1 00:00:00,200 --> 00:00:02,200 Speaker 1: Deep in the back of your mind. You've always had 2 00:00:02,240 --> 00:00:05,440 Speaker 1: the feeling that there's something strange about reality. There is 3 00:00:05,800 --> 00:00:10,320 Speaker 1: super annoyed death, much nanopartic, mechanical messiahs, punch evolution. On 4 00:00:10,360 --> 00:00:12,760 Speaker 1: our award winning science podcast Stuff About Your Mind, we 5 00:00:12,800 --> 00:00:17,000 Speaker 1: examine neurological quandaries, cosmic mysteries, evolutionary marvels, and our trans 6 00:00:17,040 --> 00:00:20,440 Speaker 1: human future. New episodes come out Tuesdays and Thursdays on iTunes, 7 00:00:20,480 --> 00:00:27,320 Speaker 1: Google Play, Spotify and anywhere you get your podcast. Welcome 8 00:00:27,360 --> 00:00:34,760 Speaker 1: to brain Stuff from How Stuff Works. Hey, brain Stuff, 9 00:00:34,760 --> 00:00:37,680 Speaker 1: this is Christian Seger. You have seen glow sticks before. 10 00:00:37,720 --> 00:00:40,200 Speaker 1: I bet they bring a festive glow to Halloween, trick 11 00:00:40,240 --> 00:00:42,559 Speaker 1: or treating and New Year's Eve celebrations. And they are 12 00:00:42,600 --> 00:00:46,519 Speaker 1: a useful gear for explorers, from scuba divers to spelunkers. 13 00:00:46,840 --> 00:00:48,600 Speaker 1: When you find a bunch of people gathered at a 14 00:00:48,640 --> 00:00:50,599 Speaker 1: party in the dark, at least a few of them 15 00:00:50,680 --> 00:00:53,800 Speaker 1: will probably be wielding glow sticks. But what the heck 16 00:00:53,840 --> 00:00:56,440 Speaker 1: are these things and how do they work well? Glow 17 00:00:56,520 --> 00:01:00,680 Speaker 1: sticks are powered by a process called kemma luminescence. Don't 18 00:01:00,720 --> 00:01:03,600 Speaker 1: let the name scare you. Luminescence is just a fancy 19 00:01:03,640 --> 00:01:07,520 Speaker 1: word for any emission of light not caused by heating. 20 00:01:08,040 --> 00:01:12,800 Speaker 1: We see luminescence and stuff like TVs, neon signs and fireflies. 21 00:01:13,120 --> 00:01:16,080 Speaker 1: The chemo luminescence in glow sticks is a pretty simple 22 00:01:16,120 --> 00:01:20,840 Speaker 1: reaction caused by mixing chemical compounds. Compounds are made up 23 00:01:20,840 --> 00:01:24,840 Speaker 1: of different elements bonded together in specific proportions so that 24 00:01:24,880 --> 00:01:28,520 Speaker 1: they can't be mechanically separated. It takes a chemical reaction 25 00:01:28,560 --> 00:01:31,720 Speaker 1: to sort out, for example, the oxygen from the hydrogen 26 00:01:31,720 --> 00:01:34,800 Speaker 1: in water. When you mix a compound with other stuff, 27 00:01:35,040 --> 00:01:37,880 Speaker 1: you can set off that reaction, and as the atoms 28 00:01:37,920 --> 00:01:42,840 Speaker 1: rearrange themselves, they'll either absorb or release energy. If you 29 00:01:42,840 --> 00:01:44,959 Speaker 1: look inside a glow stick, you'll see that there's a 30 00:01:45,040 --> 00:01:49,240 Speaker 1: small glass vial in the tube. This file typically contains 31 00:01:49,280 --> 00:01:54,360 Speaker 1: a hydrogen peroxide solution called the activator. It's floating in 32 00:01:54,360 --> 00:01:58,600 Speaker 1: a solution containing a compound called phenol oxalate ester and 33 00:01:58,680 --> 00:02:02,320 Speaker 1: a fluorescent dye. You still with me, Okay. When you 34 00:02:02,440 --> 00:02:05,360 Speaker 1: snap a glow stick, the vile breaks and the hydrogen 35 00:02:05,400 --> 00:02:10,959 Speaker 1: peroxide reacts with the phenyl oxalate ester, creating two other compounds, 36 00:02:11,280 --> 00:02:17,880 Speaker 1: phenol and a paraoxy acid esther Okay, still with me again. Okay, 37 00:02:17,919 --> 00:02:22,360 Speaker 1: this paraoxy acid stuff is unstable, so it decomposes and 38 00:02:22,440 --> 00:02:27,480 Speaker 1: produces additional phenol. It also produces a cyclic perioxy compound, 39 00:02:27,800 --> 00:02:33,200 Speaker 1: which decomposes to carbon dioxide. This decomposition releases energy to 40 00:02:33,240 --> 00:02:36,360 Speaker 1: the dye. The electrons in the dyes atoms jump to 41 00:02:36,400 --> 00:02:39,680 Speaker 1: a higher level than fall back down, releasing energy in 42 00:02:39,720 --> 00:02:42,920 Speaker 1: the form of light. The other chemicals in the fluorescent 43 00:02:43,000 --> 00:02:46,880 Speaker 1: dye determine the color of this light. All this happens 44 00:02:46,919 --> 00:02:50,760 Speaker 1: within moments of snapping and shaking your glow stick. Depending 45 00:02:50,840 --> 00:02:54,320 Speaker 1: on which compounds are used, the chemical reaction can continue 46 00:02:54,360 --> 00:02:58,080 Speaker 1: for anywhere from just a few minutes to hours. Warmer 47 00:02:58,120 --> 00:03:01,919 Speaker 1: temperatures will accelerate the reaction, making the stick glow brighter, 48 00:03:02,000 --> 00:03:05,040 Speaker 1: but for a shorter amount of time. When it's cooler, 49 00:03:05,120 --> 00:03:08,480 Speaker 1: the reaction will slow down, making the light dimmer, Which 50 00:03:08,520 --> 00:03:11,080 Speaker 1: means that if you want to preserve your light stick, 51 00:03:11,280 --> 00:03:14,400 Speaker 1: put it in the freezer overnight. It won't stop the process, 52 00:03:14,520 --> 00:03:17,640 Speaker 1: but it will slow it down and drag out the reaction. 53 00:03:18,040 --> 00:03:21,160 Speaker 1: So it turns out that there's some pretty nifty science 54 00:03:21,200 --> 00:03:23,919 Speaker 1: behind the humble glow stick. Check it out the next 55 00:03:23,960 --> 00:03:27,560 Speaker 1: time you're scuba diving, partying, or you know whatever it 56 00:03:27,600 --> 00:03:34,639 Speaker 1: is you do in the dark. Check out the brain 57 00:03:34,639 --> 00:03:36,800 Speaker 1: stuff channel on YouTube, and for more on this and 58 00:03:36,840 --> 00:03:53,520 Speaker 1: thousands of other topics, visit how stuff works dot com.