad side

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<v Speaker 1>of this. If you can engineer your way around it,

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<v Speaker 1>it can eventually be a benefit. Oh sure, it technically

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<v Speaker 1>has the highest energy output by weight of any fuel

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<v Speaker 1>um though it is the lightest elements, so that's kind

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<v Speaker 1>of yeah. You kind of have to get a lot

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<v Speaker 1>of it together too. So it's because it's it's not dense,

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<v Speaker 1>you know, which is something else will chat about. So

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<v Speaker 1>one of the reasons why we're even talking about hydrogen,

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<v Speaker 1>one of the big ones, it's what we alluded to earlier,

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<v Speaker 1>is the fact that the combustion is really clean, particularly

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<v Speaker 1>if you're using hydrogen and pure oxygen as the mixture

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<v Speaker 1>that goes into your engine, right, because then your output

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<v Speaker 1>is going to be just energy and water. Yep. You

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<v Speaker 1>get energy in the form of the power that you

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<v Speaker 1>generate and some heat because of course we don't have

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<v Speaker 1>any perfect systems where we don't lose some energy in

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<v Speaker 1>the form of heat. But yeah, the only other thing

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<v Speaker 1>you get is water. You don't get anything else. And

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<v Speaker 1>this is when I when I talk about mixtures. We'll

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<v Speaker 1>talk about combustion engines a little later too. This is

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<v Speaker 1>a typical thing where you mix together some fuel and

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<v Speaker 1>some air to go into a combustion engine. Same sort

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<v Speaker 1>of thing with hydrogen. You're not putting just pure hydrogen

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<v Speaker 1>and you're mixing it with some form of air, in

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<v Speaker 1>this case oxygen. However, that being said, most hydrogen combustion

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<v Speaker 1>engines are not using pure oxygen to mix together to

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<v Speaker 1>make the combustible mixture. They're using air. So air has

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<v Speaker 1>stuff in it besides oxygen. In fact, the primary component

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<v Speaker 1>of our atmosphere is not oxygen, it's nitrogen. So one

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<v Speaker 1>of the byproducts you get with using a hydrogen combustion

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<v Speaker 1>engine that uses air is that you get some nitrous oxides,

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<v Speaker 1>nitrogen oxides, I should say, not nitrous oxides, which would

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<v Speaker 1>be hilarious until you suffocated, but nitrogen oxides. Uh, that's

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<v Speaker 1>a that's a pollutant. You don't want that. Um. And

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<v Speaker 1>you can also get carbon monoxide and carbon dioxide if

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<v Speaker 1>you get some oil seeping into the combustion chambers, because uh,

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<v Speaker 1>oxygen does. Our atmosphere doesn't have like tons of carbon

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<v Speaker 1>in it, but oil does. So there are chances of

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<v Speaker 1>having a hydrogen combustion engine this kind of pollutants. You

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<v Speaker 1>can get around that if you wanted to go with

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<v Speaker 1>fuel cells, and we'll talk about those two. We'll be

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<v Speaker 1>back with more discussion about hydrogen fuel in just a second,

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<v Speaker 1>but first let's take a quick break. So the amount

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<v Speaker 1>of power that hydrogen engine can generate is dependent upon

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<v Speaker 1>a few different things. It depends upon the mix of

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<v Speaker 1>air and fuel and how that fuel is injected into

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<v Speaker 1>those combustion chambers in your engine. So, theoretically, the maximum

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<v Speaker 1>output of a hydrogen based combustion engine using a pre

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<v Speaker 1>mixed method. This is where you have like a carburetor

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<v Speaker 1>type situation that is mixing air and fuel together and

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<v Speaker 1>then it goes into the combustion chamber. Uh. If you're

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<v Speaker 1>using that method, theoretically your maximum output is about eight

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<v Speaker 1>of the power generated in a comparable gasoline engine, So

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<v Speaker 1>not as powerful, right, But if you were to take

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<v Speaker 1>a direct injection approach, which mixes the fuel and air

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<v Speaker 1>after the intake valve in the combustion chamber closes, then

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<v Speaker 1>the hydrogen based engine can theoretically produce fift more power

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<v Speaker 1>than a gasoline engine. So you kind of have a

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<v Speaker 1>less in one way or pent more the other way. Um, However,

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<v Speaker 1>this is all based upon the idea that you're using

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<v Speaker 1>exactly the amount of air you need to complete combustion,

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<v Speaker 1>so you're using just the right mixture of air and

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<v Speaker 1>just the right mixture of hydrogen. But the downside of

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<v Speaker 1>that is that you also produce more pollutants that way. Right.

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<v Speaker 1>Although okay, so, so this is a complicated issue and

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<v Speaker 1>the numbers on it are always going to be rough.

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<v Speaker 1>But when you're talking about fuel efficiency, you you need

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<v Speaker 1>to use more gasoline in order to make an engine

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<v Speaker 1>do the same amount of work than you would hydrogen. Yeah, exactly,

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<v Speaker 1>Like you have this note about gasoline vehicles operating at

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<v Speaker 1>around efficiency. What that means is that of all the

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<v Speaker 1>energy that's being generated is actually going to doing the

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<v Speaker 1>thing you needed to do. The other is being lost

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<v Speaker 1>in some way or another. Sure, you usually due to

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<v Speaker 1>heat loss. That's the big one, especially with engines. I mean,

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<v Speaker 1>engines generate lots and lots of heat. The the ideal

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<v Speaker 1>of a fuel cell vehicle using hydrogen, it's closer to

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<v Speaker 1>six efficiency. For for the record, electric cars may manage

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<v Speaker 1>somewhere between twenty five and sixty fuel efficiency depending on

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<v Speaker 1>where you get the electricity to recharge that battery. Right,

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<v Speaker 1>and and if you want to be really technical, a

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<v Speaker 1>fuel cell vehicle is kind of a subset of electric vehicles.

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<v Speaker 1>It's just that it's an electric vehicle that you are

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<v Speaker 1>refueling with hydrogen rather than a closed battery system exactly. So, yeah,

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<v Speaker 1>it's a great point. And that's another thing that we

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<v Speaker 1>have to take into consideration. Now. Typically, if if we're

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<v Speaker 1>talking about you know, I just mentioned about having just

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<v Speaker 1>enough air and fuel to complete combustion, and you get

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<v Speaker 1>that that crazy hundred and fifteen percent of a gasoline

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<v Speaker 1>power engine, but you produce more more pollutants as well.

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<v Speaker 1>Usually we're not using exactly the amount of air because

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<v Speaker 1>we want to cut back on those pollutants. One of

0:12:47.400 --> 0:12:49.520
<v Speaker 1>the big reasons we want to use hydrogen is to

0:12:49.920 --> 0:12:52.559
<v Speaker 1>cut back on pollutants. So if we're producing more pollutants

0:12:52.559 --> 0:12:55.000
<v Speaker 1>by making it really efficient, then we're like, well, we

0:12:55.160 --> 0:12:57.000
<v Speaker 1>just kind of traded off. That was a lot of

0:12:57.000 --> 0:13:00.400
<v Speaker 1>money to not do any better exactly. So what we

0:13:00.600 --> 0:13:03.360
<v Speaker 1>tend to see our engines that use about twice as

0:13:03.440 --> 0:13:07.360
<v Speaker 1>much air as is actually required to complete combustion. Now,

0:13:07.360 --> 0:13:10.640
<v Speaker 1>this reduces pollution, but it also reduces the output of

0:13:10.679 --> 0:13:16.040
<v Speaker 1>the engine. Yeah, sad trombone. Okay, so these are just tradeoffs.

0:13:16.040 --> 0:13:17.600
<v Speaker 1>This is the way the real world works. We have

0:13:17.679 --> 0:13:19.520
<v Speaker 1>to sit there and say, Okay, there's not a magic

0:13:19.720 --> 0:13:23.040
<v Speaker 1>solution that is going to solve all the problems equally,

0:13:23.200 --> 0:13:25.320
<v Speaker 1>we have to start making tradeoffs. This is a pretty

0:13:25.360 --> 0:13:27.560
<v Speaker 1>good one because you can you can enlarge the engine

0:13:27.559 --> 0:13:30.280
<v Speaker 1>size and make up for a lot of it. Right,

0:13:30.320 --> 0:13:32.960
<v Speaker 1>So if you make the hydrogen based engine larger than

0:13:33.000 --> 0:13:35.600
<v Speaker 1>a gasoline based engine, you can kind of make up

0:13:35.640 --> 0:13:37.520
<v Speaker 1>this this loss. Now that does, of course, mean you

0:13:37.559 --> 0:13:40.200
<v Speaker 1>have to redesign vehicles around a larger engine. So I

0:13:40.200 --> 0:13:42.319
<v Speaker 1>mean it's you know, it's those domino effects, right. You

0:13:42.360 --> 0:13:45.719
<v Speaker 1>could also include what's called a turbo charger or supercharger,

0:13:45.720 --> 0:13:48.079
<v Speaker 1>and you might wonder, hey, how did those work. We'll

0:13:48.120 --> 0:13:51.200
<v Speaker 1>do another episode because it's already going to be a

0:13:51.200 --> 0:13:53.120
<v Speaker 1>long one for this one. So we can't. We can't

0:13:53.160 --> 0:13:55.600
<v Speaker 1>sit there and uh and jump into that and hope

0:13:55.600 --> 0:13:57.880
<v Speaker 1>to make it out alive, because no will kill us.

0:13:58.440 --> 0:14:01.839
<v Speaker 1>The protective barrier is only so strong. Okay. So, like

0:14:01.880 --> 0:14:05.520
<v Speaker 1>we said, hydrogen not very dense. When you've got one

0:14:05.559 --> 0:14:08.320
<v Speaker 1>proton and one electron, you don't expect it to be Nope,

0:14:08.600 --> 0:14:12.400
<v Speaker 1>So it's uh room temperature is a gas. Getting enough

0:14:12.480 --> 0:14:14.680
<v Speaker 1>hydrogen together in one place to be useful as a

0:14:14.720 --> 0:14:16.680
<v Speaker 1>fuel takes a lot of work, and some of the

0:14:16.679 --> 0:14:19.880
<v Speaker 1>easiest ways of storing it, like in extremely cold liquid form,

0:14:19.880 --> 0:14:23.080
<v Speaker 1>aren't really practical for toting around in a consumer motor

0:14:23.160 --> 0:14:26.240
<v Speaker 1>vehicle that might not want to incorporate a complex cooling

0:14:26.240 --> 0:14:30.720
<v Speaker 1>system due to you know, cost and weight and space issues.

0:14:30.760 --> 0:14:32.640
<v Speaker 1>So usually we end up having to figure out a

0:14:32.640 --> 0:14:36.840
<v Speaker 1>way of pressure rizing it under intense amounts of pressure. Now,

0:14:36.880 --> 0:14:39.720
<v Speaker 1>that of course creates another safety issue. Anytime you have

0:14:39.800 --> 0:14:42.160
<v Speaker 1>a compressed gas, it's under a lot of pressure. If

0:14:42.160 --> 0:14:46.040
<v Speaker 1>you rupture that containment unit in some way. Yeah. You

0:14:46.200 --> 0:14:48.280
<v Speaker 1>that's and then at on top of that that the

0:14:48.320 --> 0:14:51.800
<v Speaker 1>gas itself is inflammable, and you've got the potential for really,

0:14:52.240 --> 0:14:55.440
<v Speaker 1>really a bad day, Which is why a lot of

0:14:55.520 --> 0:14:58.040
<v Speaker 1>companies that have looked into using hydrogen as a fuel

0:14:58.120 --> 0:15:00.920
<v Speaker 1>in one way or another, whether as a bustin engine

0:15:01.000 --> 0:15:04.120
<v Speaker 1>fuel or whether as a fuel sell fuel, have put

0:15:04.120 --> 0:15:07.280
<v Speaker 1>in a lot of research and development in safety for

0:15:07.520 --> 0:15:10.560
<v Speaker 1>these hydrogen canisters or you know else. They will never

0:15:10.640 --> 0:15:12.440
<v Speaker 1>be able to market it because it would just be

0:15:12.480 --> 0:15:16.119
<v Speaker 1>too dangerous. Although some people argue that, I mean, gasoline

0:15:16.240 --> 0:15:18.960
<v Speaker 1>tanks being driven around are also that's a it's a

0:15:18.960 --> 0:15:21.040
<v Speaker 1>good point. It's a fair point. I mean, we're we've

0:15:21.080 --> 0:15:25.080
<v Speaker 1>been relying on a technology that has a an inflammable

0:15:25.160 --> 0:15:28.080
<v Speaker 1>fuel for more than a century. And you know, although

0:15:28.080 --> 0:15:30.320
<v Speaker 1>it's not quite as dangerous as movies make it out

0:15:30.320 --> 0:15:32.600
<v Speaker 1>to be. I mean, it's not that. Yeah where where

0:15:32.640 --> 0:15:35.760
<v Speaker 1>you you your car your car sways a bed and

0:15:35.800 --> 0:15:39.200
<v Speaker 1>then explodes. Y. Yeah, so if Michael Bay made cars,

0:15:39.320 --> 0:15:42.440
<v Speaker 1>no one would ever get in them. But fortunately, as

0:15:42.440 --> 0:15:45.160
<v Speaker 1>far as I know, he has not made one. Uh so,

0:15:45.360 --> 0:15:48.440
<v Speaker 1>uh yeah, We've we've been making use of this hydrogen

0:15:48.480 --> 0:15:51.720
<v Speaker 1>for a long time, and in fact, we, like Lauren said,

0:15:51.720 --> 0:15:53.560
<v Speaker 1>we were kind of playing with this stuff before we

0:15:53.600 --> 0:15:56.680
<v Speaker 1>even had any idea of what it was. We didn't

0:15:56.680 --> 0:16:01.080
<v Speaker 1>really know about elements or even gas is. So we're

0:16:01.080 --> 0:16:03.760
<v Speaker 1>gonna take you on a historical journey, and along this

0:16:03.840 --> 0:16:06.480
<v Speaker 1>journey will be explaining how some of this stuff works,

0:16:06.560 --> 0:16:09.640
<v Speaker 1>because we figured we'd kind of incorporate both the history

0:16:09.760 --> 0:16:14.800
<v Speaker 1>and the technical stuff altogether. It's an experiment. Now before

0:16:14.880 --> 0:16:17.320
<v Speaker 1>we jump into the way back machine, because I know

0:16:17.360 --> 0:16:19.800
<v Speaker 1>all you guys have been missing it, Laurence looking at

0:16:19.840 --> 0:16:22.160
<v Speaker 1>me terrified. Yeah, Lauren, that's what that big thing is

0:16:22.200 --> 0:16:24.320
<v Speaker 1>in the corner that we haven't been using. It's all

0:16:24.440 --> 0:16:27.640
<v Speaker 1>dusty and stuff. Turns out it wasn't in Mongolia. It

0:16:27.720 --> 0:16:31.040
<v Speaker 1>was just in a supply closet. Alright. Well, our our

0:16:31.080 --> 0:16:33.360
<v Speaker 1>fuel gauge is not on empty yet. We still got

0:16:33.400 --> 0:16:35.680
<v Speaker 1>a bit more to go, but first let's take another

0:16:35.760 --> 0:16:45.240
<v Speaker 1>quick break. Okay, So we're back and we're ready to

0:16:45.280 --> 0:16:47.520
<v Speaker 1>get into the way Back Machine, which I know is

0:16:47.560 --> 0:16:50.800
<v Speaker 1>going to sound absolutely amazing. I can't believe all the

0:16:50.800 --> 0:16:53.120
<v Speaker 1>bells and whistles that indicate to you that we've actually

0:16:53.160 --> 0:16:56.040
<v Speaker 1>traveled back in time. Because in truth, it's silent. But

0:16:56.160 --> 0:16:58.600
<v Speaker 1>we have to give you some you know, way of

0:16:58.640 --> 0:17:01.040
<v Speaker 1>knowing that that's what's happened. Otherwise it's not it's not

0:17:01.080 --> 0:17:03.840
<v Speaker 1>fun radio trauma exactly. So let's let's just go ahead

0:17:03.840 --> 0:17:06.280
<v Speaker 1>and get in now. Over here, we've got the dial

0:17:06.720 --> 0:17:10.320
<v Speaker 1>which I'm going to set back to uh early seventeenth century.

0:17:11.359 --> 0:17:13.679
<v Speaker 1>You know, I don't know how it knows where I

0:17:13.720 --> 0:17:16.879
<v Speaker 1>wanted to go. It just does. But when is really tricky.

0:17:16.880 --> 0:17:24.800
<v Speaker 1>All right, let's just hit the button. Here here we are.

0:17:26.880 --> 0:17:30.800
<v Speaker 1>It's a glorious and smelly So I want to introduce

0:17:30.840 --> 0:17:34.600
<v Speaker 1>you to Johann Baptista van Helmont, who is the first

0:17:34.640 --> 0:17:38.680
<v Speaker 1>person to describe hydrogen as a gas, and not only that,

0:17:38.880 --> 0:17:41.679
<v Speaker 1>he's the first person to come up with the word

0:17:42.240 --> 0:17:45.879
<v Speaker 1>gas to describe substances that have the qualities of a gas.

0:17:45.880 --> 0:17:48.440
<v Speaker 1>He was thinking of stuff that is heavier than air,

0:17:48.600 --> 0:17:50.719
<v Speaker 1>or misty, or he was just trying to come up

0:17:50.720 --> 0:17:54.600
<v Speaker 1>with like a collective noun to call this stuff. He

0:17:54.720 --> 0:17:58.720
<v Speaker 1>proposed gas, and it's stuck. So he goes on to

0:17:58.800 --> 0:18:01.280
<v Speaker 1>make some more observation which in a few decades get

0:18:01.280 --> 0:18:04.800
<v Speaker 1>picked up by another person of philosopher, A natural philosopher,

0:18:04.800 --> 0:18:06.919
<v Speaker 1>and we'll chat about him. His name is Robert Boyle.

0:18:07.520 --> 0:18:11.560
<v Speaker 1>So between Robert Boyle and Johan we have in sixteen

0:18:11.600 --> 0:18:15.719
<v Speaker 1>fifty Serteodor Turk with the men May yearn which I

0:18:15.760 --> 0:18:19.880
<v Speaker 1>know I've absolutely butchered based Swiss, so so I'm sure

0:18:19.880 --> 0:18:22.840
<v Speaker 1>he's fine with it. Yeah, They the Swiss have a

0:18:22.880 --> 0:18:28.280
<v Speaker 1>beautiful way with words that escapes the physical contortions my

0:18:28.280 --> 0:18:31.800
<v Speaker 1>mouth can go through. So, but he produced hydrogen and

0:18:31.840 --> 0:18:37.240
<v Speaker 1>he called it inflammable air by combining iron with sulfuric acid. Now,

0:18:37.640 --> 0:18:41.000
<v Speaker 1>hydrogen is found in a lot of different compounds, including

0:18:41.040 --> 0:18:43.840
<v Speaker 1>all the acids, So if you are able to combine

0:18:43.880 --> 0:18:46.720
<v Speaker 1>it with other stuff, usually that that reaction you get

0:18:46.960 --> 0:18:52.320
<v Speaker 1>by introducing an element into acid will release the hydrogen exactly. Now,

0:18:52.560 --> 0:18:55.439
<v Speaker 1>sixteen seventy one we get to that Irish philosopher I

0:18:55.480 --> 0:18:59.800
<v Speaker 1>had mentioned, Robert Boyle. Now he experimented with producing hydrogen

0:18:59.800 --> 0:19:02.439
<v Speaker 1>as well, and he was of the New philosophy movement.

0:19:03.000 --> 0:19:06.720
<v Speaker 1>This was a really interesting movement. It combined observations and

0:19:06.800 --> 0:19:10.480
<v Speaker 1>experimentation with logical thinking to understand the world around him.

0:19:10.520 --> 0:19:14.560
<v Speaker 1>So this is sort of a proto scientist movement. It's

0:19:14.600 --> 0:19:17.960
<v Speaker 1>before we really had the formal sciences. We this is

0:19:18.000 --> 0:19:22.560
<v Speaker 1>when alchemy was starting to transform into chemistry. Right. We

0:19:22.640 --> 0:19:26.680
<v Speaker 1>had people who had made observations and calculations on things

0:19:26.680 --> 0:19:29.600
<v Speaker 1>like physics, but it's now starting to actually take form

0:19:29.600 --> 0:19:32.439
<v Speaker 1>into the sciences as we know them today. So he

0:19:32.520 --> 0:19:36.800
<v Speaker 1>produced hydrogen by combining iron and various assets, and that's

0:19:36.920 --> 0:19:39.800
<v Speaker 1>how he started to take a look at this hydrogen gas.

0:19:39.800 --> 0:19:43.200
<v Speaker 1>And he was he was pretty pretty intelligent. He noticed

0:19:43.320 --> 0:19:48.560
<v Speaker 1>that a gas volume varies inversely with pressure, hence Boil's law. Yeah,

0:19:48.640 --> 0:19:52.000
<v Speaker 1>we named it after after him. He also believed in

0:19:52.160 --> 0:19:55.280
<v Speaker 1>alchemy and transmutation, so he didn't get everything right. You know,

0:19:56.119 --> 0:19:58.520
<v Speaker 1>lots of people today still believe in alchemy and transmutation,

0:19:58.680 --> 0:20:01.879
<v Speaker 1>so well, will leave that for now. But yes, Boil,

0:20:02.320 --> 0:20:04.000
<v Speaker 1>he did a lot of work, and a lot of

0:20:04.000 --> 0:20:07.840
<v Speaker 1>his work inspired other people. So over the next several decades,

0:20:08.440 --> 0:20:12.840
<v Speaker 1>lots of different philosophers and then later chemists and scientists

0:20:13.480 --> 0:20:17.280
<v Speaker 1>began to experiment with hydrogen gas. They didn't really give

0:20:17.320 --> 0:20:19.720
<v Speaker 1>it a name yet, but they knew that the stuff

0:20:19.760 --> 0:20:22.760
<v Speaker 1>would blow up if you exposed it to flame, so

0:20:23.080 --> 0:20:26.400
<v Speaker 1>they began to really study it further until we get

0:20:26.440 --> 0:20:29.480
<v Speaker 1>to seventeen sixty six, and now we get to go

0:20:29.520 --> 0:20:32.760
<v Speaker 1>to England, because that's where Henry Cavendish was and he

0:20:32.800 --> 0:20:35.960
<v Speaker 1>was the first to recognize hydrogen as a distinct substance.

0:20:36.640 --> 0:20:38.720
<v Speaker 1>And he was also the first to describe the composition

0:20:38.760 --> 0:20:41.840
<v Speaker 1>of water. You know, before that, everyone just said it's wet,

0:20:43.200 --> 0:20:46.159
<v Speaker 1>and if it gets cold, it gets hard. That's that

0:20:46.320 --> 0:20:48.280
<v Speaker 1>was pretty much it. If it gets really hot, it

0:20:48.359 --> 0:20:52.480
<v Speaker 1>gets cloudy, that's you know, just that's where we were

0:20:52.480 --> 0:20:55.280
<v Speaker 1>with science until Cavendish came along. I might be exaggerating

0:20:55.280 --> 0:21:00.000
<v Speaker 1>a little, but he absolutely loved learning for learning, saying

0:21:00.240 --> 0:21:03.160
<v Speaker 1>he wasn't actually a scientist per se though as he no,

0:21:03.280 --> 0:21:05.280
<v Speaker 1>not really, I mean he was. He was more like

0:21:05.440 --> 0:21:09.560
<v Speaker 1>just obsessed. He was one of the wealthiest men in

0:21:09.640 --> 0:21:13.439
<v Speaker 1>all of Europe. He had inherited a crazy sum of money,

0:21:14.000 --> 0:21:17.320
<v Speaker 1>and he chose to live very frugally in London. He

0:21:17.720 --> 0:21:21.120
<v Speaker 1>wasn't interested in the trappings of wealth. He wasn't interested

0:21:21.119 --> 0:21:25.000
<v Speaker 1>in ostentation. He was actually, according to one thing I read,

0:21:25.320 --> 0:21:27.720
<v Speaker 1>the only reason we even have a sketch of him

0:21:28.040 --> 0:21:31.879
<v Speaker 1>is because an artist surreptitiously drew one while at a gathering,

0:21:32.000 --> 0:21:35.040
<v Speaker 1>a small private gathering at his house because he didn't.

0:21:35.280 --> 0:21:37.600
<v Speaker 1>He didn't you know, want he didn't. He didn't sit

0:21:37.640 --> 0:21:40.840
<v Speaker 1>for a portrait. He was introvert, super introvert, and he

0:21:40.920 --> 0:21:44.119
<v Speaker 1>didn't really publish most of his work. He published some

0:21:44.240 --> 0:21:45.800
<v Speaker 1>of it, but not all of it, because he wasn't

0:21:45.840 --> 0:21:47.359
<v Speaker 1>really interested in that. He know, he just wanted to

0:21:47.359 --> 0:21:50.320
<v Speaker 1>know how the world works. He was just fascinated with learning.

0:21:50.520 --> 0:21:53.320
<v Speaker 1>He wasn't not necessarily as fascinated with teaching, but he

0:21:53.400 --> 0:21:55.959
<v Speaker 1>was definitely fascinated with learning. I want someone to make

0:21:56.000 --> 0:21:58.840
<v Speaker 1>a awkward action here a movie about this guy. Yeah.

0:21:58.960 --> 0:22:01.280
<v Speaker 1>I have a feeling that we have to invent a

0:22:01.359 --> 0:22:04.399
<v Speaker 1>lot of of facts about his life, which makes it

0:22:04.440 --> 0:22:07.720
<v Speaker 1>even better. Yeah, that's what movies generally do. Anyway, I'd

0:22:07.720 --> 0:22:10.159
<v Speaker 1>be less offended if I knew less about the history

0:22:10.160 --> 0:22:12.960
<v Speaker 1>of the actual guy. So yeah, I think Henry Cavendish

0:22:13.119 --> 0:22:15.720
<v Speaker 1>Supervillain would be an awesome movie. So I'll get to

0:22:15.720 --> 0:22:17.440
<v Speaker 1>work on that. Yes, all right, then we moved to

0:22:17.520 --> 0:22:21.240
<v Speaker 1>seventeen eighty three, when Jacques Charles makes his first light

0:22:21.320 --> 0:22:25.560
<v Speaker 1>in his balloon La Charliere, which used hydrogen as it's

0:22:25.640 --> 0:22:29.119
<v Speaker 1>a lifting agent because hydrogen is lighter than atmosphere. So

0:22:29.160 --> 0:22:32.280
<v Speaker 1>if you get enough of it together, the buoyancy will

0:22:32.359 --> 0:22:35.240
<v Speaker 1>counteract gravity and then you'll float right off the ground.

0:22:35.280 --> 0:22:38.240
<v Speaker 1>Go up. Yeah. Meanwhile, in eighteen hundred, William Nicholson and

0:22:38.280 --> 0:22:42.320
<v Speaker 1>Anthony Carlyle described the process of electrolysis, in which electricity

0:22:42.359 --> 0:22:44.680
<v Speaker 1>is applied to water to break its molecules down into

0:22:44.680 --> 0:22:49.680
<v Speaker 1>their constituents, being oxygen and hydrogen. This will become important later, yeah,

0:22:49.800 --> 0:22:53.040
<v Speaker 1>but just understanding that. Hey, this process where hydrogen and

0:22:53.040 --> 0:22:55.440
<v Speaker 1>oxygen gets together to make water is reversible if you

0:22:55.520 --> 0:22:58.720
<v Speaker 1>just pour energy into it. That's pretty cool. Eighteen or

0:22:58.760 --> 0:23:02.719
<v Speaker 1>six we have Francois Isaac de Rivaz, a Swiss inventor.

0:23:02.800 --> 0:23:05.679
<v Speaker 1>He built the de Revaz engine. And again I apologize

0:23:05.680 --> 0:23:09.080
<v Speaker 1>if I'm absolutely butchering that, but this was the first

0:23:09.119 --> 0:23:12.639
<v Speaker 1>internal combustion engine to use hydrogen and oxygen as a fuel.

0:23:13.000 --> 0:23:17.000
<v Speaker 1>It would be nearly sixty five years before you get

0:23:17.080 --> 0:23:20.399
<v Speaker 1>the first gas lean powered internal combustion engine. So actually,

0:23:20.480 --> 0:23:25.760
<v Speaker 1>hydrogen combustible engines predate gas, yeah by quite a bit.

0:23:26.119 --> 0:23:28.240
<v Speaker 1>So you know, we've talked a lot about how electric

0:23:28.280 --> 0:23:31.720
<v Speaker 1>cars are older than you think, so are hydrogen combustion

0:23:31.760 --> 0:23:34.639
<v Speaker 1>engine cars. So that's kind of cool. Then in eighteen

0:23:34.680 --> 0:23:38.159
<v Speaker 1>twenty we have the Reverend W. Cecil who writes a

0:23:38.280 --> 0:23:41.800
<v Speaker 1>paper and I love this title. Here we go on

0:23:41.880 --> 0:23:44.480
<v Speaker 1>the application of hydrogen gas to produce a moving power

0:23:44.480 --> 0:23:46.480
<v Speaker 1>and machinery with a description of an engine which is

0:23:46.520 --> 0:23:48.760
<v Speaker 1>moved by pressure of the atmosphere upon a vacuum caused

0:23:48.760 --> 0:23:52.560
<v Speaker 1>by explosions of hydrogen gas and atmospheric air. I think

0:23:52.560 --> 0:23:55.600
<v Speaker 1>it's a sinct pretty much. You've read the whole article

0:23:56.160 --> 0:23:59.960
<v Speaker 1>just by the title. But yeah, he proposed an engine

0:24:00.040 --> 0:24:04.840
<v Speaker 1>and using hydrogen as the combustible material. But it's a

0:24:04.880 --> 0:24:08.959
<v Speaker 1>different style of combustion engine than what we see today.

0:24:09.040 --> 0:24:13.440
<v Speaker 1>So his design involved having a chamber that you would

0:24:13.480 --> 0:24:17.240
<v Speaker 1>fill with hydrogen plus regular old air, and it would

0:24:17.200 --> 0:24:20.000
<v Speaker 1>be connected to a valve so that you could insert

0:24:20.119 --> 0:24:23.639
<v Speaker 1>this stuff but it wouldn't escape back out. Uh. And

0:24:23.680 --> 0:24:27.919
<v Speaker 1>then the you would put a flame in there, and

0:24:27.960 --> 0:24:30.440
<v Speaker 1>then you have the valve switched so it would allow

0:24:30.440 --> 0:24:32.679
<v Speaker 1>it to escape again. Right, you put the flame in.

0:24:32.720 --> 0:24:37.760
<v Speaker 1>This causes the gas to expand rapidly. Uh. And normally

0:24:37.840 --> 0:24:40.080
<v Speaker 1>in our combustion engines we used as a pushing force,

0:24:40.160 --> 0:24:43.480
<v Speaker 1>but at this case, the the piston in this chamber

0:24:43.560 --> 0:24:45.800
<v Speaker 1>is all the way out already, so it can't be

0:24:45.840 --> 0:24:48.840
<v Speaker 1>pushed further out, so he's not using as a pushing force. Instead,

0:24:49.200 --> 0:24:51.879
<v Speaker 1>once that guest starts to cool and is released, it

0:24:51.960 --> 0:24:54.200
<v Speaker 1>starts to shrink down. It's not and he's not letting

0:24:54.280 --> 0:24:56.440
<v Speaker 1>more air in there to replace it, and the valve

0:24:56.560 --> 0:24:59.040
<v Speaker 1>is closed, so it's pulling the piston back in in

0:24:59.119 --> 0:25:01.720
<v Speaker 1>that vacuum that's created in the chamber exactly. It's a

0:25:01.760 --> 0:25:05.359
<v Speaker 1>partial vacuum and imperfect vacuum, and that creates an area

0:25:05.440 --> 0:25:08.440
<v Speaker 1>of low pressure. That low pressure pulls on the piston,

0:25:08.760 --> 0:25:11.960
<v Speaker 1>which then moves to the other end of the combustion chamber.

0:25:12.240 --> 0:25:17.400
<v Speaker 1>So you're using this vacuum engine. Now. It worked, but uh,

0:25:17.440 --> 0:25:22.880
<v Speaker 1>it's not really practical, So this particular design wasn't widely implemented,

0:25:23.480 --> 0:25:26.840
<v Speaker 1>but it does in fact work. The principles are all sound.

0:25:27.400 --> 0:25:31.680
<v Speaker 1>So then you had a lot more experimentation following with hydrogen,

0:25:32.040 --> 0:25:36.280
<v Speaker 1>which included everything from inventors to chemists to physicists and

0:25:36.680 --> 0:25:40.720
<v Speaker 1>regular old crazy people and all of this is leading

0:25:40.800 --> 0:25:45.000
<v Speaker 1>up to some pretty cool stuff, including the first fuel cell,

0:25:45.760 --> 0:25:49.439
<v Speaker 1>and that wraps up part one of how hydrogen fuel works.

0:25:49.480 --> 0:25:52.480
<v Speaker 1>Next week we will have um let me chip my

0:25:52.480 --> 0:25:55.840
<v Speaker 1>nose oh part two? Hey how about that? So, if

0:25:55.880 --> 0:25:58.560
<v Speaker 1>you have any suggestions for topics I should cover on

0:25:58.640 --> 0:26:02.000
<v Speaker 1>future episodes of tech Stuff, or maybe there's a topic

0:26:02.040 --> 0:26:04.439
<v Speaker 1>that we have covered that is in sore need of

0:26:04.440 --> 0:26:06.800
<v Speaker 1>an update, let me know. The best way to do

0:26:06.840 --> 0:26:09.280
<v Speaker 1>that is to pop on over to Twitter. Our handle

0:26:09.400 --> 0:26:12.159
<v Speaker 1>is text stuff H s W and I'll talk to

0:26:12.160 --> 0:26:20.600
<v Speaker 1>you again really soon. Text Stuff is an I Heart

0:26:20.720 --> 0:26:24.440
<v Speaker 1>Radio production. For more podcasts from my heart Radio, visit

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