1 00:00:01,840 --> 00:00:07,640 Speaker 1: Welcome to Brainstuff, a production of iHeartRadio, Hey, brain Stuff, 2 00:00:07,680 --> 00:00:12,000 Speaker 1: Lor and Volgevan here. Think about the way of building. 3 00:00:12,240 --> 00:00:16,040 Speaker 1: Like a house is constructed. You've got outer walls made 4 00:00:16,040 --> 00:00:19,720 Speaker 1: of materials like brick or wood, with openings built in 5 00:00:19,840 --> 00:00:22,520 Speaker 1: or cut in for windows, which are frames that hold 6 00:00:22,600 --> 00:00:27,680 Speaker 1: panes or sheets of glass. Windows make a home feel bright, warm, 7 00:00:27,720 --> 00:00:32,159 Speaker 1: and welcoming because they let sunlight enter. But why should 8 00:00:32,159 --> 00:00:35,400 Speaker 1: a glass window be any more transparent than the wood 9 00:00:35,520 --> 00:00:40,000 Speaker 1: or brick that surrounds it. After all, both materials are solid, 10 00:00:40,240 --> 00:00:43,760 Speaker 1: and both keep out rain, snow, and wind. Yet wood 11 00:00:43,840 --> 00:00:47,720 Speaker 1: is opaque and blocks like completely, while glass is transparent 12 00:00:47,880 --> 00:00:52,960 Speaker 1: and let's sunshine stream through unimpeded. You may have heard 13 00:00:53,000 --> 00:00:56,200 Speaker 1: some people and even some science textbooks try to explain 14 00:00:56,240 --> 00:00:59,080 Speaker 1: this by saying that wood is a true solid and 15 00:00:59,080 --> 00:01:02,720 Speaker 1: that glass is highly viscous liquid. They go on to 16 00:01:02,840 --> 00:01:05,720 Speaker 1: argue that the atoms in glass are spread farther apart 17 00:01:05,959 --> 00:01:09,560 Speaker 1: and that these gaps let like squeeze through. They may 18 00:01:09,600 --> 00:01:12,600 Speaker 1: even point to the windows of centuries old houses, which 19 00:01:12,720 --> 00:01:16,280 Speaker 1: often look wavy and unevenly thick, as evidence that the 20 00:01:16,280 --> 00:01:19,479 Speaker 1: windows have flowed over the years, like the slow crawl 21 00:01:19,520 --> 00:01:23,399 Speaker 1: of molasses on a cold day. In reality, glass isn't 22 00:01:23,440 --> 00:01:26,480 Speaker 1: a liquid at all. It's a special kind of solid 23 00:01:26,640 --> 00:01:29,920 Speaker 1: known as an amorphous solid. This is a state of 24 00:01:29,959 --> 00:01:33,240 Speaker 1: matter in which the atoms and molecules are locked into place, 25 00:01:33,640 --> 00:01:38,160 Speaker 1: but instead of forming neat orderly crystals, they arrange themselves randomly. 26 00:01:39,240 --> 00:01:42,480 Speaker 1: As a result, glass is mechanically rigid like a solid, 27 00:01:42,880 --> 00:01:46,759 Speaker 1: yet it has the disordered arrangement of molecules like liquids. 28 00:01:47,840 --> 00:01:51,960 Speaker 1: Amorphous solids form when a solid substance like silicon dioxide 29 00:01:52,000 --> 00:01:55,040 Speaker 1: also known as silica or sand, is melted at high 30 00:01:55,080 --> 00:01:58,080 Speaker 1: temperatures and then cooled so fast that it doesn't have 31 00:01:58,160 --> 00:02:02,320 Speaker 1: time to form orderly crystal, a process known as quenching. 32 00:02:03,480 --> 00:02:06,240 Speaker 1: The panes of glass in old houses aren't wavy and 33 00:02:06,280 --> 00:02:09,240 Speaker 1: thicker at the bottom because they're still flowing. They were 34 00:02:09,280 --> 00:02:11,920 Speaker 1: made in a time when glass technology wasn't as good 35 00:02:11,919 --> 00:02:14,839 Speaker 1: as it is today, so each pain may have had 36 00:02:14,880 --> 00:02:17,640 Speaker 1: some rippling in it when it's set and been thicker 37 00:02:17,720 --> 00:02:20,520 Speaker 1: on one end than the other. The carpenter would have 38 00:02:20,520 --> 00:02:23,079 Speaker 1: put the thicker end on the bottom because it's sturdier 39 00:02:23,120 --> 00:02:27,920 Speaker 1: like that. In many ways, glasses are like ceramics and 40 00:02:27,960 --> 00:02:31,559 Speaker 1: have all of the same properties durability, strength and brittleness, 41 00:02:31,960 --> 00:02:37,960 Speaker 1: high electrical and thermal resistance, and a lack of chemical reactivity. Basically, 42 00:02:38,160 --> 00:02:42,240 Speaker 1: glass won't corrode, break down, or discolor, which is why 43 00:02:42,280 --> 00:02:47,240 Speaker 1: it's used in so many applications. What's called soda lime glass, 44 00:02:47,280 --> 00:02:49,840 Speaker 1: which is the commercial glass that you find in sheet 45 00:02:49,880 --> 00:02:53,040 Speaker 1: and plate glass glass, jars and bottles and light bulbs, 46 00:02:53,280 --> 00:02:56,960 Speaker 1: has another important property. It's transparent to the range of 47 00:02:56,960 --> 00:03:01,880 Speaker 1: electromagnetic wavelengths known as visible light. To understand why, we 48 00:03:01,960 --> 00:03:04,160 Speaker 1: have to take a closer look at the atomic structure 49 00:03:04,160 --> 00:03:08,000 Speaker 1: of glass and understand what happens when photons, the smallest 50 00:03:08,000 --> 00:03:13,200 Speaker 1: particles of light, interact with that structure. Okay, so soda 51 00:03:13,240 --> 00:03:16,959 Speaker 1: lime glass is made up of mostly silicon dioxide or silica, 52 00:03:17,240 --> 00:03:19,760 Speaker 1: with a little bit of sodium carbonate or soda ash 53 00:03:19,919 --> 00:03:24,000 Speaker 1: added for manageability, and calcium carbonate or lime added for 54 00:03:24,160 --> 00:03:28,600 Speaker 1: hardness and durability. All of those atoms are arranged in 55 00:03:28,639 --> 00:03:33,000 Speaker 1: the amorphous solid body of the glass. Now, think about 56 00:03:33,040 --> 00:03:36,120 Speaker 1: the structure of an atom. You've got the atom's nucleus 57 00:03:36,160 --> 00:03:38,880 Speaker 1: with any protons and neutrons it has, and then the 58 00:03:38,920 --> 00:03:43,840 Speaker 1: electrons around that occupying different energy levels. If an electron 59 00:03:43,880 --> 00:03:46,720 Speaker 1: gains energy, it might move to a higher energy level. 60 00:03:47,200 --> 00:03:49,120 Speaker 1: If it gives up energy, it might move to a 61 00:03:49,160 --> 00:03:52,640 Speaker 1: lower one. In either case, the electron can only gain 62 00:03:52,760 --> 00:03:57,320 Speaker 1: or release energy in discrete bundles. Light is made up 63 00:03:57,360 --> 00:04:01,440 Speaker 1: of photons. Now, let's that are a photon moving toward 64 00:04:01,480 --> 00:04:04,520 Speaker 1: and interacting with a solid object made up of atoms. 65 00:04:05,360 --> 00:04:09,640 Speaker 1: One of three things can happen. First scenario, the substance 66 00:04:09,720 --> 00:04:13,720 Speaker 1: could absorb the photon. This occurs when the photon gives 67 00:04:13,800 --> 00:04:16,520 Speaker 1: up its energy to an electron located in the material. 68 00:04:17,360 --> 00:04:20,000 Speaker 1: Armed with this extra energy, the electron is able to 69 00:04:20,040 --> 00:04:23,480 Speaker 1: skip to a higher energy level while the photon disappears. 70 00:04:24,839 --> 00:04:29,880 Speaker 1: Second scenario, the substance could reflect the photon. To do this, 71 00:04:30,040 --> 00:04:32,719 Speaker 1: the photon gives up its energy to the material, but 72 00:04:32,920 --> 00:04:37,960 Speaker 1: a photon of identical energy is emitted. Third scenario, the 73 00:04:38,000 --> 00:04:42,600 Speaker 1: substance could allow the photon to pass through unchanged, known 74 00:04:42,640 --> 00:04:46,320 Speaker 1: as transmission. This happens because the photon doesn't interact with 75 00:04:46,360 --> 00:04:49,719 Speaker 1: any electrons and continues its journey until it interacts with 76 00:04:49,760 --> 00:04:55,880 Speaker 1: another object. Clear glass falls into this last category. Photons 77 00:04:55,920 --> 00:04:59,200 Speaker 1: pass through the material because they don't have sufficient energy 78 00:04:59,279 --> 00:05:01,320 Speaker 1: to excite a lo electrons in the glass to a 79 00:05:01,400 --> 00:05:05,599 Speaker 1: higher energy level. Physicists sometimes talk about this in terms 80 00:05:05,600 --> 00:05:09,360 Speaker 1: of band theory, which says energy levels exist together in 81 00:05:09,400 --> 00:05:13,840 Speaker 1: regions known as energy bands. In between those bands are 82 00:05:13,880 --> 00:05:17,440 Speaker 1: regions known as band gaps, where energy levels for electrons 83 00:05:17,600 --> 00:05:21,599 Speaker 1: don't exist at all. Some materials have larger band gaps 84 00:05:21,640 --> 00:05:25,919 Speaker 1: than others. Glass has pretty large band gaps, which means 85 00:05:25,960 --> 00:05:29,279 Speaker 1: it's electrons require much more energy before they can skip 86 00:05:29,320 --> 00:05:33,600 Speaker 1: from one energy band to another and back again. Photons 87 00:05:33,600 --> 00:05:36,520 Speaker 1: of visible light, that is, light with wavelengths from four 88 00:05:36,640 --> 00:05:42,920 Speaker 1: hundred to seven hundred nanimeters, corresponding to the colors violet, indigo, blue, green, yellow, orange, 89 00:05:42,960 --> 00:05:47,040 Speaker 1: and red, these photons simply don't have enough energy to 90 00:05:47,120 --> 00:05:52,440 Speaker 1: cause this skipping in glass. Therefore, photons of visible light 91 00:05:52,640 --> 00:05:56,080 Speaker 1: travel right through glass instead of being absorbed or reflected, 92 00:05:56,560 --> 00:06:02,080 Speaker 1: thus making glass transparent. At wavelengths smaller than visible light, 93 00:06:02,440 --> 00:06:05,520 Speaker 1: photons begin to have enough energy to move the electrons 94 00:06:05,560 --> 00:06:08,880 Speaker 1: in glass from one energy band to another. For example, 95 00:06:09,120 --> 00:06:12,479 Speaker 1: ultraviolet or UV light, which has a wavelength ranging from 96 00:06:12,600 --> 00:06:16,080 Speaker 1: ten to four hundred animeters, cannot pass through most sodo 97 00:06:16,120 --> 00:06:18,560 Speaker 1: lime glass, such as the glass and a window pane. 98 00:06:19,720 --> 00:06:23,240 Speaker 1: This makes a window, including the window in our hypothetical house, 99 00:06:23,560 --> 00:06:27,080 Speaker 1: as opaque to UV light as wood is to visible light, 100 00:06:27,440 --> 00:06:30,280 Speaker 1: which is pretty excellent considering the damage that EV light 101 00:06:30,320 --> 00:06:33,919 Speaker 1: can do to where eyes and skin. Pure silica glass 102 00:06:33,960 --> 00:06:38,320 Speaker 1: would let UV light through. There are other types of 103 00:06:38,320 --> 00:06:41,760 Speaker 1: transparent glass too, like lead glass, which is sometimes called 104 00:06:41,839 --> 00:06:44,599 Speaker 1: lead crystal and is used in decorative pieces because it 105 00:06:44,640 --> 00:06:47,880 Speaker 1: has such high brilliance, especially when cut with lots of facets. 106 00:06:49,040 --> 00:06:51,880 Speaker 1: There's also borsilicate glass, which is used for kitchen and 107 00:06:51,920 --> 00:06:55,320 Speaker 1: lab equipment because it's much better at withstanding temperature changes 108 00:06:55,440 --> 00:07:00,560 Speaker 1: than lead or soda lime glasses. It actually took humans 109 00:07:00,600 --> 00:07:03,719 Speaker 1: thousands of years to work out how to make glass clear. 110 00:07:05,120 --> 00:07:08,520 Speaker 1: Ancient crafts people in Mesopotamia in Egypt some four thousand 111 00:07:08,600 --> 00:07:11,880 Speaker 1: years ago discovered sodoaline glass and cast it to make 112 00:07:11,920 --> 00:07:17,320 Speaker 1: objects like beads and hollow containers. However, natural impurities and 113 00:07:17,320 --> 00:07:20,560 Speaker 1: the raw materials for glass will cause it to turn colors. 114 00:07:21,200 --> 00:07:24,640 Speaker 1: For example, iron oxides will create a blue to green 115 00:07:24,760 --> 00:07:28,800 Speaker 1: to yellow to brownish tint. By around the first century 116 00:07:28,800 --> 00:07:32,920 Speaker 1: bceeb artisans in Jerusalem invented the technique of blowing glass 117 00:07:33,160 --> 00:07:38,440 Speaker 1: very thinly so that it appeared transparent mostly, but it 118 00:07:38,520 --> 00:07:41,880 Speaker 1: wasn't until the fourteen hundreds that Venetian glass makers figured 119 00:07:41,880 --> 00:07:45,800 Speaker 1: out how to make glass colorless. They achieved this by 120 00:07:45,840 --> 00:07:49,680 Speaker 1: carefully controlling the purity of their raw materials and by 121 00:07:49,760 --> 00:07:53,400 Speaker 1: adding small amounts of other materials to counteract the tints 122 00:07:53,400 --> 00:07:58,520 Speaker 1: caused by iron oxides like antimony, potash, or manganese oxides. 123 00:07:59,760 --> 00:08:03,320 Speaker 1: This glass was considered super fancy and also led to 124 00:08:03,360 --> 00:08:08,080 Speaker 1: the development of technologies like magnifying lenses. All along this 125 00:08:08,200 --> 00:08:11,360 Speaker 1: timeline and up through today, people working with glass have 126 00:08:11,400 --> 00:08:15,920 Speaker 1: developed different techniques to color glass on purpose. Modernly, that's 127 00:08:15,960 --> 00:08:19,600 Speaker 1: often by adding metals or metal oxides alike copper for 128 00:08:19,680 --> 00:08:23,760 Speaker 1: red glass or cobalt for blue. When they do, the 129 00:08:23,800 --> 00:08:32,080 Speaker 1: glass will start reflecting those particular wavelengths of light. Today's 130 00:08:32,120 --> 00:08:34,840 Speaker 1: episode is based on the article what makes glass Transparent 131 00:08:34,920 --> 00:08:38,040 Speaker 1: on how Stuffworks dot Com, written by William Harris. Rain 132 00:08:38,040 --> 00:08:40,160 Speaker 1: Stuff is production of by Heart Radio in partnership with 133 00:08:40,160 --> 00:08:42,680 Speaker 1: how Stuffworks dot Com, and it's produced by Tyler Klang. 134 00:08:43,360 --> 00:08:46,440 Speaker 1: For more podcasts from My Heart Radio, visit the iHeartRadio app, 135 00:08:46,600 --> 00:08:49,480 Speaker 1: Apple Podcasts, or wherever you listen to your favorite shows. 136 00:09:00,080 --> 00:09:00,120 Speaker 1: M