1 00:00:00,520 --> 00:00:03,800 Speaker 1: Welcome to Brainstuff from house Stuff Works dot com where 2 00:00:03,840 --> 00:00:14,840 Speaker 1: smart Happens. Hi Am Marshall Brain with today's question, why 3 00:00:14,880 --> 00:00:19,680 Speaker 1: do win a green Life Savers spark in the dark? Actually, 4 00:00:19,840 --> 00:00:23,439 Speaker 1: any hard sugar based candy will emit some amount of 5 00:00:23,520 --> 00:00:25,840 Speaker 1: light when you bite on it, but most of the 6 00:00:25,920 --> 00:00:29,680 Speaker 1: time that light is extremely faint. This effect is called 7 00:00:29,760 --> 00:00:34,760 Speaker 1: tribo luminescence. It's the admission of light that happens when 8 00:00:34,920 --> 00:00:38,239 Speaker 1: something is being smashed or torn. When you rip a 9 00:00:38,280 --> 00:00:40,640 Speaker 1: piece of tape off the roll, it will produce a 10 00:00:40,720 --> 00:00:46,440 Speaker 1: slight glow. For the same reason, tribo luminescence occurs when molecules, 11 00:00:46,560 --> 00:00:51,159 Speaker 1: in this case crystalline sugars, are crushed. This forces some 12 00:00:51,240 --> 00:00:54,880 Speaker 1: of the electrons out of their atomic fields. These free 13 00:00:54,920 --> 00:00:58,640 Speaker 1: electrons bump into nitrogen molecules in the air, and when 14 00:00:58,640 --> 00:01:03,240 Speaker 1: they collide, the elector drowns impart energy to the nitrogen molecules, 15 00:01:03,320 --> 00:01:07,839 Speaker 1: causing them to vibrate. In this excited state, these nitrogen 16 00:01:07,880 --> 00:01:12,480 Speaker 1: molecules emit light, mostly ultra violet light that's not visible, 17 00:01:12,760 --> 00:01:14,920 Speaker 1: but they do emit a small amount of visible light 18 00:01:14,959 --> 00:01:18,840 Speaker 1: as well. This is why all hard sugary candies will 19 00:01:18,880 --> 00:01:22,000 Speaker 1: produce a faint glow when cracked, but when you bite 20 00:01:22,000 --> 00:01:25,520 Speaker 1: into a winter Green lifesaver, a much greater amount of 21 00:01:25,600 --> 00:01:29,280 Speaker 1: visible light can be seen. This brighter light is produced 22 00:01:29,319 --> 00:01:34,240 Speaker 1: by the winter green flavoring itself. Methyl salicillate or oil 23 00:01:34,280 --> 00:01:38,039 Speaker 1: of winter green, is fluorescent, meaning it absorbs light of 24 00:01:38,080 --> 00:01:40,920 Speaker 1: a shorter wavelength and then emits it is light of 25 00:01:40,920 --> 00:01:45,080 Speaker 1: a longer wavelength. Ultra Violet light has a shorter wavelength 26 00:01:45,080 --> 00:01:48,280 Speaker 1: than visible light, so when a winter green lifesaver is 27 00:01:48,360 --> 00:01:52,840 Speaker 1: crushed between your teeth, the methyl salicillate molecules absorb the 28 00:01:52,920 --> 00:01:57,360 Speaker 1: ultra violet shorter wavelength light produced by the excited nitrogen 29 00:01:57,640 --> 00:02:01,320 Speaker 1: and then re emit it as light in the visible spectrum, 30 00:02:01,320 --> 00:02:05,800 Speaker 1: specifically as blue light. Thus you see blue sparks when 31 00:02:05,800 --> 00:02:08,519 Speaker 1: you crunch on a winter green light saver. So you 32 00:02:08,560 --> 00:02:12,120 Speaker 1: can try this out yourself. Grab some lifesavers, go to 33 00:02:12,200 --> 00:02:15,120 Speaker 1: a pitch black room or closet with a friend and 34 00:02:15,200 --> 00:02:19,880 Speaker 1: see what happens. Maybe some sparks will fly. Do you 35 00:02:19,919 --> 00:02:23,320 Speaker 1: have any ideas or suggestions for this podcast? If so, 36 00:02:23,480 --> 00:02:26,160 Speaker 1: please send me an email at podcast at how stuff 37 00:02:26,200 --> 00:02:28,920 Speaker 1: works dot com. For more on this and thousands of 38 00:02:28,960 --> 00:02:32,120 Speaker 1: other topics, go to how stuff works dot com and 39 00:02:32,160 --> 00:02:34,320 Speaker 1: be sure to check out the brain Stuff blog on 40 00:02:34,360 --> 00:02:36,160 Speaker 1: the how stuff works dot com home page