1 00:00:00,520 --> 00:00:03,840 Speaker 1: Welcome to Brainstuff from house stuff works dot com where 2 00:00:03,840 --> 00:00:14,600 Speaker 1: smart happens. Hi Am Marshal Brain with today's question, how 3 00:00:14,640 --> 00:00:19,239 Speaker 1: do you decaffeinate coffee and tea? Caffeine occurs naturally and 4 00:00:19,280 --> 00:00:21,720 Speaker 1: more than sixty plants, and you can find it in 5 00:00:21,840 --> 00:00:25,639 Speaker 1: things like coffee beans, cola nuts, and tea leaves. But 6 00:00:25,840 --> 00:00:29,400 Speaker 1: some people don't like the effects of caffeine, so these 7 00:00:29,480 --> 00:00:33,760 Speaker 1: different plant products need to be decaffeinated. When separated from 8 00:00:33,760 --> 00:00:38,720 Speaker 1: its source, caffeine is a white, bitter tasting powder. Several 9 00:00:38,760 --> 00:00:42,120 Speaker 1: different methods are used to remove this bitter tasting powder 10 00:00:42,159 --> 00:00:47,559 Speaker 1: from its natural sources. They include methylene chloride processing, ethyl 11 00:00:47,640 --> 00:00:54,360 Speaker 1: acetate processing, carbon dioxide processing, and water processing. Methylene Chloride 12 00:00:54,400 --> 00:00:57,840 Speaker 1: is a chemical used as a solvent to extract caffeine 13 00:00:57,880 --> 00:01:02,400 Speaker 1: from many raw materials. Moll alecules of caffeine bond molecules 14 00:01:02,400 --> 00:01:06,279 Speaker 1: of methylene chloride. The materials are softened in a water 15 00:01:06,400 --> 00:01:09,800 Speaker 1: bath or in steam. The next step is to process 16 00:01:09,880 --> 00:01:14,399 Speaker 1: the materials with methylene chloride, either by directly soaking the 17 00:01:14,480 --> 00:01:19,919 Speaker 1: materials in methylene chloride or by an indirect method. Caffeine, 18 00:01:19,959 --> 00:01:23,840 Speaker 1: which is water soluble, is extracted by soaking the materials 19 00:01:23,840 --> 00:01:27,319 Speaker 1: in water. Many of the flavors and oils are extracted 20 00:01:27,400 --> 00:01:31,000 Speaker 1: during this process, so the solution is treated with methylene 21 00:01:31,080 --> 00:01:34,080 Speaker 1: chloride to remove the caffeine from it, and then it's 22 00:01:34,160 --> 00:01:38,400 Speaker 1: returned to the material for reabsorption of the flavorings. Ethyl 23 00:01:38,480 --> 00:01:43,360 Speaker 1: Acetate process products are referred to as naturally decaffeated because 24 00:01:43,440 --> 00:01:48,160 Speaker 1: ethyl acetate is a chemical found naturally many fruits. Caffeine 25 00:01:48,200 --> 00:01:50,480 Speaker 1: is extracted in the exact same way you do it 26 00:01:50,520 --> 00:01:54,680 Speaker 1: with methylene chloride, but ethyl acetate is the solvent. To 27 00:01:54,800 --> 00:02:00,000 Speaker 1: decaffeinate something using carbon dioxide, water softened materials are pressure 28 00:02:00,000 --> 00:02:03,800 Speaker 1: are cooked with the carbon dioxide gas. At high pressures 29 00:02:03,800 --> 00:02:07,960 Speaker 1: and high temperatures. Carbon dioxide is in a supercritical state, 30 00:02:08,360 --> 00:02:11,640 Speaker 1: acting as both a gas and a liquid. It becomes 31 00:02:11,639 --> 00:02:15,919 Speaker 1: a solvent with its small, nonpolar molecules attracting the small 32 00:02:16,000 --> 00:02:21,280 Speaker 1: caffeine molecules. Since flavor molecules are larger, they remain intact 33 00:02:21,280 --> 00:02:24,520 Speaker 1: in the materials, which is why this process retains the 34 00:02:24,560 --> 00:02:28,880 Speaker 1: flavor of the natural materials better. Caffeine extraction with water 35 00:02:29,040 --> 00:02:32,720 Speaker 1: is used primarily for coffee. The process is similar to 36 00:02:32,720 --> 00:02:36,640 Speaker 1: the indirect method used in methylene chloride processing, but no 37 00:02:36,840 --> 00:02:40,280 Speaker 1: chemicals are used after the caffeine is leached out of 38 00:02:40,320 --> 00:02:42,880 Speaker 1: the material by soaking it in hot water for some 39 00:02:42,960 --> 00:02:46,280 Speaker 1: period of time. The solution is then passed through a 40 00:02:46,360 --> 00:02:50,040 Speaker 1: carbon filter, which grabs ahold of the caffeine molecules and 41 00:02:50,080 --> 00:02:53,240 Speaker 1: holds them. The water is then returned to the beans 42 00:02:53,240 --> 00:02:56,320 Speaker 1: for reabsorption of the flavors and the oils. In the 43 00:02:56,440 --> 00:03:00,360 Speaker 1: Swiss water process, the same method is used, but instead 44 00:03:00,400 --> 00:03:03,120 Speaker 1: of soaking in water, the beans are soaked in a 45 00:03:03,240 --> 00:03:07,680 Speaker 1: coffee flavored solution. This results in the caffeine being extracted 46 00:03:07,720 --> 00:03:11,560 Speaker 1: without removing any of the flavors from the coffee. Caffeine 47 00:03:11,639 --> 00:03:14,720 Speaker 1: is not removed completely using any of these methods, but 48 00:03:14,840 --> 00:03:19,040 Speaker 1: under federal regulations in the United States, caffeine levels must 49 00:03:19,040 --> 00:03:21,560 Speaker 1: not be above two and a half percent of the 50 00:03:21,680 --> 00:03:24,960 Speaker 1: product in order for the product to be labeled decaffeinated. 51 00:03:25,639 --> 00:03:29,760 Speaker 1: Most of the caffeine removed in processing is manufactured for 52 00:03:29,880 --> 00:03:33,000 Speaker 1: use in other products, such as medicines and soft drinks. 53 00:03:33,320 --> 00:03:36,280 Speaker 1: For example, less than five percent of the caffeine found 54 00:03:36,280 --> 00:03:39,960 Speaker 1: in cola drinks is actually from the cola nut, and 55 00:03:40,040 --> 00:03:43,440 Speaker 1: many of the popular high caffeine soft drinks don't contain 56 00:03:43,480 --> 00:03:47,160 Speaker 1: cola nut extracts at all. The caffeine content of soft 57 00:03:47,240 --> 00:03:51,280 Speaker 1: drinks is primarily and sometimes completely from the addition of 58 00:03:51,360 --> 00:03:58,080 Speaker 1: caffeine extracted from these other decaffeination processes for moralness and 59 00:03:58,120 --> 00:04:00,680 Speaker 1: thousands of other topics, because it how stuff works. Dot 60 00:04:00,720 --> 00:04:04,960 Speaker 1: com