1 00:00:00,520 --> 00:00:03,800 Speaker 1: Welcome to Brainstoff front House, stuff Works dot Com, where 2 00:00:03,840 --> 00:00:15,360 Speaker 1: smart happens Him Marshall Brain with today's question, do you 3 00:00:15,360 --> 00:00:19,960 Speaker 1: remember the polaroid camera with the instant film? How did 4 00:00:20,000 --> 00:00:23,119 Speaker 1: that film work? How could you take a picture and 5 00:00:23,320 --> 00:00:26,160 Speaker 1: have the picture developed right in your hand in just 6 00:00:26,239 --> 00:00:30,520 Speaker 1: a minute or two. Instant camera film is remarkable because 7 00:00:30,560 --> 00:00:34,920 Speaker 1: it has its own built in developing studio. To understand 8 00:00:34,920 --> 00:00:38,000 Speaker 1: how this works, you need to understand the basics of 9 00:00:38,080 --> 00:00:42,760 Speaker 1: traditional photographic film. This has mostly been replaced by digital 10 00:00:42,840 --> 00:00:45,840 Speaker 1: cameras today, but it's still interesting and it's a great 11 00:00:45,920 --> 00:00:51,520 Speaker 1: chemistry experiment. Film is a plastic base coated with particles 12 00:00:51,560 --> 00:00:55,120 Speaker 1: of silver compound that are sensitive to light. Black and 13 00:00:55,120 --> 00:00:58,560 Speaker 1: white film has one layer of silver compound, while color 14 00:00:58,680 --> 00:01:02,000 Speaker 1: film has three layers. The top layer is sensitive to 15 00:01:02,040 --> 00:01:04,720 Speaker 1: blue light, the next layer is sensitive to green, and 16 00:01:04,760 --> 00:01:07,960 Speaker 1: the bottom layer is sensitive to red. When you expose 17 00:01:08,040 --> 00:01:11,840 Speaker 1: the film, the sensitive grains of each layer react to 18 00:01:11,959 --> 00:01:15,840 Speaker 1: light of that color, forming metallic silver at that layer. 19 00:01:16,280 --> 00:01:18,920 Speaker 1: This gives you a chemical record of the light and 20 00:01:19,040 --> 00:01:22,480 Speaker 1: color pattern. To turn this into a picture, you have 21 00:01:22,560 --> 00:01:26,720 Speaker 1: to develop the film. One developer chemical turns the exposed 22 00:01:26,760 --> 00:01:30,600 Speaker 1: particles into metallic silver. The film is then treated with 23 00:01:30,760 --> 00:01:35,680 Speaker 1: three different die developers containing die couplers. The three die 24 00:01:35,760 --> 00:01:40,000 Speaker 1: colors are cyan, a combination of green and blue light, magenta, 25 00:01:40,120 --> 00:01:43,240 Speaker 1: a combination of red and blue light, and yellow, a 26 00:01:43,319 --> 00:01:47,040 Speaker 1: combination of green and red light. Each of these die 27 00:01:47,120 --> 00:01:50,320 Speaker 1: coupler types react with one of the color layers in 28 00:01:50,360 --> 00:01:54,800 Speaker 1: the film. In ordinary print film, the die couplers attached 29 00:01:54,800 --> 00:01:58,800 Speaker 1: to particles that have been exposed. In color slide film, 30 00:01:59,080 --> 00:02:03,520 Speaker 1: the die cup is attached to non exposed areas. Developed 31 00:02:03,640 --> 00:02:07,640 Speaker 1: color film has a negative image, the colors appear opposite 32 00:02:07,640 --> 00:02:11,280 Speaker 1: of the colors in the original scene. In slide film, 33 00:02:11,320 --> 00:02:15,040 Speaker 1: the two dyes that attached to the unexposed area combined 34 00:02:15,080 --> 00:02:19,440 Speaker 1: to form the color captured at the exposed area. For example, 35 00:02:19,720 --> 00:02:23,359 Speaker 1: if the green layer is exposed, yellow and cyan dye 36 00:02:23,480 --> 00:02:26,640 Speaker 1: will attach to either side of the green layer, but 37 00:02:26,720 --> 00:02:29,680 Speaker 1: the magenta dye will not attach. At the green layer, 38 00:02:30,080 --> 00:02:34,320 Speaker 1: the yellow and cyan combined to form green. The instant 39 00:02:34,440 --> 00:02:39,880 Speaker 1: camera developing process combines colors the same basic way that 40 00:02:40,040 --> 00:02:43,440 Speaker 1: slide film does. It has the same layers of light 41 00:02:43,520 --> 00:02:47,799 Speaker 1: sensitive grains as traditional film, all arranged on a plastic sheet. 42 00:02:48,280 --> 00:02:52,919 Speaker 1: The film also contains several additional layers. However, these layers 43 00:02:52,960 --> 00:02:57,760 Speaker 1: contain all the necessary chemicals for the development process. Underneath 44 00:02:57,840 --> 00:03:02,799 Speaker 1: each color layer there's a dive aveloper layer containing die couplers. 45 00:03:02,840 --> 00:03:06,200 Speaker 1: All these layers sit on top of a black base layer, 46 00:03:06,440 --> 00:03:10,320 Speaker 1: and they sit underneath the image layer, timing layer, and 47 00:03:10,480 --> 00:03:14,880 Speaker 1: acid layer. This arrangement is essentially a chemical chain reaction 48 00:03:15,120 --> 00:03:18,840 Speaker 1: waiting to be set into motion. The component that gets 49 00:03:18,880 --> 00:03:24,080 Speaker 1: the developing process going is the reagent, as in reagent, 50 00:03:24,600 --> 00:03:29,760 Speaker 1: a mix of a pacifiers, alkali, white pigment, and other elements. 51 00:03:30,160 --> 00:03:33,839 Speaker 1: The reagent sits in a layer just above the light 52 00:03:33,919 --> 00:03:37,600 Speaker 1: sensitive layers and just below the image layer. Before you 53 00:03:37,640 --> 00:03:41,560 Speaker 1: take the picture, the reagent material is all collected in 54 00:03:41,600 --> 00:03:45,080 Speaker 1: a blob at the border of the plastic sheet, away 55 00:03:45,080 --> 00:03:48,680 Speaker 1: from the light sensitive material. This keeps the film from 56 00:03:48,680 --> 00:03:52,960 Speaker 1: developing before it's been exposed. After you snap the picture, 57 00:03:53,400 --> 00:03:56,520 Speaker 1: the film sheet passes out of the camera through a 58 00:03:56,560 --> 00:04:01,080 Speaker 1: pair of tight rollers. The rollers spread the reagent material 59 00:04:01,240 --> 00:04:03,960 Speaker 1: out into the middle of the film sheet, just like 60 00:04:04,000 --> 00:04:08,360 Speaker 1: a rolling pin spreading out dough. When the reagent is 61 00:04:08,480 --> 00:04:12,120 Speaker 1: spread in between the image layer and the light sensitive layers, 62 00:04:12,560 --> 00:04:15,600 Speaker 1: it reacts with the other chemical layers in the film. 63 00:04:16,080 --> 00:04:20,560 Speaker 1: The obasifier material stops light from filtering into the layers below, 64 00:04:21,000 --> 00:04:24,920 Speaker 1: so the film isn't fully exposed. Before it's developed, the 65 00:04:25,040 --> 00:04:29,840 Speaker 1: reagent chemicals moved downward through the layers, changing the exposed 66 00:04:29,880 --> 00:04:34,320 Speaker 1: particles in each layer into metallic silver. The chemicals then 67 00:04:34,440 --> 00:04:38,520 Speaker 1: dissolved the developer die, so it begins to diffuse up 68 00:04:38,680 --> 00:04:43,040 Speaker 1: toward the image layer. The metallic silver areas at each layer. 69 00:04:43,440 --> 00:04:47,240 Speaker 1: The grains that were exposed to light grab the dies, 70 00:04:47,400 --> 00:04:50,400 Speaker 1: so they stopped moving up. Only the dyes from the 71 00:04:50,560 --> 00:04:54,560 Speaker 1: unexposed layers will move up to the image layer. For example, 72 00:04:54,640 --> 00:04:57,720 Speaker 1: if the green layer was exposed, no bin jet to 73 00:04:57,839 --> 00:05:01,160 Speaker 1: die will make it to the image layer, but cyane 74 00:05:01,160 --> 00:05:05,280 Speaker 1: and yellow will. These colors combined to create a translucent 75 00:05:05,440 --> 00:05:10,400 Speaker 1: green film on the image surface. Light reflecting off the 76 00:05:10,400 --> 00:05:14,720 Speaker 1: white pigment and the reagent shines through these color layers 77 00:05:14,760 --> 00:05:17,760 Speaker 1: the same way that light from a bulb shines through 78 00:05:17,760 --> 00:05:22,200 Speaker 1: a slide. There is one problem left to solve. Recall 79 00:05:22,320 --> 00:05:25,560 Speaker 1: that there was this opacifier that made it so that 80 00:05:25,680 --> 00:05:28,760 Speaker 1: light couldn't get in to expose the film. While all 81 00:05:28,760 --> 00:05:31,880 Speaker 1: this developing is taking place. How do you make the 82 00:05:31,920 --> 00:05:35,440 Speaker 1: image clear. It turns out that at the same time 83 00:05:35,520 --> 00:05:38,880 Speaker 1: these re agent chemicals are working down through the light 84 00:05:38,960 --> 00:05:43,960 Speaker 1: sensitive layers, other re agent chemicals are working up through 85 00:05:44,040 --> 00:05:47,880 Speaker 1: the upper film layers. The acid layer in the film 86 00:05:47,960 --> 00:05:52,320 Speaker 1: reacts with the alkali and opacifiers in the reagent, making 87 00:05:52,360 --> 00:05:56,760 Speaker 1: the opacifiers become clear. This lets you see the image below. 88 00:05:57,320 --> 00:06:00,240 Speaker 1: The timing layer slows the re agent down on its 89 00:06:00,360 --> 00:06:03,159 Speaker 1: path to the acid layer to give the film time 90 00:06:03,200 --> 00:06:06,159 Speaker 1: to develop before it's exposed to light, and you can 91 00:06:06,200 --> 00:06:09,080 Speaker 1: see it. When you watch the image in a photo 92 00:06:09,200 --> 00:06:14,400 Speaker 1: film come into view, you're actually seeing this final chemical reaction. 93 00:06:14,839 --> 00:06:18,320 Speaker 1: The image is already developed underneath. You're just watching the 94 00:06:18,440 --> 00:06:22,280 Speaker 1: acid layer clear up the opacifiers in the reagent so 95 00:06:22,320 --> 00:06:26,840 Speaker 1: the image becomes visible to you. For more on this 96 00:06:27,040 --> 00:06:29,479 Speaker 1: and thousands of other topics, is that how stuff works 97 00:06:29,480 --> 00:06:31,560 Speaker 1: dot com and don't forget to check out the brain 98 00:06:31,560 --> 00:06:33,920 Speaker 1: stuff blog on the house stuff works dot com home page. 99 00:06:34,240 --> 00:06:36,760 Speaker 1: You can also follow brain stuff on Facebook or Twitter 100 00:06:37,120 --> 00:06:38,720 Speaker 1: at brain stuff hs W