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Cards issued by JP 42 00:02:16,600 --> 00:02:20,280 Speaker 3: Morgan Chase Bank NA Member FDIC subject to credit approval 43 00:02:20,360 --> 00:02:21,600 Speaker 3: Offers subject to change. 44 00:02:21,760 --> 00:02:22,480 Speaker 1: Terms apply. 45 00:02:31,440 --> 00:02:33,720 Speaker 4: Hey, Daniel, I have an explosive question for you. 46 00:02:34,000 --> 00:02:35,520 Speaker 1: Uh oh, are you gonna ask me about how to 47 00:02:35,520 --> 00:02:36,200 Speaker 1: blow things up? 48 00:02:36,760 --> 00:02:39,360 Speaker 4: Isn't that what you do every day anyways at the 49 00:02:39,360 --> 00:02:42,280 Speaker 4: Particle Collider? I mean, like, on a more every day basis. 50 00:02:42,320 --> 00:02:44,560 Speaker 4: How do you feel about summer fireworks? 51 00:02:45,000 --> 00:02:47,120 Speaker 1: M I used to love fireworks as a kid. 52 00:02:47,639 --> 00:02:49,480 Speaker 4: You used to love them. You don't like them anymore. 53 00:02:49,560 --> 00:02:53,760 Speaker 1: I guess I just used to have a more sparkling personality. 54 00:02:54,000 --> 00:02:56,000 Speaker 4: Well, you can be a real firecracker, trust me. 55 00:02:56,520 --> 00:02:58,519 Speaker 1: Well, I'm hoping one day that all blows over. 56 00:02:58,680 --> 00:03:02,000 Speaker 4: Yeah, very bright and popping's personality. Also, you seem to 57 00:03:02,040 --> 00:03:02,760 Speaker 4: make a lot of noise. 58 00:03:03,680 --> 00:03:06,080 Speaker 1: So far, I've never been fired from work for setting 59 00:03:06,120 --> 00:03:06,880 Speaker 1: off fireworks. 60 00:03:22,240 --> 00:03:25,200 Speaker 4: I am Hooreham, a cartoonist and the creator of PhD comics. 61 00:03:25,400 --> 00:03:28,240 Speaker 1: Hi, I'm Daniel. I'm a particle physicist and a professor 62 00:03:28,280 --> 00:03:31,400 Speaker 1: at UC Irvine, and I really do love blowing things up. 63 00:03:31,440 --> 00:03:33,840 Speaker 4: Oh yeah, do you do that as a hobby, not 64 00:03:33,919 --> 00:03:34,600 Speaker 4: just in your work. 65 00:03:35,920 --> 00:03:38,800 Speaker 1: Yeah, I'm pitching a new reality show called will It Explode? 66 00:03:41,680 --> 00:03:45,640 Speaker 4: Interesting? I guess if you don't like your fingers or hands, 67 00:03:45,920 --> 00:03:47,640 Speaker 4: that sounds like a great show to join. 68 00:03:48,400 --> 00:03:50,440 Speaker 1: I think everybody would want to tune in and see 69 00:03:50,680 --> 00:03:52,560 Speaker 1: how much T and T does it take to blow 70 00:03:52,680 --> 00:03:56,160 Speaker 1: up this or that, a banana, a watermelon, a coconut. 71 00:03:56,280 --> 00:03:58,120 Speaker 4: You remind me of my cousin when we were little 72 00:03:58,960 --> 00:04:01,200 Speaker 4: that can love to blow things up with far correctly. 73 00:04:01,400 --> 00:04:02,760 Speaker 1: And how'd that work out for your cousin? 74 00:04:04,160 --> 00:04:06,520 Speaker 4: All right, he's still alive, still has all his fingers, 75 00:04:06,960 --> 00:04:08,280 Speaker 4: He managed to survive. 76 00:04:07,960 --> 00:04:10,240 Speaker 1: Success, and I hope his job lets him blow things 77 00:04:10,320 --> 00:04:11,720 Speaker 1: up on a regular basis like. 78 00:04:11,920 --> 00:04:16,000 Speaker 4: Mine actually fixes planes now, so I hope it doesn't 79 00:04:16,040 --> 00:04:16,799 Speaker 4: blow things open. 80 00:04:19,960 --> 00:04:22,360 Speaker 1: His job is the opposite now of his childhood passion. 81 00:04:22,520 --> 00:04:25,960 Speaker 4: That's right, keep things are blowing up, please Gus. But anyways, 82 00:04:25,960 --> 00:04:28,440 Speaker 4: welcome to our podcast, Daniel and Jorge Explain the Universe, 83 00:04:28,480 --> 00:04:29,760 Speaker 4: a production of Iurheart Radio. 84 00:04:29,960 --> 00:04:31,839 Speaker 1: We're the only thing we want to blow up is 85 00:04:31,920 --> 00:04:35,000 Speaker 1: your mind. As we delve into the secrets of the 86 00:04:35,160 --> 00:04:38,840 Speaker 1: universe and try to understand how it all works. We 87 00:04:38,920 --> 00:04:42,200 Speaker 1: take apart the very fabric of space and time and 88 00:04:42,279 --> 00:04:45,599 Speaker 1: reality and seek to understand it at the smallest level. 89 00:04:45,920 --> 00:04:48,760 Speaker 1: How does the universe really work? What are its most 90 00:04:48,800 --> 00:04:52,359 Speaker 1: fundamental bits, and how do those weave themselves together to 91 00:04:52,400 --> 00:04:56,760 Speaker 1: make this incredible, exciting and explosive universe that we enjoy 92 00:04:56,920 --> 00:04:57,520 Speaker 1: every summer. 93 00:04:57,640 --> 00:05:00,320 Speaker 4: Yeah, it is an exploding universe. As we know. Dark 94 00:05:00,440 --> 00:05:03,520 Speaker 4: energy is making the universe accelerate and expand faster and 95 00:05:03,560 --> 00:05:06,080 Speaker 4: faster each day. Literally, it is sort of exploding, and 96 00:05:06,160 --> 00:05:09,120 Speaker 4: it's also full of sparkly, amazing and colorful things for 97 00:05:09,240 --> 00:05:10,279 Speaker 4: us to wonder about. 98 00:05:10,360 --> 00:05:12,719 Speaker 1: That's right, Although thinking about the Big Bang and the 99 00:05:12,760 --> 00:05:15,720 Speaker 1: expansion of the universe as an explosion does tend to 100 00:05:15,800 --> 00:05:18,599 Speaker 1: lead people to thinking about things the wrong way. A 101 00:05:18,640 --> 00:05:20,719 Speaker 1: lot of people think about the Big Bang is like 102 00:05:20,960 --> 00:05:23,800 Speaker 1: this tiny dot of matter which then blew up into 103 00:05:23,920 --> 00:05:26,960 Speaker 1: space which already existed. Though these days our vision of 104 00:05:26,960 --> 00:05:30,120 Speaker 1: the early universe isn't as much like a firecracker as 105 00:05:30,120 --> 00:05:33,360 Speaker 1: it is like a big rubber sheet getting stretched everywhere. 106 00:05:33,960 --> 00:05:36,120 Speaker 4: Maybe you shouldn't have called it the Big Bang. I 107 00:05:36,120 --> 00:05:38,240 Speaker 4: mean it's in the name Da Hill. The Big Bang 108 00:05:38,279 --> 00:05:39,279 Speaker 4: sounds like an explosion. 109 00:05:39,400 --> 00:05:41,640 Speaker 1: It does, indeed sound like an explosion, and so we'll 110 00:05:41,640 --> 00:05:45,120 Speaker 1: added to the list of horribly named astronomical concepts. 111 00:05:45,680 --> 00:05:47,960 Speaker 4: I mean, you just misnamed the entire universe. I mean 112 00:05:48,839 --> 00:05:50,000 Speaker 4: just a small error there. 113 00:05:50,160 --> 00:05:51,719 Speaker 1: We should have called it the Big Stretch. 114 00:05:53,720 --> 00:05:55,720 Speaker 4: But it is interesting. Do you see your job as 115 00:05:55,800 --> 00:05:58,080 Speaker 4: blowing things up? You said earlier you like blowing things up, 116 00:05:58,080 --> 00:06:01,560 Speaker 4: and you're a particle physicist, which means you collide things. 117 00:06:01,640 --> 00:06:04,359 Speaker 4: But does that is also the same thing as blowing 118 00:06:04,400 --> 00:06:04,800 Speaker 4: things up? 119 00:06:04,960 --> 00:06:07,720 Speaker 1: Yeah? Well, the reason we collide things is to blow 120 00:06:07,720 --> 00:06:10,440 Speaker 1: them up. Like you want to know what's inside a proton, 121 00:06:10,800 --> 00:06:13,080 Speaker 1: you can't like put it on the table and tease 122 00:06:13,120 --> 00:06:15,359 Speaker 1: it apart with plyers. What you got to do is 123 00:06:15,360 --> 00:06:17,719 Speaker 1: smash two of them together, blow them up, and see 124 00:06:17,720 --> 00:06:21,200 Speaker 1: what comes out from that explosion. So every collision inside 125 00:06:21,240 --> 00:06:24,040 Speaker 1: the Large Hadron Collider is like a mini explosion, and 126 00:06:24,080 --> 00:06:25,640 Speaker 1: we do millions of them per. 127 00:06:25,520 --> 00:06:28,200 Speaker 4: Second, although it's more like a smashing. I don't know 128 00:06:28,240 --> 00:06:29,120 Speaker 4: if it's exploding. 129 00:06:29,160 --> 00:06:33,440 Speaker 1: Really, Well, what happens if you smash two watermelons together? 130 00:06:33,640 --> 00:06:34,880 Speaker 1: They explode, don't they. 131 00:06:35,320 --> 00:06:38,720 Speaker 4: They just smash. If you put a grenade inside of 132 00:06:38,760 --> 00:06:40,279 Speaker 4: a watermelon, that's an explosion. 133 00:06:40,360 --> 00:06:42,200 Speaker 1: Well, if I could put a grenade inside of proton. 134 00:06:42,320 --> 00:06:44,839 Speaker 1: I would totally do it, But what would. 135 00:06:44,640 --> 00:06:45,600 Speaker 4: The grenade be made out of? 136 00:06:45,680 --> 00:06:52,120 Speaker 1: Danium? Grenadons obviously a delicious dessert. Explosions, but I'm also 137 00:06:52,160 --> 00:06:55,400 Speaker 1: a big fan of aerial explosions, though maybe more so 138 00:06:55,480 --> 00:06:55,920 Speaker 1: as a kid. 139 00:06:56,120 --> 00:06:59,160 Speaker 4: Yeah, you mentioned that before, So you don't like fireworks anymore? 140 00:06:59,279 --> 00:07:01,159 Speaker 4: Like you go to display and what do you do? 141 00:07:01,000 --> 00:07:02,919 Speaker 4: You close your ears or you close your eyes. 142 00:07:03,080 --> 00:07:04,560 Speaker 1: I used to be really amazed by them. I thought 143 00:07:04,560 --> 00:07:06,320 Speaker 1: they were fantastic when I was a kid, And now 144 00:07:06,400 --> 00:07:08,520 Speaker 1: I don't know if I've just gotten old and grumpy, 145 00:07:08,760 --> 00:07:10,280 Speaker 1: but they're just sort of less impressive. 146 00:07:11,320 --> 00:07:13,960 Speaker 4: They're beautiful now, and they're they're getting more complicated now, 147 00:07:14,040 --> 00:07:16,160 Speaker 4: right Like now they can you know, like sync them 148 00:07:16,200 --> 00:07:18,880 Speaker 4: up with music and do all kinds of things like 149 00:07:19,000 --> 00:07:22,840 Speaker 4: multiple explosions that make different formations up there in the sky. 150 00:07:23,080 --> 00:07:25,640 Speaker 1: Mm hmm. And as we come up on July fourth, 151 00:07:25,920 --> 00:07:28,680 Speaker 1: it reminds me that the best fireworks display I ever 152 00:07:28,760 --> 00:07:32,440 Speaker 1: saw for July fourth, for American Independence Day was actually 153 00:07:32,560 --> 00:07:33,440 Speaker 1: in Switzerland. 154 00:07:33,560 --> 00:07:36,600 Speaker 4: Oh yeah, they make everything better out there, more precise. 155 00:07:37,040 --> 00:07:40,720 Speaker 1: There's a huge American population in Switzerland, and so in 156 00:07:40,760 --> 00:07:45,280 Speaker 1: Geneva they have an incredible July fourth fireworks display in Geneva. 157 00:07:45,280 --> 00:07:47,960 Speaker 1: It's like outside the US, but they go all out 158 00:07:48,040 --> 00:07:51,160 Speaker 1: and have a live orchestra which plays music and coordination 159 00:07:51,280 --> 00:07:53,240 Speaker 1: with the fireworks. It really was pretty impressive. 160 00:07:53,840 --> 00:07:55,720 Speaker 4: Well, so you do like fireworks then. 161 00:07:55,720 --> 00:07:57,600 Speaker 1: Yeah, occasionally I've been known to enjoy them. 162 00:07:57,680 --> 00:08:03,040 Speaker 4: Yeah, occasionally. I mean, who doesn't like fireworks, Daniel? Maybe dogs? 163 00:08:03,480 --> 00:08:06,480 Speaker 4: Dogs and physicists, dogs and jaded physicists. 164 00:08:06,520 --> 00:08:08,400 Speaker 1: Dan. Well, when you blow things up for a living, 165 00:08:08,480 --> 00:08:10,080 Speaker 1: you know you expect the higher standard. 166 00:08:10,080 --> 00:08:12,080 Speaker 4: I guess right, right, when you smash things for a living? 167 00:08:12,160 --> 00:08:16,440 Speaker 4: You mean I you said you got the big name 168 00:08:16,480 --> 00:08:19,000 Speaker 4: for the origin of the universe. Wrong, Maybe you should be. 169 00:08:18,960 --> 00:08:21,800 Speaker 1: A little more careful yep, point taking. 170 00:08:21,880 --> 00:08:24,840 Speaker 4: But anyways, fireworks are pretty amazing and incredible and part 171 00:08:24,840 --> 00:08:27,480 Speaker 4: of our tradition and part of how the world celebrates 172 00:08:27,520 --> 00:08:31,040 Speaker 4: big events like independence and New Year's But it's kind 173 00:08:31,040 --> 00:08:33,320 Speaker 4: of interesting to think about how that actually works. 174 00:08:33,440 --> 00:08:35,680 Speaker 1: Yeah, it's an example of how we have put our 175 00:08:35,760 --> 00:08:38,640 Speaker 1: knowledge of how the universe works to work for us. 176 00:08:38,760 --> 00:08:41,200 Speaker 1: We manipulate these things and take advantage of them to 177 00:08:41,280 --> 00:08:44,560 Speaker 1: create these incredible, bright displays. But to do so, you 178 00:08:44,679 --> 00:08:47,119 Speaker 1: have to know some physics and some chemistry. 179 00:08:47,280 --> 00:08:49,400 Speaker 4: Yeah, so today on the program we'll be tackling the 180 00:08:49,480 --> 00:08:58,959 Speaker 4: question how do fireworks work, or I guess more technically, 181 00:08:59,000 --> 00:09:01,079 Speaker 4: how the fire works fire and work? 182 00:09:01,600 --> 00:09:04,560 Speaker 1: And can you set off fireworks at work without getting fired? 183 00:09:05,600 --> 00:09:07,640 Speaker 4: It is a bit of an oxymorn, isn't it. In 184 00:09:07,679 --> 00:09:11,080 Speaker 4: one word, you have firing, you can fire someone and 185 00:09:11,200 --> 00:09:14,760 Speaker 4: they can also work exactly fire works. 186 00:09:15,440 --> 00:09:17,120 Speaker 1: It's like we works, but we don't work. 187 00:09:18,160 --> 00:09:22,360 Speaker 4: Yeah, fire crashed. Yeah, it's pretty interesting to think about 188 00:09:22,360 --> 00:09:24,920 Speaker 4: how fireworks work. But I think you sort of said 189 00:09:24,920 --> 00:09:28,079 Speaker 4: earlier that it's the result of our knowledge of the universe, 190 00:09:28,120 --> 00:09:30,440 Speaker 4: But really sort of fireworks weren't you know? It didn't 191 00:09:30,480 --> 00:09:33,240 Speaker 4: come from us understanding anything about the universe, right, I 192 00:09:33,280 --> 00:09:35,600 Speaker 4: think it was mostly just people playing around with and 193 00:09:35,679 --> 00:09:37,640 Speaker 4: maybe figuring out that some things blow up. 194 00:09:37,720 --> 00:09:39,920 Speaker 1: You're absolutely right that fireworks have been with us for 195 00:09:40,000 --> 00:09:43,199 Speaker 1: a lot longer than like our understanding of the chemistry 196 00:09:43,240 --> 00:09:46,000 Speaker 1: and the physics of them, that's for sure. In fact, 197 00:09:46,160 --> 00:09:48,880 Speaker 1: I think they're invented in China like more than a 198 00:09:49,000 --> 00:09:51,920 Speaker 1: thousand years ago. So firework has been a part of 199 00:09:51,920 --> 00:09:54,320 Speaker 1: a human existence for a very very long time, longer 200 00:09:54,360 --> 00:09:56,400 Speaker 1: than we've had modern chemistry, that's for sure. 201 00:09:56,840 --> 00:09:58,600 Speaker 4: How they were invented. Do you think someone would just 202 00:09:58,880 --> 00:10:01,760 Speaker 4: foolling around with things and then that blew up on 203 00:10:01,880 --> 00:10:04,160 Speaker 4: them and then the person next to them was like, oh, 204 00:10:04,280 --> 00:10:04,960 Speaker 4: that's interesting. 205 00:10:05,120 --> 00:10:08,840 Speaker 1: I love thinking about how people stumbled into understanding of 206 00:10:08,880 --> 00:10:11,560 Speaker 1: how things work. You think, like, think about like the 207 00:10:11,559 --> 00:10:15,320 Speaker 1: metallurgy of swords. People have really refined techniques for exactly 208 00:10:15,400 --> 00:10:18,160 Speaker 1: how to make very hard steal well before we had 209 00:10:18,200 --> 00:10:20,600 Speaker 1: any understanding of the chemistry of it. And I think 210 00:10:20,640 --> 00:10:24,440 Speaker 1: that must have just been accidentally discovered people making mistakes 211 00:10:24,440 --> 00:10:26,960 Speaker 1: and then discovering, oh wow, look this is pretty awesome. 212 00:10:27,040 --> 00:10:29,840 Speaker 1: So yeah, I think gunpowder probably discovered accidentally. 213 00:10:30,360 --> 00:10:32,920 Speaker 4: Interesting. Well, we'll get into how it works and how 214 00:10:32,920 --> 00:10:34,760 Speaker 4: it was discovered, but as you said, the history of 215 00:10:34,800 --> 00:10:36,920 Speaker 4: it is that it was invented in China about a 216 00:10:37,000 --> 00:10:39,320 Speaker 4: thousand years ago. People are not sure. I guess there 217 00:10:39,320 --> 00:10:40,199 Speaker 4: are no records of it. 218 00:10:40,320 --> 00:10:42,320 Speaker 1: There are some records of it, and you can look 219 00:10:42,320 --> 00:10:45,800 Speaker 1: at like Chinese historical drawings and visitors who went to 220 00:10:45,880 --> 00:10:48,640 Speaker 1: China of course to see evidence of it for more 221 00:10:48,720 --> 00:10:50,400 Speaker 1: than a thousand years. It's pretty cool. 222 00:10:51,000 --> 00:10:53,120 Speaker 4: Do you think they were they invented as a like 223 00:10:53,160 --> 00:10:55,800 Speaker 4: a celebration display or more for warfare. 224 00:10:55,960 --> 00:10:58,319 Speaker 1: They were initially invented for celebration, they think, and then 225 00:10:58,440 --> 00:11:00,840 Speaker 1: later applied for war like everything. 226 00:11:01,720 --> 00:11:05,040 Speaker 4: No, it's usually the other way around these days. 227 00:11:05,120 --> 00:11:05,280 Speaker 5: Right. 228 00:11:05,600 --> 00:11:09,760 Speaker 4: The Internet was started for the military darpnet. Yeah, it 229 00:11:09,800 --> 00:11:12,640 Speaker 4: was originally darpnet, and then it became you know, cat 230 00:11:12,720 --> 00:11:14,960 Speaker 4: videos and podcasts. 231 00:11:15,200 --> 00:11:17,839 Speaker 1: I see. So you're saying fireworks eventually would just turn 232 00:11:17,880 --> 00:11:18,720 Speaker 1: into cat videos. 233 00:11:18,960 --> 00:11:21,400 Speaker 4: That would be super impressive. If they can do a 234 00:11:21,400 --> 00:11:23,520 Speaker 4: cat video with explosives. 235 00:11:22,960 --> 00:11:25,480 Speaker 1: Engineers can get to it. That is the goal. The 236 00:11:25,520 --> 00:11:28,600 Speaker 1: way every life form eventually evolves into a crab, every 237 00:11:28,640 --> 00:11:31,679 Speaker 1: form of weapon eventually evolves into a cat video. 238 00:11:31,800 --> 00:11:33,960 Speaker 4: Well, and then eventually it came to Europe, but not 239 00:11:34,080 --> 00:11:34,800 Speaker 4: till much later. 240 00:11:34,960 --> 00:11:38,160 Speaker 1: That's right. In the fourteenth century is when Europe started 241 00:11:38,160 --> 00:11:41,160 Speaker 1: to use fireworks and developed the same sort of technology. 242 00:11:40,640 --> 00:11:42,240 Speaker 4: And then somehow it made it to America and it 243 00:11:42,400 --> 00:11:44,880 Speaker 4: became part ofly fourth our celebrations. 244 00:11:45,000 --> 00:11:47,040 Speaker 1: Yeah, but blowing things up have been part of how 245 00:11:47,080 --> 00:11:51,320 Speaker 1: people celebrate things for a long long time. Watermelons, fireworks, 246 00:11:51,640 --> 00:11:52,680 Speaker 1: hopefully not cats. 247 00:11:52,880 --> 00:11:56,760 Speaker 4: The beginning of the universe with a big bang. Well, 248 00:11:56,800 --> 00:11:59,360 Speaker 4: it's interesting because it's something that's in our everyday lives 249 00:11:59,400 --> 00:12:01,640 Speaker 4: almost least once or twice a year, but a bit 250 00:12:01,679 --> 00:12:03,920 Speaker 4: not a lot of people know how it works, and 251 00:12:03,960 --> 00:12:06,000 Speaker 4: so as usual we were wondering what would happen if 252 00:12:06,000 --> 00:12:07,959 Speaker 4: you ask people on the street or on the internet 253 00:12:08,160 --> 00:12:09,400 Speaker 4: how fireworks work. 254 00:12:09,640 --> 00:12:12,560 Speaker 1: So thanks very much to everybody out there who answers 255 00:12:12,679 --> 00:12:15,679 Speaker 1: random questions about the Big Bang, the origin of the universe, 256 00:12:15,760 --> 00:12:18,840 Speaker 1: and how fireworks work without any chance to prepare. We 257 00:12:18,920 --> 00:12:21,520 Speaker 1: really love you participating. And if you're out there and 258 00:12:21,559 --> 00:12:24,079 Speaker 1: you've never joined in, please don't be shy right to 259 00:12:24,160 --> 00:12:27,520 Speaker 1: us two questions at Danielandjorge dot com. We want to 260 00:12:27,559 --> 00:12:28,559 Speaker 1: hear from you, So. 261 00:12:28,520 --> 00:12:30,000 Speaker 4: Think about it for a second. How do you think 262 00:12:30,080 --> 00:12:32,880 Speaker 4: fireworks work? Here's a people had to say. 263 00:12:33,040 --> 00:12:36,080 Speaker 6: There's some small amount of gunpowder in a tube that 264 00:12:36,160 --> 00:12:39,320 Speaker 6: two explodes, creating a big old pressure wave in a tiny, 265 00:12:39,320 --> 00:12:43,280 Speaker 6: little enclosed area, so that exerts a force on something 266 00:12:43,280 --> 00:12:45,280 Speaker 6: that's gonna get shot into the air or or I 267 00:12:45,280 --> 00:12:47,840 Speaker 6: guess whichever way you point it at a friend or 268 00:12:49,520 --> 00:12:51,199 Speaker 6: a building or a car, And if it's one of 269 00:12:51,200 --> 00:12:53,640 Speaker 6: those big fireworks, it probably has a second charge in it. 270 00:12:54,160 --> 00:12:56,120 Speaker 6: You can put a bunch of different metals in there 271 00:12:56,120 --> 00:13:00,480 Speaker 6: that are gonna burn at different colors, and that would 272 00:13:00,520 --> 00:13:02,520 Speaker 6: be what makes all the pretty colors in the sky 273 00:13:02,559 --> 00:13:03,960 Speaker 6: after that second charge goes off. 274 00:13:04,120 --> 00:13:08,320 Speaker 5: It's my understanding that you have a shell that is 275 00:13:09,000 --> 00:13:13,319 Speaker 5: made up of black powder or gunpowder or something explosive, 276 00:13:13,840 --> 00:13:18,839 Speaker 5: surrounded by little things, little balls of something that is 277 00:13:19,320 --> 00:13:23,880 Speaker 5: dipped in a salt, like a strontium or you know, 278 00:13:23,960 --> 00:13:26,320 Speaker 5: some sort of metal that when it heats up, it 279 00:13:26,440 --> 00:13:27,960 Speaker 5: glows in a specific color. 280 00:13:28,320 --> 00:13:34,439 Speaker 7: Fireworks show differently because I think there are chemicals within 281 00:13:34,559 --> 00:13:41,760 Speaker 7: each display that, once exploded, will reflect light differently, and 282 00:13:42,000 --> 00:13:44,160 Speaker 7: that's what produces all of the beautiful colors. 283 00:13:44,600 --> 00:13:48,880 Speaker 8: Fireworks are like an amazing confluence of chemistry and physics. 284 00:13:49,120 --> 00:13:51,240 Speaker 8: There's all of this energy that you have stored in 285 00:13:51,840 --> 00:13:54,680 Speaker 8: the propellant and the explosive that you're using, and then 286 00:13:55,040 --> 00:13:57,600 Speaker 8: once you get it up there, you're using different chemicals 287 00:13:58,080 --> 00:14:01,000 Speaker 8: to create all the wild colors. In effect, it's early 288 00:14:01,120 --> 00:14:03,800 Speaker 8: rockets and payloads of joy. 289 00:14:04,040 --> 00:14:06,640 Speaker 9: Oh, I'm so excited if you are talking about fireworks. 290 00:14:06,800 --> 00:14:09,520 Speaker 9: I love them, and yet I am not sure how 291 00:14:09,520 --> 00:14:16,679 Speaker 9: they work. There's something explosive and different elements create different colors. 292 00:14:17,040 --> 00:14:19,560 Speaker 9: I think, though I have no idea how they make 293 00:14:19,640 --> 00:14:22,440 Speaker 9: those really cool ones with the different sparkles and sounds 294 00:14:22,560 --> 00:14:25,560 Speaker 9: that sound like they're crackling. I love those. 295 00:14:25,920 --> 00:14:29,560 Speaker 10: I think fireworks work by firing stuff at the back 296 00:14:29,600 --> 00:14:33,120 Speaker 10: of them, and due to one of Neuter's laws, which 297 00:14:33,120 --> 00:14:37,240 Speaker 10: I can't remember, that means that due to the opposite reaction, 298 00:14:37,600 --> 00:14:41,000 Speaker 10: the firework will go up and then I guess some 299 00:14:41,080 --> 00:14:45,440 Speaker 10: dynamite explodes and makes a nice color in shape. 300 00:14:45,640 --> 00:14:46,040 Speaker 11: Well. 301 00:14:46,240 --> 00:14:49,480 Speaker 1: I always imagine fireworks as like a tiny, little colorful 302 00:14:49,520 --> 00:14:52,640 Speaker 1: controlled bomb that exploded only once you reach the sky. 303 00:14:53,560 --> 00:14:54,680 Speaker 1: But maybe works differently. 304 00:14:55,080 --> 00:14:59,600 Speaker 12: Fireworks work by oxidizing flammables with a specific chemical that 305 00:14:59,640 --> 00:15:03,080 Speaker 12: emits light at a certain frequency, creating the different colors 306 00:15:03,080 --> 00:15:03,600 Speaker 12: we see. 307 00:15:03,920 --> 00:15:07,040 Speaker 4: All right, some pretty technical sounding answers. I like this 308 00:15:07,080 --> 00:15:10,800 Speaker 4: one that said the confluence of chemistry and physics. That 309 00:15:10,880 --> 00:15:14,480 Speaker 4: sounds almost poetic. Little do they know chemists and physicists 310 00:15:14,520 --> 00:15:16,000 Speaker 4: never confluence exactly. 311 00:15:16,040 --> 00:15:17,880 Speaker 1: I was like, that's so naive, man, They're like all 312 00:15:17,880 --> 00:15:20,800 Speaker 1: the way in fluence together. They're on the other side 313 00:15:20,840 --> 00:15:23,640 Speaker 1: of campus, man, Like they do totally different physics from us. 314 00:15:24,040 --> 00:15:26,800 Speaker 1: Chemistry might as well be sociology from our perspective. 315 00:15:27,480 --> 00:15:30,200 Speaker 4: Is there a stereotype of like a chemists and physicists. 316 00:15:30,880 --> 00:15:32,680 Speaker 4: Like one of them will were sandals, the other ones 317 00:15:32,720 --> 00:15:35,600 Speaker 4: were were's socks and slippers. 318 00:15:35,600 --> 00:15:37,920 Speaker 1: I don't know eye protection. Chemistr are always wearing eye 319 00:15:37,960 --> 00:15:40,200 Speaker 1: protection when I see them around the building. I see 320 00:15:40,280 --> 00:15:43,360 Speaker 1: interesting the chemistry, you see, I have these huge labs 321 00:15:43,360 --> 00:15:46,720 Speaker 1: of like thirty grad students pumping out different synthesis of 322 00:15:46,760 --> 00:15:48,920 Speaker 1: this and that and the other thing. It's really amazing 323 00:15:48,960 --> 00:15:51,200 Speaker 1: and impressive, though I don't understand most of it. 324 00:15:51,320 --> 00:15:53,880 Speaker 4: You sound little jealous there, Well, the chemistry do you 325 00:15:53,920 --> 00:15:55,480 Speaker 4: have like thirty grad students yourself? 326 00:15:55,960 --> 00:15:58,360 Speaker 1: I only have eight grad students right now, thank you. 327 00:15:58,560 --> 00:16:02,000 Speaker 1: But the uichemistry department is top notch. Somebody who graduated 328 00:16:02,000 --> 00:16:04,040 Speaker 1: from here won the Nobel Prize in chemistry last year. 329 00:16:04,080 --> 00:16:09,120 Speaker 4: I think always an opportunity to plug you, ciz. But yeah, 330 00:16:09,120 --> 00:16:11,560 Speaker 4: it's pretty interesting. Everyone seems to have an idea that 331 00:16:11,640 --> 00:16:14,920 Speaker 4: it's about exploding things, which sort of makes sense and 332 00:16:15,160 --> 00:16:18,400 Speaker 4: maybe a little obvious. There's an explosion involved and gunpowder. 333 00:16:18,560 --> 00:16:21,320 Speaker 1: Yeah, but fireworks are much more than just an explosion. Right. 334 00:16:21,360 --> 00:16:24,200 Speaker 1: If you've been to a recent fireworks display, you've seen 335 00:16:24,240 --> 00:16:27,840 Speaker 1: that they can do incredible stuff. They're sparkly, they're shimmery, 336 00:16:28,320 --> 00:16:31,240 Speaker 1: they have different colors, they can make smiley faces. I've 337 00:16:31,240 --> 00:16:34,360 Speaker 1: seen butterflies, I've seen palm trees. It's really amazing and 338 00:16:34,400 --> 00:16:36,200 Speaker 1: what they can do up there in the sky. 339 00:16:36,640 --> 00:16:40,160 Speaker 4: Yeah, Well for today, let's break it down maybe a 340 00:16:40,160 --> 00:16:42,760 Speaker 4: little bit further, right, because when we think about fireworks 341 00:16:42,800 --> 00:16:45,800 Speaker 4: and you know, celebrations like New Year's or July fourth, 342 00:16:45,920 --> 00:16:48,080 Speaker 4: there's really sort of three things that people think about. 343 00:16:48,120 --> 00:16:48,400 Speaker 13: Right. 344 00:16:48,520 --> 00:16:51,560 Speaker 4: There is the firecrackers that kind of just explode and 345 00:16:51,600 --> 00:16:54,600 Speaker 4: make noise that usually the kind of people throughout in 346 00:16:54,600 --> 00:16:57,600 Speaker 4: the middle of the street. There are sparklers, which are 347 00:16:57,640 --> 00:17:00,160 Speaker 4: the you know sticks that you hold and they to 348 00:17:00,200 --> 00:17:01,960 Speaker 4: pr out a lot of sparkles. And then there is 349 00:17:02,000 --> 00:17:04,040 Speaker 4: a big fireworks display that go up in the sky 350 00:17:04,119 --> 00:17:05,720 Speaker 4: and give us all these amazing colors. 351 00:17:05,880 --> 00:17:08,360 Speaker 1: Yeah, and those things are actually all connected. So that's 352 00:17:08,359 --> 00:17:09,560 Speaker 1: a great order to tackle them in. 353 00:17:09,880 --> 00:17:12,800 Speaker 4: Right. Well, we'll start with the firecrackers, Daniel, How what 354 00:17:12,880 --> 00:17:14,760 Speaker 4: is that? What are the basics of a fire cracker? 355 00:17:15,200 --> 00:17:19,879 Speaker 1: Firecracker is really pretty simple stuff. It's essentially just gunpowder 356 00:17:20,080 --> 00:17:22,919 Speaker 1: in a little tube with a fuse, so it's just 357 00:17:22,960 --> 00:17:25,480 Speaker 1: like a mini bomb, right, And All it does is 358 00:17:25,640 --> 00:17:29,199 Speaker 1: rapidly burn the gunpowder, the black powder, and explode and 359 00:17:29,240 --> 00:17:31,280 Speaker 1: give you a loud noise and a little bit of smoke. 360 00:17:32,240 --> 00:17:34,359 Speaker 4: Now, but I guess the question is what is gunpowder? 361 00:17:34,680 --> 00:17:37,600 Speaker 1: Yeah, I've wondered this for a long time. Actually gunpowder 362 00:17:37,880 --> 00:17:41,040 Speaker 1: is this weird mixture of stuff. So it's got some 363 00:17:41,240 --> 00:17:43,959 Speaker 1: charcoal in it, like fifteen percent, ten percent of it 364 00:17:44,000 --> 00:17:47,000 Speaker 1: is sulfur, and then seventy five percent of it is 365 00:17:47,000 --> 00:17:50,240 Speaker 1: this stuff called saltpeter, which I always thought was really weird, 366 00:17:50,280 --> 00:17:52,600 Speaker 1: like who is Peter and why is he so salty? 367 00:17:53,200 --> 00:17:56,080 Speaker 1: But it's basically just like a funny historical name for 368 00:17:56,119 --> 00:17:58,120 Speaker 1: a chemical potassium nitrate. 369 00:17:59,000 --> 00:18:02,080 Speaker 4: Interesting, maybe salt Peter is the cousin of Sweet John. 370 00:18:04,240 --> 00:18:06,679 Speaker 1: I think they're both blues singers. Sounds like, you know, 371 00:18:06,680 --> 00:18:08,400 Speaker 1: Mississippi saltpeter or something. 372 00:18:08,760 --> 00:18:12,040 Speaker 4: All Right, So to make gunpowder, you just need charcoal, sulfur, 373 00:18:12,080 --> 00:18:16,199 Speaker 4: and potassium nitrate. Now, what's potassium nitrate? It's like p 374 00:18:17,000 --> 00:18:18,480 Speaker 4: K can N something. 375 00:18:18,680 --> 00:18:22,639 Speaker 1: Yeah, So the chemical formula is k no three. So 376 00:18:22,720 --> 00:18:26,159 Speaker 1: it's got potassium, it's got nitrogen, it's got oxygen, and 377 00:18:26,200 --> 00:18:28,800 Speaker 1: it occurs in nature as a mineral and it's a 378 00:18:28,880 --> 00:18:32,719 Speaker 1: useful source of nitrogen, and it's used in fertilizers and 379 00:18:32,840 --> 00:18:36,360 Speaker 1: also for like obviously rocket propellants and fireworks, and they 380 00:18:36,400 --> 00:18:38,600 Speaker 1: also put some of it in processed meats. 381 00:18:38,880 --> 00:18:41,720 Speaker 4: Wait what, Oh, that's right, let's get curing agent. 382 00:18:42,680 --> 00:18:45,520 Speaker 1: And like the reason that like red hot dogs are 383 00:18:45,560 --> 00:18:47,720 Speaker 1: red is because the potassium nitrate? 384 00:18:48,000 --> 00:18:50,199 Speaker 4: Well does that mean hot dogs are flammable? And they 385 00:18:50,240 --> 00:18:54,439 Speaker 4: will explode if you light them up? Is that why 386 00:18:54,480 --> 00:18:55,359 Speaker 4: they're called hot dogs? 387 00:18:55,760 --> 00:18:57,080 Speaker 1: I don't know. But the first thing I would do 388 00:18:57,119 --> 00:18:59,320 Speaker 1: is take two hot dogs and accelerate them together. See 389 00:18:59,320 --> 00:19:01,840 Speaker 1: if that can general a nice hot dog smash. 390 00:19:01,920 --> 00:19:04,159 Speaker 4: Yeah, that sounds like a great use of a billion 391 00:19:04,160 --> 00:19:09,080 Speaker 4: dollar facility in Geneva. Maybe for July fourth parties smash 392 00:19:09,119 --> 00:19:14,000 Speaker 4: hot dogs and sell them too little kids. Okay, so 393 00:19:14,040 --> 00:19:17,680 Speaker 4: that's gunpowder, charcoal, sulfur, and potassium nit rate. Now why 394 00:19:17,760 --> 00:19:19,360 Speaker 4: does that light up? Why does that explode? 395 00:19:19,440 --> 00:19:21,679 Speaker 1: Mm hm? And so what's happening anytime you have an 396 00:19:21,680 --> 00:19:24,800 Speaker 1: explosion is just a rapid release of energy, and like 397 00:19:24,880 --> 00:19:28,560 Speaker 1: one shell of exploding material then sets off the next one. 398 00:19:28,600 --> 00:19:30,200 Speaker 1: It's sort of just like a fire in the sense 399 00:19:30,200 --> 00:19:32,159 Speaker 1: of like the way one piece of wood ignites the 400 00:19:32,160 --> 00:19:35,119 Speaker 1: next piece. But here it happens very very rapidly, so 401 00:19:35,119 --> 00:19:38,520 Speaker 1: you have a rapid emission of energy, usually faster than 402 00:19:38,520 --> 00:19:40,960 Speaker 1: the speed of sound. That's what an explosive is. It's 403 00:19:41,000 --> 00:19:44,560 Speaker 1: usually supersonic. So that's the basics of an explosion. The 404 00:19:44,600 --> 00:19:47,600 Speaker 1: details depend on exactly what you have in there, how 405 00:19:47,720 --> 00:19:51,280 Speaker 1: rapidly it oxidizes, how rapidly it releases that energy. 406 00:19:51,400 --> 00:19:53,639 Speaker 4: Wait, so maybe take us through that process then, like 407 00:19:53,680 --> 00:19:56,840 Speaker 4: what's what's going on? What does oxidizing mean? What do 408 00:19:56,880 --> 00:19:58,400 Speaker 4: you need like a flame to get it started? 409 00:19:58,560 --> 00:20:01,600 Speaker 1: Right? So fundamental process. What's happening here chemically is something 410 00:20:01,640 --> 00:20:06,840 Speaker 1: called combustion, right, which technically is just like high temperature exothermic, 411 00:20:06,880 --> 00:20:10,240 Speaker 1: which means it's releasing energy. So you're doing some chemical 412 00:20:10,359 --> 00:20:13,160 Speaker 1: change to what's going on inside. You're changing the molecules 413 00:20:13,200 --> 00:20:16,480 Speaker 1: and their bonds in a way that releases some stored energy, 414 00:20:16,600 --> 00:20:18,639 Speaker 1: the same way like when you burn gasoline, right, it 415 00:20:18,720 --> 00:20:21,879 Speaker 1: releases energy that used to be stored inside the fuel. 416 00:20:22,119 --> 00:20:24,840 Speaker 1: So here it's an exothermic reaction, and it's called a 417 00:20:25,000 --> 00:20:28,400 Speaker 1: redox reaction because it reacts with some oxidant, often that's 418 00:20:28,400 --> 00:20:31,879 Speaker 1: atmospheric oxygen, like fire. Needs oxygen, right, it's part of 419 00:20:31,920 --> 00:20:35,560 Speaker 1: the chemical process to release the energy that's bound inside 420 00:20:35,600 --> 00:20:38,640 Speaker 1: the wood. Here, you also need some source of oxygen 421 00:20:38,640 --> 00:20:41,000 Speaker 1: because there's not enough oxygen in the atmosphere to get 422 00:20:41,000 --> 00:20:43,639 Speaker 1: this reaction going and to have it happen so fast. 423 00:20:44,240 --> 00:20:45,960 Speaker 1: You want it to start in the center and then 424 00:20:46,040 --> 00:20:50,000 Speaker 1: explode outwards, and you know they can't access enough oxygen 425 00:20:50,280 --> 00:20:52,040 Speaker 1: to just take that from the air, so you have 426 00:20:52,119 --> 00:20:55,400 Speaker 1: to provide a source of oxygen to make this whole 427 00:20:55,440 --> 00:20:56,280 Speaker 1: explosion happen. 428 00:20:57,040 --> 00:20:59,800 Speaker 4: But I guess you know, like what's the actual reaction? 429 00:21:00,160 --> 00:21:04,720 Speaker 4: Like why do you need potassium, nitrogen, charcoal, carbon, and sulfur? 430 00:21:05,000 --> 00:21:07,440 Speaker 4: Like what's going on? Is something transforming into something else 431 00:21:07,560 --> 00:21:10,719 Speaker 4: or something breaking apart? Why do you need those three ingredients? 432 00:21:10,800 --> 00:21:14,159 Speaker 1: You start with potassium nitrate and carbon and sulfur, and 433 00:21:14,200 --> 00:21:16,440 Speaker 1: then you get out the same bits but arrange it 434 00:21:16,480 --> 00:21:19,639 Speaker 1: in a different pattern, So you get carbon dioxide, you 435 00:21:19,680 --> 00:21:22,480 Speaker 1: get atmospheric nitrogen, which is end two, and then you 436 00:21:22,480 --> 00:21:25,200 Speaker 1: get potassium sulfide. So you end up with the same 437 00:21:25,200 --> 00:21:28,800 Speaker 1: bits but just rearranged in different molecules in a way 438 00:21:28,840 --> 00:21:31,760 Speaker 1: that takes less energy. So you've released some of the energy. 439 00:21:32,240 --> 00:21:35,800 Speaker 4: Whoa that's that sounds like a pretty complicated reaction there, 440 00:21:35,840 --> 00:21:37,840 Speaker 4: Like you put in three things and then three other 441 00:21:37,880 --> 00:21:40,719 Speaker 4: things come out, but they're totally different. The fire somehow 442 00:21:41,160 --> 00:21:41,760 Speaker 4: trigger set. 443 00:21:41,880 --> 00:21:45,360 Speaker 1: Yeah, it's actually a complicated multi stage reaction. Doesn't all 444 00:21:45,400 --> 00:21:47,960 Speaker 1: happen at once, and it's something people are still sort 445 00:21:47,960 --> 00:21:50,639 Speaker 1: of studying and trying to optimize, and they've come up 446 00:21:50,680 --> 00:21:53,840 Speaker 1: recently with more fancy versions of gunpowder that like don't 447 00:21:53,880 --> 00:21:57,240 Speaker 1: release any smoke. So it's a complicated multi stage reaction. 448 00:21:57,480 --> 00:21:59,520 Speaker 4: Well, what do you mean multi stage? Like the first 449 00:21:59,560 --> 00:22:02,920 Speaker 4: the potassium nitrate reacts with this, and then something else 450 00:22:02,920 --> 00:22:05,200 Speaker 4: and then the charcoal comes in or what exactly. 451 00:22:05,280 --> 00:22:07,639 Speaker 1: It's multi steps. You don't have all three things happening 452 00:22:07,680 --> 00:22:10,160 Speaker 1: at the same time. First you have the potassium nitrate, 453 00:22:10,400 --> 00:22:12,679 Speaker 1: which it breaks down and releases the oxygen, and then 454 00:22:12,720 --> 00:22:15,800 Speaker 1: that oxygen's crucial for the next stages of the reaction. 455 00:22:16,720 --> 00:22:18,720 Speaker 4: But I guess you need something to start it, right, 456 00:22:18,840 --> 00:22:20,880 Speaker 4: like you need that spark, and so when you light 457 00:22:20,960 --> 00:22:24,040 Speaker 4: up a match, you're burning the stuff in the match, 458 00:22:24,320 --> 00:22:28,640 Speaker 4: which is creating temperature I guess heat, right, then high 459 00:22:28,680 --> 00:22:31,040 Speaker 4: kinetic energy things that are moving really fast. And then 460 00:22:31,040 --> 00:22:33,480 Speaker 4: when you put it close to the gunpowder that somehow 461 00:22:33,560 --> 00:22:34,600 Speaker 4: triggers the reaction. 462 00:22:35,080 --> 00:22:37,280 Speaker 1: Well, these things are in a stable state as is, right. 463 00:22:37,280 --> 00:22:40,199 Speaker 1: Gunpowder just sitting on the table doesn't give off the 464 00:22:40,320 --> 00:22:43,200 Speaker 1: energy that's stored in it the same way gasoline doesn't 465 00:22:43,400 --> 00:22:46,000 Speaker 1: or wood doesn't. But if you can trigger this reaction, 466 00:22:46,040 --> 00:22:48,359 Speaker 1: if you can get it hot enough to trigger this reaction, 467 00:22:48,400 --> 00:22:50,800 Speaker 1: it will release some of its internal energy. So it's 468 00:22:50,840 --> 00:22:53,119 Speaker 1: sort of like a ball trapped on a shelf. You 469 00:22:53,200 --> 00:22:54,880 Speaker 1: got to give it a little push so it'll fall 470 00:22:54,920 --> 00:22:57,399 Speaker 1: off and release all of that potential energy. And so 471 00:22:57,520 --> 00:23:00,320 Speaker 1: this is all trapped stored inside these chemicals, and if 472 00:23:00,320 --> 00:23:02,879 Speaker 1: you provide some heat to kick it off, then it 473 00:23:02,920 --> 00:23:05,560 Speaker 1: will release a lot of that internal stored energy, and 474 00:23:05,640 --> 00:23:09,119 Speaker 1: that release will then trigger more release from the adjacent molecules, 475 00:23:09,320 --> 00:23:11,880 Speaker 1: so it builds on itself. It's a chain reaction that way. 476 00:23:12,000 --> 00:23:14,280 Speaker 4: Right, And I imagine it's also you need like a 477 00:23:14,480 --> 00:23:17,439 Speaker 4: certain amount of heat, right, Like, I'm sure if it's 478 00:23:17,480 --> 00:23:19,960 Speaker 4: sitting there out there in the open, there are air 479 00:23:20,040 --> 00:23:22,520 Speaker 4: molecules hitting it, and some of them are partly hitting 480 00:23:22,560 --> 00:23:25,040 Speaker 4: it pretty fast and it is maybe causing some reactions, 481 00:23:25,040 --> 00:23:28,119 Speaker 4: but maybe not enough to really get that snowball. 482 00:23:27,760 --> 00:23:31,040 Speaker 1: Rolling exactly, although you can have that happen naturally from 483 00:23:31,080 --> 00:23:34,000 Speaker 1: like lightning strikes. Fires can start in the woods from 484 00:23:34,080 --> 00:23:36,720 Speaker 1: lightning strikes. But you're right, air molecules don't trigger this 485 00:23:36,720 --> 00:23:39,679 Speaker 1: because they don't deposit enough energy to get over that hump. 486 00:23:39,720 --> 00:23:41,879 Speaker 1: It's in a stable state, which means, like you perturb 487 00:23:41,920 --> 00:23:43,360 Speaker 1: it a little bit, it's just going to go back 488 00:23:43,400 --> 00:23:45,560 Speaker 1: to hanging out in the molecules it was in. It 489 00:23:45,560 --> 00:23:47,640 Speaker 1: needs a big push to get it out of its 490 00:23:47,680 --> 00:23:51,040 Speaker 1: little local stable equilibrium and over the hump, to release 491 00:23:51,040 --> 00:23:53,200 Speaker 1: a lot of that energy and fall into a different 492 00:23:53,240 --> 00:23:56,280 Speaker 1: stable equilibrium of these products of the chemical reaction. 493 00:23:56,520 --> 00:23:58,960 Speaker 4: All right, well, those are the basics of gunpowder. Let's 494 00:23:58,960 --> 00:24:03,240 Speaker 4: get into how they figure into fire crackers, sparklers, and fireworks. 495 00:24:03,800 --> 00:24:18,679 Speaker 4: But first let's take a quick break. All right, we 496 00:24:18,720 --> 00:24:22,679 Speaker 4: are lighting up the podcast guy I guess, and celebrating 497 00:24:22,800 --> 00:24:25,919 Speaker 4: July fourth here in the US and or whenever you 498 00:24:25,960 --> 00:24:29,240 Speaker 4: want listen to this episode, and we're talking about fireworks 499 00:24:29,240 --> 00:24:32,199 Speaker 4: and gunpowder and how that all works for me, I 500 00:24:32,200 --> 00:24:36,440 Speaker 4: guess physico chemists perspective, Are we forcing you to be 501 00:24:36,480 --> 00:24:37,840 Speaker 4: a chemist in this episode, Daniel? 502 00:24:38,640 --> 00:24:41,159 Speaker 1: As much as I can possibly be. You know, my 503 00:24:41,280 --> 00:24:44,720 Speaker 1: natural state is thinking about like one fundamental particle maybe 504 00:24:44,840 --> 00:24:47,199 Speaker 1: interacting with another one. And one of the reasons I 505 00:24:47,200 --> 00:24:49,560 Speaker 1: didn't end up in chemistry is that it's so many 506 00:24:49,640 --> 00:24:52,240 Speaker 1: particles to keep track of all at once. It seems 507 00:24:52,280 --> 00:24:55,199 Speaker 1: to be like impossible to really ever understand what's going on. 508 00:24:55,480 --> 00:24:57,959 Speaker 1: You always have to zoom out and think about things statistically, 509 00:24:58,000 --> 00:24:58,960 Speaker 1: which makes me less. 510 00:24:58,800 --> 00:25:01,360 Speaker 4: Comfortable one thing at a time kind of guy. 511 00:25:01,480 --> 00:25:03,880 Speaker 1: Yeah, like drill down to the fundamental nature and look 512 00:25:03,920 --> 00:25:04,520 Speaker 1: at it, you know. 513 00:25:05,119 --> 00:25:08,040 Speaker 4: All right, Well we talked about gunpowder. It's a mixture 514 00:25:08,080 --> 00:25:11,320 Speaker 4: of charcoal, sulfur, and potassium nitrate, and that's somehow when 515 00:25:11,359 --> 00:25:13,360 Speaker 4: you put a flame to it, it starts a chain 516 00:25:13,400 --> 00:25:18,320 Speaker 4: reaction that transforms the elements and also, I guess releases energy. Now, 517 00:25:19,000 --> 00:25:22,320 Speaker 4: how is this energy released just kinetic energy or photons 518 00:25:22,400 --> 00:25:23,040 Speaker 4: or what's going on? 519 00:25:23,200 --> 00:25:26,200 Speaker 1: Well, the energy is released both as heat, right, because 520 00:25:26,560 --> 00:25:29,760 Speaker 1: one shell of exploding gunpowder heats up the next one 521 00:25:29,760 --> 00:25:30,520 Speaker 1: and sets it off. 522 00:25:30,760 --> 00:25:32,760 Speaker 4: And by heat you mean just like kinetic energy of 523 00:25:32,800 --> 00:25:34,800 Speaker 4: the particles. Right, Like a mole, like it breaks apart 524 00:25:34,840 --> 00:25:38,480 Speaker 4: and the pieces fly off in different directions. 525 00:25:38,280 --> 00:25:41,000 Speaker 1: And they're flying off with higher speeds exactly. That's a 526 00:25:41,040 --> 00:25:44,000 Speaker 1: good rough idea for what temperature is, what heat is. 527 00:25:44,040 --> 00:25:46,639 Speaker 1: It's the sphadometer of the particles that are inside it. 528 00:25:46,920 --> 00:25:50,000 Speaker 1: So you release this energy, meaning that instead of being 529 00:25:50,040 --> 00:25:53,000 Speaker 1: bound into some molecule where you have like springs that 530 00:25:53,040 --> 00:25:56,360 Speaker 1: are compressed and tightly wound. Now you release those particles 531 00:25:56,400 --> 00:25:58,959 Speaker 1: and they're flying out. The springs have released their energy 532 00:25:59,160 --> 00:26:01,960 Speaker 1: and they're zooming out and hitting other particles, and that 533 00:26:02,000 --> 00:26:05,160 Speaker 1: creates a shock wave, right, because you're hitting other particles 534 00:26:05,200 --> 00:26:08,000 Speaker 1: which then hit other particles. And that's what sound is. 535 00:26:08,240 --> 00:26:12,440 Speaker 1: Sound is a traveling compression wave. So as this explodes, 536 00:26:12,480 --> 00:26:15,880 Speaker 1: it creates pressure in the air, and that pressure hits 537 00:26:15,880 --> 00:26:18,320 Speaker 1: your ear and you hear it. So the reason a 538 00:26:18,359 --> 00:26:21,600 Speaker 1: fire cracker sounds like a boom is because it's a 539 00:26:21,600 --> 00:26:24,520 Speaker 1: little bomb. It's created this little pressure wave which travels 540 00:26:24,560 --> 00:26:25,720 Speaker 1: out and hits your. 541 00:26:25,560 --> 00:26:27,600 Speaker 4: Ear, all right, So that's the band that we hear 542 00:26:27,640 --> 00:26:30,480 Speaker 4: when a firecracker goes off. And what about the flash, 543 00:26:30,560 --> 00:26:31,760 Speaker 4: Like where does that light come from? 544 00:26:31,880 --> 00:26:33,919 Speaker 1: That's again just from the energy that's released. Some of 545 00:26:33,960 --> 00:26:36,240 Speaker 1: it gets converted into sound, some of it gets converted 546 00:26:36,280 --> 00:26:39,560 Speaker 1: into heat, and some of it is released as photons, right, 547 00:26:39,560 --> 00:26:41,679 Speaker 1: And so just like when you're looking at a fire, 548 00:26:41,720 --> 00:26:44,800 Speaker 1: it's releasing heat, but it's also releasing visible light. You're 549 00:26:44,840 --> 00:26:47,119 Speaker 1: going to see some of that with your eyes. Remember, 550 00:26:47,160 --> 00:26:49,800 Speaker 1: anything that gets hot is going to release photons. It's 551 00:26:49,800 --> 00:26:53,680 Speaker 1: impossible to warm up without glowing. Everything in physics we 552 00:26:53,800 --> 00:26:56,480 Speaker 1: think of as a black body radiator, meaning that the 553 00:26:56,600 --> 00:26:59,840 Speaker 1: temperature you are determines the frequency in which you glow. 554 00:27:00,119 --> 00:27:02,200 Speaker 1: So things that get hot enough are going to glow 555 00:27:02,240 --> 00:27:03,000 Speaker 1: in the visible light. 556 00:27:03,280 --> 00:27:03,399 Speaker 9: Right. 557 00:27:03,600 --> 00:27:05,840 Speaker 4: I think we covered this in a previous episode. Like 558 00:27:05,880 --> 00:27:09,159 Speaker 4: when things are hot, the molecules are moving really fast, 559 00:27:09,160 --> 00:27:13,360 Speaker 4: and somehow that causes the electrons to drop down levels, right, 560 00:27:13,440 --> 00:27:15,320 Speaker 4: and then that's what releases the photons. 561 00:27:15,520 --> 00:27:18,160 Speaker 1: The universe doesn't like to have high energy density, likes 562 00:27:18,160 --> 00:27:20,639 Speaker 1: to spread that energy out. So if a bunch of 563 00:27:20,680 --> 00:27:24,239 Speaker 1: molecules with energy, either because those electrons have energy, or 564 00:27:24,240 --> 00:27:27,000 Speaker 1: because the molecules themselves have high kinetic energy, or maybe 565 00:27:27,000 --> 00:27:30,320 Speaker 1: they have vibrational energy in their bonds, that likes to 566 00:27:30,320 --> 00:27:34,000 Speaker 1: spread out. So anything that's excited will release that energy 567 00:27:34,000 --> 00:27:36,760 Speaker 1: in terms of photons, and that's how things are basically glowing. 568 00:27:37,920 --> 00:27:42,919 Speaker 4: I see when things are excited, they release photons and 569 00:27:42,960 --> 00:27:44,520 Speaker 4: an explosion. Things are super. 570 00:27:44,280 --> 00:27:47,120 Speaker 1: Exciting, the way kids get excited in holidays and their 571 00:27:47,119 --> 00:27:47,879 Speaker 1: faces glow. 572 00:27:48,119 --> 00:27:51,280 Speaker 4: All right, well, I guess one question I had was 573 00:27:51,720 --> 00:27:55,280 Speaker 4: how does gunpowder relate to batpoop? Because I remember thinking 574 00:27:55,440 --> 00:27:58,359 Speaker 4: or hearing about how, you know, originally or maybe to 575 00:27:58,400 --> 00:28:01,879 Speaker 4: make fireworks or gunpower, you just need like bat poop, 576 00:28:02,000 --> 00:28:04,720 Speaker 4: guano or maybe seagull poop. I think I've heard that too. 577 00:28:04,960 --> 00:28:05,720 Speaker 4: It requires poop. 578 00:28:06,320 --> 00:28:10,040 Speaker 1: People used to mine guano because guano has exceptionally high 579 00:28:10,080 --> 00:28:14,440 Speaker 1: amounts of nitrogen, phosphate and potassium, and so you need 580 00:28:14,440 --> 00:28:18,119 Speaker 1: that potassium and that nitrogen to make gunpowder. So I 581 00:28:18,119 --> 00:28:20,760 Speaker 1: mean gunpowder is not like something you find underground. You 582 00:28:20,760 --> 00:28:24,000 Speaker 1: don't like mine gunpowder the way you mind. You know, salt, 583 00:28:24,080 --> 00:28:25,920 Speaker 1: for example, You have to put it together. It's a 584 00:28:25,960 --> 00:28:28,720 Speaker 1: chemical mixture of other various elements. You need to find 585 00:28:28,760 --> 00:28:33,000 Speaker 1: those ingredients to manufacture gunpowder. The bats basically have concentrated 586 00:28:33,040 --> 00:28:35,280 Speaker 1: a lot of these things for you and delivered it 587 00:28:35,280 --> 00:28:36,639 Speaker 1: to you in the form of poop. 588 00:28:37,000 --> 00:28:39,920 Speaker 4: That's super interesting, right, isn't it Like it's a biological 589 00:28:39,960 --> 00:28:43,280 Speaker 4: process that actually kind of makes gunpowder, right, I meaning 590 00:28:43,320 --> 00:28:45,400 Speaker 4: like their poop is kind of explosive. 591 00:28:45,040 --> 00:28:48,600 Speaker 1: Well, they're essential ingredients in gunpowder. It's not like they 592 00:28:48,640 --> 00:28:50,760 Speaker 1: have really you know, explosive arts or something like that. 593 00:28:52,880 --> 00:28:55,880 Speaker 4: Well, you don't know the bats that I do, but. 594 00:28:55,880 --> 00:28:57,760 Speaker 1: Yeah, these are essential ingredients. And you know, we rely 595 00:28:57,840 --> 00:29:01,720 Speaker 1: on biological processes all the time to capture energy to 596 00:29:01,760 --> 00:29:05,560 Speaker 1: produce chemicals that we find important. You know, basically everybody 597 00:29:05,600 --> 00:29:09,000 Speaker 1: on the planet is eating the results of biological processes 598 00:29:09,240 --> 00:29:11,520 Speaker 1: that have stripped out energy from the sun and taken 599 00:29:11,520 --> 00:29:15,640 Speaker 1: carbon dioxide and do this essential chemical processing for us. So, yeah, 600 00:29:15,840 --> 00:29:18,640 Speaker 1: we're all building on top of this huge pyramid of 601 00:29:18,680 --> 00:29:21,320 Speaker 1: photosynthesis and bapoop production. 602 00:29:21,560 --> 00:29:23,960 Speaker 4: Yeah, that's interesting. Yeah, I guess when you eat a solid, 603 00:29:24,000 --> 00:29:28,280 Speaker 4: you're kind of ingesting you know, pre packed energy packets, right, 604 00:29:28,320 --> 00:29:29,960 Speaker 4: prepacked by another biological being. 605 00:29:30,160 --> 00:29:33,520 Speaker 1: Yeah, exactly. It's this like pyramid of energy processing and 606 00:29:33,640 --> 00:29:36,520 Speaker 1: chemical conservation to take that energy and store it in 607 00:29:36,520 --> 00:29:39,320 Speaker 1: a useful way. And it's much more economically feasible and 608 00:29:39,440 --> 00:29:42,880 Speaker 1: easier to just gather this from biological processes than to 609 00:29:42,920 --> 00:29:45,760 Speaker 1: synthesize this in the laboratory in a pure way. That 610 00:29:45,800 --> 00:29:47,440 Speaker 1: could be done, but then you have to do the 611 00:29:47,440 --> 00:29:48,600 Speaker 1: bat's job for them. 612 00:29:48,880 --> 00:29:53,880 Speaker 4: Yeah, No, thanks. I wouldn't want to be, you know, 613 00:29:53,960 --> 00:29:54,640 Speaker 4: poop for a living. 614 00:29:54,680 --> 00:29:56,800 Speaker 1: I guess I think bats eat a lot of fruit, right, 615 00:29:56,880 --> 00:29:58,040 Speaker 1: so that doesn't sound too bad. 616 00:29:58,280 --> 00:30:01,200 Speaker 4: Oh, there you go, I guess I wouldn you know, 617 00:30:01,240 --> 00:30:07,440 Speaker 4: go to that fireworks display featuring fireworks made only from 618 00:30:07,960 --> 00:30:08,920 Speaker 4: a cartoonist poop. 619 00:30:09,920 --> 00:30:12,160 Speaker 1: No bats or cartoonists were hurt in the making of this. 620 00:30:12,160 --> 00:30:16,200 Speaker 4: Fires But anyways, one thing that's interesting here that you 621 00:30:16,200 --> 00:30:20,240 Speaker 4: wrote down is that gunpowder and firecrackers and fireworks in 622 00:30:20,280 --> 00:30:23,120 Speaker 4: general are slow explosives. What does that mean? 623 00:30:23,360 --> 00:30:26,520 Speaker 1: So the speed at which the explosion happens determines a 624 00:30:26,520 --> 00:30:28,360 Speaker 1: lot about how useful it is and what it can 625 00:30:28,360 --> 00:30:30,800 Speaker 1: be used for. HE and T and other related chemicals. 626 00:30:30,920 --> 00:30:34,760 Speaker 1: Those are actually more explosive, and so the speed at 627 00:30:34,760 --> 00:30:37,200 Speaker 1: which this thing blows up determines whether you're getting like 628 00:30:37,520 --> 00:30:41,240 Speaker 1: a big shock wave or a bang. And it's interesting 629 00:30:41,320 --> 00:30:44,480 Speaker 1: that black powder is better for fireworks because it blows 630 00:30:44,560 --> 00:30:47,400 Speaker 1: up more slowly than dynamite. 631 00:30:47,640 --> 00:30:49,520 Speaker 4: Yeah by a lot, right, Yeah, black. 632 00:30:49,400 --> 00:30:51,960 Speaker 1: Powder blows up at like one hundred yards per second, 633 00:30:52,000 --> 00:30:55,240 Speaker 1: that's the detonation velocity, and dynamite has a velocity of 634 00:30:55,240 --> 00:30:58,520 Speaker 1: detonation more than a thousand yards. Per second, so ten 635 00:30:58,640 --> 00:30:59,880 Speaker 1: times as strong. 636 00:31:00,280 --> 00:31:02,320 Speaker 4: Yeah, it's super interesting because you know, I think to 637 00:31:02,520 --> 00:31:05,680 Speaker 4: us as humans with our limited kind of capacity to 638 00:31:06,240 --> 00:31:08,840 Speaker 4: see things and perceive things, you know, to us, they're 639 00:31:08,880 --> 00:31:11,040 Speaker 4: both just explosions. But I guess if you had like 640 00:31:11,080 --> 00:31:14,440 Speaker 4: a super duper fast camera, you would see the difference 641 00:31:14,480 --> 00:31:18,000 Speaker 4: between a T and T explosion and a fireworks explosion, right, Like, 642 00:31:18,000 --> 00:31:20,320 Speaker 4: one of them would be ten times lower. So does 643 00:31:20,320 --> 00:31:23,520 Speaker 4: that mean that then firecracker explosions are less dangerous, but 644 00:31:23,560 --> 00:31:25,840 Speaker 4: they they'll still blow up your fingers, or if you 645 00:31:25,880 --> 00:31:27,880 Speaker 4: put enough of them, they'll still blow up a tank 646 00:31:27,920 --> 00:31:28,400 Speaker 4: for example. 647 00:31:28,480 --> 00:31:30,880 Speaker 1: Right, Yeah, they're both explosives, and you definitely don't want 648 00:31:30,920 --> 00:31:33,760 Speaker 1: to mess around with either of them. They're both definitely dangerous, 649 00:31:33,960 --> 00:31:36,840 Speaker 1: but they produce a different sort of character of explosion. 650 00:31:37,080 --> 00:31:39,240 Speaker 1: So you get like a longer duration of the explosion, 651 00:31:39,560 --> 00:31:41,520 Speaker 1: and I think you get a different mixture of light 652 00:31:41,640 --> 00:31:44,120 Speaker 1: and sound because the explosion is slower, so I think 653 00:31:44,160 --> 00:31:45,840 Speaker 1: there's more time for the stuff to heat up. 654 00:31:46,040 --> 00:31:48,920 Speaker 4: And I guess if it's faster too, it's also more destructive, 655 00:31:49,000 --> 00:31:52,000 Speaker 4: right Like, you're concentrating more energy in a smaller place, 656 00:31:52,040 --> 00:31:55,560 Speaker 4: which is probably better for you know, destroying things. 657 00:31:55,720 --> 00:31:57,600 Speaker 1: Yeah, when you want to like crack open a rock, 658 00:31:57,640 --> 00:31:59,800 Speaker 1: then you want to convert most of the energy into 659 00:31:59,840 --> 00:32:02,840 Speaker 1: high pressure waves, whereas with a firework, you don't want 660 00:32:02,880 --> 00:32:04,600 Speaker 1: to produce as much pressure because you don't want to 661 00:32:04,600 --> 00:32:06,560 Speaker 1: pop people's ear drums. So you want more of the 662 00:32:06,640 --> 00:32:09,800 Speaker 1: energy to produce bright flashes of light, which requires heating 663 00:32:09,800 --> 00:32:12,320 Speaker 1: this stuff up. So you actually want a lower explosion 664 00:32:12,400 --> 00:32:15,000 Speaker 1: velocity so that the stuff actually gets hotter. 665 00:32:15,520 --> 00:32:18,320 Speaker 4: Interesting. And so that's what a gunpowder is, and that's 666 00:32:18,360 --> 00:32:20,720 Speaker 4: what a firecracker is. You just take a bunch of gunpowder, 667 00:32:20,800 --> 00:32:22,560 Speaker 4: put it in a little package, and I guess have 668 00:32:22,640 --> 00:32:25,040 Speaker 4: an attach of fuse to it, right, which is really 669 00:32:25,080 --> 00:32:26,920 Speaker 4: just a string, And so when you light up the string, 670 00:32:27,000 --> 00:32:29,640 Speaker 4: the fire kind of travels along the string and then 671 00:32:29,640 --> 00:32:31,480 Speaker 4: eventually it hits the gunpowder. 672 00:32:31,800 --> 00:32:34,760 Speaker 1: And one nice thing about black powder and gunpowder is 673 00:32:34,760 --> 00:32:37,640 Speaker 1: that it's sort of insensitive to friction. Like if you 674 00:32:37,720 --> 00:32:39,680 Speaker 1: have a pile of it and it rubs against itself, 675 00:32:39,680 --> 00:32:42,160 Speaker 1: it doesn't just set itself off, which is good. You 676 00:32:42,200 --> 00:32:44,400 Speaker 1: want it to only blow when you want it to blow. 677 00:32:44,840 --> 00:32:46,560 Speaker 1: And so what that's what the fuse does, is it 678 00:32:46,600 --> 00:32:49,640 Speaker 1: delivers that first spark of energy to get the reaction going. 679 00:32:50,040 --> 00:32:52,400 Speaker 4: Right. Oh, I see, well, bifrictionating. I think you mean 680 00:32:52,480 --> 00:32:54,560 Speaker 4: like dropping it, Like you don't want to drop a 681 00:32:54,600 --> 00:32:57,479 Speaker 4: firecracker and have it explode. But like I think if 682 00:32:57,480 --> 00:33:00,000 Speaker 4: you drop a stick of TNT, it could blow up. 683 00:33:00,080 --> 00:33:02,600 Speaker 1: Right, Yeah, TNT is much less stable gunpowder if it 684 00:33:02,640 --> 00:33:05,160 Speaker 1: rubs against itself, won't blow up. You can blow up 685 00:33:05,200 --> 00:33:08,040 Speaker 1: gunpowder without a spark, right, you can just use percussion. 686 00:33:08,200 --> 00:33:11,320 Speaker 1: That's how gun works, right, black powder. Gunpowder is in 687 00:33:11,360 --> 00:33:13,320 Speaker 1: the back of the bullet, and then the hammer comes 688 00:33:13,320 --> 00:33:15,080 Speaker 1: back and hits the back of the bullet and that 689 00:33:15,120 --> 00:33:18,120 Speaker 1: actually sets off the gunpowder. So you can set off 690 00:33:18,120 --> 00:33:19,560 Speaker 1: gunpowder without a spark. 691 00:33:19,840 --> 00:33:22,400 Speaker 4: Oh. Interesting, Well, I think these days in bullets they 692 00:33:22,680 --> 00:33:25,000 Speaker 4: use a little like the back of the bullet has 693 00:33:25,040 --> 00:33:27,120 Speaker 4: something that causes a spark. But I think maybe you're 694 00:33:27,160 --> 00:33:29,880 Speaker 4: thinking like way before when they would use like they 695 00:33:29,920 --> 00:33:33,120 Speaker 4: would literally pour gunpowder into the gun. Then just hitting it, 696 00:33:33,200 --> 00:33:34,640 Speaker 4: hitting gunpowder makes it agnight. 697 00:33:34,840 --> 00:33:37,440 Speaker 1: Yeah, sunfire and guns just have a hammer, right, there's 698 00:33:37,440 --> 00:33:39,600 Speaker 1: no spark in a lot of those guns. There's a 699 00:33:39,680 --> 00:33:41,160 Speaker 1: huge range of technologies though. 700 00:33:41,360 --> 00:33:43,959 Speaker 4: All right, Well, those are firecrackers that kind of go 701 00:33:44,080 --> 00:33:47,360 Speaker 4: pop up up. But now let's talk about sparklers. I 702 00:33:47,360 --> 00:33:49,520 Speaker 4: think these are my favorite from when I was a kid. 703 00:33:49,840 --> 00:33:51,200 Speaker 4: I'm still a fan of sparklers. 704 00:33:51,360 --> 00:33:53,960 Speaker 1: Sparklers are super fun because you can hold them right. 705 00:33:54,120 --> 00:33:56,280 Speaker 1: It makes them feel much more immediate. Like a firecracker, 706 00:33:56,280 --> 00:33:58,080 Speaker 1: you set it and you run, it goes bang. But 707 00:33:58,160 --> 00:34:00,120 Speaker 1: a sparkleer you can hold it. You could wave it 708 00:34:00,160 --> 00:34:02,800 Speaker 1: around and you can like draw in the air with 709 00:34:02,840 --> 00:34:04,880 Speaker 1: a light. Because the impression stays in you're retina for 710 00:34:04,880 --> 00:34:07,000 Speaker 1: a while, and it also lasts for a while. You know, 711 00:34:07,040 --> 00:34:09,280 Speaker 1: it can burn for like thirty seconds or a minute. 712 00:34:09,360 --> 00:34:11,560 Speaker 1: So this is definitely one of my favorite childhood memories. 713 00:34:11,600 --> 00:34:14,200 Speaker 4: Also, yeah, they're pretty cool. And if you're not familiar, 714 00:34:14,239 --> 00:34:16,120 Speaker 4: I guess they're like a stick. There's usually like a 715 00:34:16,160 --> 00:34:18,800 Speaker 4: metal stick and the top half of it is covered 716 00:34:18,920 --> 00:34:22,399 Speaker 4: in some sort of gray stuff that makes it sort 717 00:34:22,440 --> 00:34:25,279 Speaker 4: of look like a corn dog. I guess, right, like 718 00:34:25,320 --> 00:34:27,920 Speaker 4: a great long corn dog. Although you don't know what 719 00:34:27,960 --> 00:34:29,919 Speaker 4: a sparkle looks like, you probably know what a corn 720 00:34:29,960 --> 00:34:30,600 Speaker 4: dog looks like. 721 00:34:30,680 --> 00:34:33,640 Speaker 1: Either, it looks really gross. It does not look like 722 00:34:33,680 --> 00:34:36,839 Speaker 1: a corn dog. It's like totally gray and metallic. It's 723 00:34:37,040 --> 00:34:38,520 Speaker 1: completely unappetizing. 724 00:34:38,680 --> 00:34:42,080 Speaker 4: Oh boy, did I just in salt corn dogs? Are 725 00:34:42,120 --> 00:34:43,320 Speaker 4: you a big fan of corn dogs? 726 00:34:43,360 --> 00:34:44,960 Speaker 1: It doesn't matter how much must did you put on 727 00:34:45,000 --> 00:34:46,560 Speaker 1: that thing, It's not gonna taste good. 728 00:34:47,440 --> 00:34:50,759 Speaker 4: It's gonna it's kinda sparkle though in your mouth. So 729 00:34:50,840 --> 00:34:53,240 Speaker 4: the way these works is that you take a sparkler 730 00:34:53,320 --> 00:34:54,920 Speaker 4: and then you light up one end, but it takes 731 00:34:55,000 --> 00:34:57,000 Speaker 4: it's sometimes it takes a while to light up, right Like, 732 00:34:57,040 --> 00:34:58,600 Speaker 4: It's not like you put the flame to it and 733 00:34:58,640 --> 00:35:00,640 Speaker 4: it immediately starts sparking and you kind of have to 734 00:35:00,680 --> 00:35:01,399 Speaker 4: wait a little bit. 735 00:35:01,719 --> 00:35:04,600 Speaker 1: It's not like a fuse that immediately goes. You got 736 00:35:04,640 --> 00:35:06,920 Speaker 1: to get it like hot enough to really start. And 737 00:35:06,920 --> 00:35:10,920 Speaker 1: a sparkler is sort of like a slow motion firecracker. 738 00:35:11,000 --> 00:35:13,920 Speaker 1: Like it's got the same basic material inside of it. Again, 739 00:35:14,000 --> 00:35:17,280 Speaker 1: it's black powder doing a lot of the work, releasing energy. 740 00:35:17,440 --> 00:35:20,040 Speaker 1: That's like the fuel that powers the sparkler. But then 741 00:35:20,080 --> 00:35:22,920 Speaker 1: it's got stuff inside of it which sparkles, and also 742 00:35:22,920 --> 00:35:25,840 Speaker 1: stuff that slows down the reaction, so it doesn't just 743 00:35:25,880 --> 00:35:27,120 Speaker 1: like blow your hand off. 744 00:35:27,520 --> 00:35:29,960 Speaker 4: Right, it's sort of diluted in a way, right, Like 745 00:35:30,000 --> 00:35:32,080 Speaker 4: that's the idea to slow it down. You mix it 746 00:35:32,120 --> 00:35:34,160 Speaker 4: with other things that don't explode exactly. 747 00:35:34,200 --> 00:35:37,960 Speaker 1: You modify this mixture of like potassium nitrate and sulfur 748 00:35:38,120 --> 00:35:41,520 Speaker 1: and charcoal so that you get a slower explosion. Sometimes 749 00:35:41,600 --> 00:35:45,080 Speaker 1: adding more sulfur or more charcoal reduces how fast the 750 00:35:45,120 --> 00:35:47,680 Speaker 1: oxygen is released, and so you can tinker with those 751 00:35:47,719 --> 00:35:50,600 Speaker 1: mixtures to get a different speed of the reaction essentially. 752 00:35:51,200 --> 00:35:54,120 Speaker 4: And then for the sparkler, you actually mix it with sugar, right, 753 00:35:54,120 --> 00:35:55,279 Speaker 4: Like there's sugar on that thing. 754 00:35:55,480 --> 00:35:57,600 Speaker 1: There is sugar in there. That's mostly just to hold 755 00:35:57,640 --> 00:35:59,759 Speaker 1: it together to make it like a goop and not 756 00:35:59,840 --> 00:36:02,640 Speaker 1: just like a powder. But the reason that it sparkles 757 00:36:02,800 --> 00:36:05,879 Speaker 1: is sort of weird. They have metal powder in there, 758 00:36:06,040 --> 00:36:08,839 Speaker 1: like you put aluminium or steel or something in there, 759 00:36:09,160 --> 00:36:12,080 Speaker 1: and then that steel gets really really hot and it 760 00:36:12,120 --> 00:36:14,719 Speaker 1: glows for the same reason we talked about earlier. You 761 00:36:14,719 --> 00:36:17,480 Speaker 1: take metal, you heat it up, it's gonna glow. And 762 00:36:17,560 --> 00:36:20,799 Speaker 1: so here you have metal powder which gets heated up, 763 00:36:20,800 --> 00:36:23,600 Speaker 1: and that's what's actually making those little sparkles that shoot out. 764 00:36:23,760 --> 00:36:27,920 Speaker 4: Oh interesting, the metal that heats it. Well, if there's 765 00:36:27,960 --> 00:36:32,000 Speaker 4: a central flame in the middle, right, and then that's 766 00:36:32,080 --> 00:36:34,759 Speaker 4: the big bright dot that you see in a sparkler, 767 00:36:34,880 --> 00:36:37,239 Speaker 4: but then there's other things shooting off of it, these 768 00:36:37,360 --> 00:36:42,000 Speaker 4: sparkles basically, and you're saying, the sparkles are metal that's 769 00:36:42,040 --> 00:36:45,000 Speaker 4: getting super heat up by this central kind of flame. 770 00:36:45,760 --> 00:36:49,720 Speaker 1: It's basically tiny bullets, right, A sparkler is shooting super 771 00:36:49,840 --> 00:36:52,560 Speaker 1: tiny little pellets of hot metal. It sounds like a 772 00:36:52,680 --> 00:36:54,880 Speaker 1: terrible idea, right now, give this to kids and let 773 00:36:54,920 --> 00:36:57,680 Speaker 1: them run around. But these things are so small they 774 00:36:57,719 --> 00:37:00,360 Speaker 1: burn up quickly and basically vaporize. But if you do 775 00:37:00,400 --> 00:37:02,719 Speaker 1: put your hand really close to a sparkler, you will 776 00:37:02,760 --> 00:37:05,319 Speaker 1: feel these tiny little hot pellets hitting your hand. It's 777 00:37:05,360 --> 00:37:06,320 Speaker 1: not a great idea. 778 00:37:06,400 --> 00:37:09,200 Speaker 4: Well, what's interesting is sometimes it sort of looks like 779 00:37:09,239 --> 00:37:12,400 Speaker 4: almost like a snowflake pattern, right Like you'll see a 780 00:37:12,520 --> 00:37:15,759 Speaker 4: big stream of sparkle and then that will divide, and 781 00:37:15,760 --> 00:37:18,239 Speaker 4: then those people then divide in itself, making sort of 782 00:37:18,280 --> 00:37:21,760 Speaker 4: like this beautiful tree like almost snowflake like pattern. 783 00:37:22,120 --> 00:37:24,120 Speaker 1: It's sort of like fractals, right They heat breaking down 784 00:37:24,160 --> 00:37:26,799 Speaker 1: into smaller and smaller pieces, and that's those little bits 785 00:37:26,840 --> 00:37:29,120 Speaker 1: of metal getting heated up, and if they're big enough, 786 00:37:29,160 --> 00:37:32,040 Speaker 1: they'll split in half before they completely vaporize, and then 787 00:37:32,040 --> 00:37:35,080 Speaker 1: maybe split in half again. You get these really cool patterns, 788 00:37:35,400 --> 00:37:38,200 Speaker 1: and they're aphemarol, right. They don't last very long. It 789 00:37:38,239 --> 00:37:40,759 Speaker 1: all happens very very quickly, but long enough for the 790 00:37:40,760 --> 00:37:42,880 Speaker 1: pattern to remain in your eye. So it's really a 791 00:37:42,920 --> 00:37:43,720 Speaker 1: beautiful effect. 792 00:37:43,840 --> 00:37:45,640 Speaker 4: And I guess, why does it need to be metal 793 00:37:46,120 --> 00:37:49,680 Speaker 4: that heats up? Like why does metal give off light 794 00:37:49,760 --> 00:37:52,560 Speaker 4: when it gets heat up more than other things like carbon? 795 00:37:52,719 --> 00:37:55,320 Speaker 1: That's a good question. I think you use metal because 796 00:37:55,360 --> 00:37:58,279 Speaker 1: it doesn't burn, right, It just heats up and vaporizes, 797 00:37:58,680 --> 00:38:00,879 Speaker 1: so like absorbs the energy and then gives it off 798 00:38:00,920 --> 00:38:04,560 Speaker 1: as light rather than like contributing to the explosion itself. 799 00:38:05,120 --> 00:38:08,040 Speaker 1: So it's fairly inert that way. Chemically, it's not getting modified. 800 00:38:08,040 --> 00:38:09,879 Speaker 1: It's just getting heated up and vaporized. 801 00:38:10,040 --> 00:38:13,360 Speaker 4: Cool, all right. Well, and so you hear it from Daniel, 802 00:38:13,480 --> 00:38:17,319 Speaker 4: sparklers have sugar in them, so I'm just kidding. They 803 00:38:17,560 --> 00:38:20,160 Speaker 4: don't give them a dry and don't put your head 804 00:38:20,160 --> 00:38:22,600 Speaker 4: and you're too close to one if you're a little child. 805 00:38:23,360 --> 00:38:25,960 Speaker 4: We just give them bad advice here today, Daniel. But 806 00:38:26,000 --> 00:38:28,200 Speaker 4: they are super fun and they are super cool. And 807 00:38:28,200 --> 00:38:29,600 Speaker 4: so the next time you look at one, you know, 808 00:38:29,840 --> 00:38:32,839 Speaker 4: think about all the processes that are going on in there. Right, 809 00:38:32,880 --> 00:38:35,680 Speaker 4: Let's get into now how farworks. The big ones, the 810 00:38:35,680 --> 00:38:38,520 Speaker 4: ones that light up the sky and have all these 811 00:38:38,560 --> 00:38:41,840 Speaker 4: amazing displays and colors. How they work. 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Visit 880 00:42:14,400 --> 00:42:17,200 Speaker 1: us dairy dot com slash sustainability to learn more. 881 00:42:25,600 --> 00:42:28,520 Speaker 4: All right, we are celebrating I guess July fourth, Daniel. 882 00:42:28,560 --> 00:42:31,280 Speaker 4: This episode will come out around July fourth. 883 00:42:31,440 --> 00:42:34,640 Speaker 1: Mm hmmm, yeah, and all the summer holidays. You know, 884 00:42:34,680 --> 00:42:37,160 Speaker 1: in France this bestial day. And it feels like a 885 00:42:37,200 --> 00:42:40,120 Speaker 1: lot of cultures have a reason to set off fireworks 886 00:42:40,120 --> 00:42:40,279 Speaker 1: in the. 887 00:42:40,280 --> 00:42:42,719 Speaker 4: Summer, right right, Who doesn't love a good explosion? 888 00:42:44,000 --> 00:42:45,400 Speaker 1: The particle physicists in us. 889 00:42:45,400 --> 00:42:49,600 Speaker 4: All well, all right, I won't get into it anymore. 890 00:42:49,960 --> 00:42:53,000 Speaker 4: I'm a baiting you go backing and exploding, Daniel. 891 00:42:53,520 --> 00:42:56,000 Speaker 1: I'm just trolling you. 892 00:42:56,040 --> 00:42:57,960 Speaker 4: Make sure to call it the big smash in the 893 00:42:57,960 --> 00:43:00,160 Speaker 4: Big Bang, since it all means the same to you anyway, 894 00:43:00,880 --> 00:43:01,920 Speaker 4: Let's be more confusing. 895 00:43:02,160 --> 00:43:02,640 Speaker 1: Sounds good. 896 00:43:03,960 --> 00:43:06,640 Speaker 4: How about the small the small smash. It needs to 897 00:43:06,719 --> 00:43:08,880 Speaker 4: be extra extra confusing. 898 00:43:10,640 --> 00:43:13,000 Speaker 1: The micro smash that started it all, the. 899 00:43:13,000 --> 00:43:15,600 Speaker 4: Small smash, formerly known as the Big Bang. 900 00:43:17,440 --> 00:43:19,440 Speaker 1: That's what we need to change the name of something 901 00:43:19,480 --> 00:43:22,120 Speaker 1: everybody already knows the name of now, so that some 902 00:43:22,120 --> 00:43:24,959 Speaker 1: people can say, actually, it's now called. 903 00:43:27,400 --> 00:43:29,840 Speaker 4: Are you Are you mocking chemists or physicists with that? 904 00:43:30,000 --> 00:43:36,680 Speaker 1: Boys, physicists. I would never mock chemists because they're better 905 00:43:36,680 --> 00:43:39,080 Speaker 1: at making poison gas and bombs than I am. I 906 00:43:39,120 --> 00:43:39,520 Speaker 1: see right. 907 00:43:39,560 --> 00:43:41,480 Speaker 4: You don't want to lose that chemistry with them. But 908 00:43:41,560 --> 00:43:43,879 Speaker 4: all right, so now let's get into now. Fireworks. Now, 909 00:43:43,920 --> 00:43:45,960 Speaker 4: this is the question we started off at the beginning. 910 00:43:46,160 --> 00:43:48,000 Speaker 4: So these are the ones that most people think of, 911 00:43:48,239 --> 00:43:51,440 Speaker 4: you know, July fourth or Bestiel Day. They throw these 912 00:43:51,520 --> 00:43:53,560 Speaker 4: up in the sky, they light up the sky. There's 913 00:43:53,600 --> 00:43:56,319 Speaker 4: all kinds of colors. Nowadays there's all kinds of shapes too. 914 00:43:56,400 --> 00:43:59,840 Speaker 1: Yeah, they're very dramatic. And fireworks are basically a combination 915 00:43:59,880 --> 00:44:02,640 Speaker 1: of everything we've talked about so far. There's a combination 916 00:44:02,680 --> 00:44:06,319 Speaker 1: of sparklers and firecrackers and then all wrapped together in 917 00:44:06,400 --> 00:44:09,360 Speaker 1: a little mini rocket. One of the essential components in 918 00:44:09,400 --> 00:44:13,360 Speaker 1: fireworks are these things called stars, which again are not 919 00:44:13,440 --> 00:44:16,320 Speaker 1: the burning balls of plasma in the sky. There's something 920 00:44:16,360 --> 00:44:20,280 Speaker 1: totally different. They're like sparkler like stuff formed into little balls. 921 00:44:20,600 --> 00:44:23,480 Speaker 4: Oh interesting, you're seeing a firework. It's like a bunch 922 00:44:23,480 --> 00:44:25,680 Speaker 4: of sparklers stuffed in with an explosion. 923 00:44:25,800 --> 00:44:28,520 Speaker 1: Exactly when you see the firework in the sky and 924 00:44:28,520 --> 00:44:31,880 Speaker 1: you see it sparkling, it's a sparkler up there. And 925 00:44:31,960 --> 00:44:33,680 Speaker 1: so the way you make a firework is that you 926 00:44:33,719 --> 00:44:36,879 Speaker 1: pack a bunch of little balls of sparkler together into 927 00:44:36,880 --> 00:44:38,880 Speaker 1: a little tube, and then you also fill it with 928 00:44:38,920 --> 00:44:42,040 Speaker 1: black powder, which sprays all the sparklers out when it explodes, 929 00:44:42,239 --> 00:44:44,080 Speaker 1: and that's what makes your pattern in the sky. 930 00:44:44,400 --> 00:44:47,880 Speaker 4: Oh interesting, really, so I guess I mean, I'm not 931 00:44:47,920 --> 00:44:49,799 Speaker 4: saying you should do this, but you could do this, 932 00:44:49,920 --> 00:44:52,040 Speaker 4: Like if you put a bunch of sparklers in with 933 00:44:52,080 --> 00:44:54,279 Speaker 4: a firecracker. You could make your own firework kind of. 934 00:44:54,520 --> 00:44:57,520 Speaker 1: That's what a firework is exactly. It's just sparkler stuff 935 00:44:57,800 --> 00:45:01,080 Speaker 1: packed in with black powder those high precision in order 936 00:45:01,120 --> 00:45:02,919 Speaker 1: to get it to explode in just the right way 937 00:45:03,000 --> 00:45:05,279 Speaker 1: and at the right time, and then you also have 938 00:45:05,360 --> 00:45:08,200 Speaker 1: to somehow launch it up into the air. So it's 939 00:45:08,200 --> 00:45:10,440 Speaker 1: a bit of a complicated construction, but those are the 940 00:45:10,520 --> 00:45:13,160 Speaker 1: essential ingredients, black powder and sparkler stuff. 941 00:45:13,320 --> 00:45:15,319 Speaker 4: I see. Well, let's break it down. How does the 942 00:45:15,520 --> 00:45:19,320 Speaker 4: rocket launching part work. Is it like a rocket rocket? 943 00:45:19,520 --> 00:45:21,440 Speaker 1: No, it's more like a gun. You have like a 944 00:45:21,480 --> 00:45:24,719 Speaker 1: steel tube with black powder in the bottom, and then 945 00:45:24,719 --> 00:45:26,759 Speaker 1: the firework is sitting on top of that. So you 946 00:45:26,840 --> 00:45:29,160 Speaker 1: light some black powder in the bottom of the tube 947 00:45:29,200 --> 00:45:32,640 Speaker 1: and that explosion like a firecracker inside of it sets 948 00:45:32,680 --> 00:45:35,239 Speaker 1: off the firecracker to fly up into the sky and 949 00:45:35,320 --> 00:45:38,200 Speaker 1: at the same time lights the fuse at the bottom 950 00:45:38,239 --> 00:45:40,719 Speaker 1: of it. So that's how you launch the thing up. 951 00:45:40,840 --> 00:45:42,040 Speaker 1: It's just like a little gun. 952 00:45:42,400 --> 00:45:44,040 Speaker 4: Oh, but it's not like a gun. Like, it's not 953 00:45:44,080 --> 00:45:47,200 Speaker 4: an explosion that propels it upward. Right, It's more like 954 00:45:47,239 --> 00:45:49,719 Speaker 4: a controlled you know, like a real rocket, right, Like, 955 00:45:49,760 --> 00:45:52,560 Speaker 4: it's not like a big bang. It's like a show, right, 956 00:45:52,960 --> 00:45:56,280 Speaker 4: like it has to you know, expel the propellant slowly 957 00:45:56,440 --> 00:45:56,759 Speaker 4: kind of. 958 00:45:56,840 --> 00:45:59,000 Speaker 1: Well, no, the explosion happens at the bottom of the tube. 959 00:45:59,000 --> 00:46:01,960 Speaker 1: It's like a mortar, right, and that explosion pushes the 960 00:46:02,000 --> 00:46:04,759 Speaker 1: firework up. It's not like the firework is burning on 961 00:46:04,880 --> 00:46:07,319 Speaker 1: its way up and pushing itself up. It's more like 962 00:46:07,360 --> 00:46:10,960 Speaker 1: it's gotten thrown up. It's on a projectile motion, just 963 00:46:11,000 --> 00:46:13,719 Speaker 1: from the initial explosion that pushed it out of the tube. 964 00:46:13,960 --> 00:46:16,960 Speaker 1: A rocket has like continuous burning that's pushing it up 965 00:46:17,040 --> 00:46:20,160 Speaker 1: as thrust, but a firework doesn't. It's just like thrown 966 00:46:20,239 --> 00:46:22,040 Speaker 1: up by this tube, more like a mortar. 967 00:46:22,280 --> 00:46:24,120 Speaker 4: Well, maybe that's some of them, right, I think some 968 00:46:24,160 --> 00:46:26,040 Speaker 4: of them, how do use sort of a rocket like 969 00:46:26,080 --> 00:46:26,800 Speaker 4: a thing doing. 970 00:46:26,920 --> 00:46:29,239 Speaker 1: Yeah, you can definitely buy some fireworks that you can 971 00:46:29,320 --> 00:46:32,719 Speaker 1: light off yourself that are like bottle rockets, right, that 972 00:46:32,760 --> 00:46:35,279 Speaker 1: are propelled by those the kind I'm thinking about, you know, 973 00:46:35,320 --> 00:46:37,400 Speaker 1: the big ones you see at the displays. Those are 974 00:46:37,440 --> 00:46:40,200 Speaker 1: almost all just projectiles that are fired up by an 975 00:46:40,239 --> 00:46:43,439 Speaker 1: initial explosion. But yeah, there are some versions that are 976 00:46:43,480 --> 00:46:46,200 Speaker 1: like more like rockets that have a continuous explosion. 977 00:46:46,400 --> 00:46:48,440 Speaker 4: Hmmm, I see well, I guess it's it's going to 978 00:46:48,480 --> 00:46:52,440 Speaker 4: be tricky because you want to explode something or rocket 979 00:46:52,480 --> 00:46:54,520 Speaker 4: something at the bottom, but you don't want it to somehow, 980 00:46:54,960 --> 00:46:58,279 Speaker 4: you know, burn up your gunpowder and sparklers that are 981 00:46:58,320 --> 00:46:59,080 Speaker 4: at the front. 982 00:46:59,120 --> 00:47:02,520 Speaker 1: Exactly so very carefully, and they have like multiple stages, 983 00:47:02,840 --> 00:47:05,920 Speaker 1: and they have fuses that have time delays, so they 984 00:47:05,920 --> 00:47:09,239 Speaker 1: have materials that burn at very well known rates. So 985 00:47:09,280 --> 00:47:11,480 Speaker 1: you light this fuse and you have like four seconds 986 00:47:11,600 --> 00:47:13,520 Speaker 1: before it gets to the top of the firework and 987 00:47:13,600 --> 00:47:15,120 Speaker 1: sets off the rest of it. So you're right, it's 988 00:47:15,120 --> 00:47:16,560 Speaker 1: a very delicately balanced system. 989 00:47:16,640 --> 00:47:18,200 Speaker 4: Yeah, and it's interesting what you said. You get to 990 00:47:18,239 --> 00:47:21,200 Speaker 4: time it right because you want the fireworks to explode 991 00:47:21,239 --> 00:47:23,919 Speaker 4: and give you all the sparkles, like at the very top, 992 00:47:24,000 --> 00:47:26,040 Speaker 4: not as it's going up or right as soon as 993 00:47:26,080 --> 00:47:26,759 Speaker 4: it takes off. 994 00:47:26,880 --> 00:47:28,880 Speaker 1: Yeah, And some of these things happen like two or 995 00:47:28,960 --> 00:47:31,839 Speaker 1: three different stages, so they'll blow up once and then 996 00:47:31,840 --> 00:47:33,480 Speaker 1: they'll blow up again at the top, and then on 997 00:47:33,520 --> 00:47:35,920 Speaker 1: the way down they blow up one more time. So 998 00:47:36,000 --> 00:47:38,640 Speaker 1: people have gotten really advanced with the technology for how 999 00:47:38,640 --> 00:47:41,239 Speaker 1: to put these things together to make the most spectacular 1000 00:47:41,239 --> 00:47:43,640 Speaker 1: displays in the sky. But it's all about how you 1001 00:47:43,640 --> 00:47:46,839 Speaker 1: package this stuff so the explosions happen at the right time. Right. 1002 00:47:46,880 --> 00:47:49,000 Speaker 4: They can even make things like a smiley face. Right, 1003 00:47:49,080 --> 00:47:50,800 Speaker 4: they can make a firework that blows up into a 1004 00:47:50,840 --> 00:47:51,439 Speaker 4: smiley face. 1005 00:47:51,640 --> 00:47:54,000 Speaker 1: Yeah, you can. You can make all sorts of crazy shapes. 1006 00:47:54,360 --> 00:47:57,000 Speaker 1: And the way they do this is by very carefully 1007 00:47:57,120 --> 00:48:01,720 Speaker 1: arranging those stars, these pieces of spararkler inside that tube 1008 00:48:02,160 --> 00:48:04,600 Speaker 1: and arranging the black powder around them in just the 1009 00:48:04,680 --> 00:48:07,120 Speaker 1: right way, so when it blows up from the center, 1010 00:48:07,320 --> 00:48:09,719 Speaker 1: it ends up shooting those things out in just that 1011 00:48:09,800 --> 00:48:11,759 Speaker 1: right pattern, because when that black powder goes off, it 1012 00:48:11,800 --> 00:48:14,600 Speaker 1: then sets off the sparklers, which then glow. But it 1013 00:48:14,640 --> 00:48:17,680 Speaker 1: must take a lot of experimentation exactly how to arrange 1014 00:48:17,760 --> 00:48:20,800 Speaker 1: those stars inside the fireworks to give you that reaction. 1015 00:48:21,160 --> 00:48:23,279 Speaker 1: I imagine they must fail a lot that or they 1016 00:48:23,280 --> 00:48:26,399 Speaker 1: have done some like really complicated computer simulations to figure 1017 00:48:26,400 --> 00:48:27,880 Speaker 1: out exactly how to build these things. 1018 00:48:28,320 --> 00:48:30,200 Speaker 4: Hmm interesting. What do you think it is? 1019 00:48:30,280 --> 00:48:31,880 Speaker 1: Well, I think these things have been around for a 1020 00:48:31,880 --> 00:48:34,680 Speaker 1: lot longer than fancy computers, so initially it must have 1021 00:48:34,760 --> 00:48:36,920 Speaker 1: just been trial and error. You know, people like had 1022 00:48:36,920 --> 00:48:39,520 Speaker 1: an artistic skill at this, you know, coming up with 1023 00:48:39,640 --> 00:48:42,280 Speaker 1: clever things that you can do with your limited ability 1024 00:48:42,280 --> 00:48:45,880 Speaker 1: to arrange the stars inside the fireworks, and then people 1025 00:48:45,920 --> 00:48:48,960 Speaker 1: being creative and discovering new stuff these days. I bet 1026 00:48:49,000 --> 00:48:51,280 Speaker 1: they could use computers, but I'm not sure if anybody's 1027 00:48:51,320 --> 00:48:51,600 Speaker 1: doing that. 1028 00:48:51,840 --> 00:48:53,800 Speaker 4: Yeah, I guess you. You know, to get a circle, 1029 00:48:54,000 --> 00:48:56,040 Speaker 4: for example, for a smiless phase, you just kind of 1030 00:48:56,120 --> 00:49:00,480 Speaker 4: arrange the sparklers in a circle around your explosion, right explosive, 1031 00:49:00,600 --> 00:49:02,440 Speaker 4: and then when it blows up, it'll come out in 1032 00:49:02,480 --> 00:49:02,960 Speaker 4: the circle. 1033 00:49:03,560 --> 00:49:05,279 Speaker 1: And if what you want is a heart, then you 1034 00:49:05,320 --> 00:49:07,040 Speaker 1: move some of those a little bit further away and 1035 00:49:07,040 --> 00:49:09,200 Speaker 1: some of those a little closer in so they burn 1036 00:49:09,280 --> 00:49:11,440 Speaker 1: up sooner. And some of these things are not like 1037 00:49:11,520 --> 00:49:14,080 Speaker 1: a circle or a heart, they're like a big flower, 1038 00:49:14,200 --> 00:49:16,400 Speaker 1: like a chrysanthemum, right, And for that you just have 1039 00:49:16,520 --> 00:49:18,080 Speaker 1: like stars everywhere. 1040 00:49:17,920 --> 00:49:20,359 Speaker 4: All right. So then how do the colors work? How 1041 00:49:20,360 --> 00:49:22,480 Speaker 4: do you get different colors of sparklers? 1042 00:49:22,960 --> 00:49:25,480 Speaker 1: So the colors come from the different kinds of metal 1043 00:49:25,600 --> 00:49:28,960 Speaker 1: inside the sparkler. Remember the reason the sparkl or sparkle 1044 00:49:29,040 --> 00:49:31,680 Speaker 1: is because you have metal powder. That metal gets really 1045 00:49:31,719 --> 00:49:34,319 Speaker 1: hot and then it glows. But these metals are made 1046 00:49:34,320 --> 00:49:36,840 Speaker 1: of different elements, so they tend to glow at different 1047 00:49:36,840 --> 00:49:39,839 Speaker 1: frequencies because these metals have different energy levels that they 1048 00:49:39,920 --> 00:49:43,240 Speaker 1: like to release photons at. So different kinds of metals 1049 00:49:43,239 --> 00:49:45,800 Speaker 1: will glow in different colors. And you know, for example, 1050 00:49:45,840 --> 00:49:48,680 Speaker 1: if you sprinkle copper powder into a flame, the flame 1051 00:49:48,719 --> 00:49:52,200 Speaker 1: turns green, and so different metals give you different colors. 1052 00:49:52,960 --> 00:49:55,200 Speaker 4: Where does that come from? I guess, I guess because 1053 00:49:55,280 --> 00:49:59,200 Speaker 4: when the photon comes out of the metal, that comes 1054 00:49:59,200 --> 00:50:02,719 Speaker 4: with a specific frequency which is related to its energy. 1055 00:50:02,800 --> 00:50:04,560 Speaker 1: Just like if you look at a star, you can 1056 00:50:04,600 --> 00:50:07,440 Speaker 1: tell what it's made out of based on the frequency 1057 00:50:07,440 --> 00:50:09,719 Speaker 1: of light that's coming to you from the star. And 1058 00:50:09,760 --> 00:50:13,680 Speaker 1: that's because different elements glow with different fingerprints, and that 1059 00:50:13,719 --> 00:50:16,399 Speaker 1: comes from the energy levels of the electrons going around 1060 00:50:16,440 --> 00:50:19,880 Speaker 1: the atom, and also, in more complicated situations, from rotational 1061 00:50:19,960 --> 00:50:23,000 Speaker 1: or vibrational modes of a molecule. But usually it's just 1062 00:50:23,040 --> 00:50:25,080 Speaker 1: from the energy levels of the atom, and those are 1063 00:50:25,120 --> 00:50:27,840 Speaker 1: all different for different elements, and so you get different 1064 00:50:27,840 --> 00:50:29,800 Speaker 1: mixtures of colors for different elements. 1065 00:50:29,880 --> 00:50:32,520 Speaker 4: So for example, if I wanted an orange firework, what 1066 00:50:32,560 --> 00:50:33,120 Speaker 4: would I use? 1067 00:50:33,440 --> 00:50:35,000 Speaker 1: Then you'd use calcium. 1068 00:50:35,040 --> 00:50:37,200 Speaker 4: Calcium, Oh, that's a metal, right. 1069 00:50:38,440 --> 00:50:40,160 Speaker 1: And these things don't have to be metals, right, they 1070 00:50:40,239 --> 00:50:42,759 Speaker 1: just have to be elements that can accept heat and 1071 00:50:42,760 --> 00:50:44,160 Speaker 1: not participate in the reaction. 1072 00:50:44,320 --> 00:50:47,680 Speaker 4: Hmmm, what about like red red? 1073 00:50:47,800 --> 00:50:50,000 Speaker 1: You can either use lithium, which is going to give 1074 00:50:50,000 --> 00:50:52,400 Speaker 1: you like a medium red, or a strontium for like 1075 00:50:52,440 --> 00:50:53,839 Speaker 1: a really intense red. 1076 00:50:54,040 --> 00:50:56,280 Speaker 4: Oh cool. What are some other colors? 1077 00:50:56,360 --> 00:50:59,200 Speaker 1: So you can get like yellow from sodium or green 1078 00:50:59,280 --> 00:51:02,200 Speaker 1: from barium. Copper actually gives you more of a blue 1079 00:51:02,280 --> 00:51:06,040 Speaker 1: than a green. You can get violet from potassium or rubidium. 1080 00:51:06,320 --> 00:51:09,640 Speaker 1: You can even get gold colors from charcoal or iron. 1081 00:51:09,880 --> 00:51:12,920 Speaker 1: Things like aluminium or titanium tend to give you white. 1082 00:51:13,000 --> 00:51:14,560 Speaker 1: So you have a whole palette to play with if 1083 00:51:14,600 --> 00:51:16,400 Speaker 1: you're the person designing these fireworks. 1084 00:51:16,600 --> 00:51:21,120 Speaker 4: Interesting, it's almost like you're painting with materials, right, And. 1085 00:51:21,120 --> 00:51:23,320 Speaker 1: A lot of these things are made sort of by hand, 1086 00:51:24,000 --> 00:51:27,680 Speaker 1: like they are these fireworks masters that pack these things 1087 00:51:27,680 --> 00:51:31,320 Speaker 1: together and very carefully mix the ingredients to get exactly 1088 00:51:31,360 --> 00:51:35,160 Speaker 1: what they want, you know, magnesium or aluminium or whatever. 1089 00:51:35,760 --> 00:51:37,480 Speaker 1: And so they tend to make these things sort of 1090 00:51:37,480 --> 00:51:39,880 Speaker 1: by hand and cut them into these pieces. And that's 1091 00:51:39,920 --> 00:51:41,799 Speaker 1: why some of these things are very expensive because they're 1092 00:51:41,840 --> 00:51:43,960 Speaker 1: like fabricated by artisans. 1093 00:51:43,680 --> 00:51:48,120 Speaker 4: Whoa it's like organic, you know, artisan farworks. 1094 00:51:49,200 --> 00:51:51,600 Speaker 1: Somebody with like a wax mustache and a long beard 1095 00:51:51,719 --> 00:51:53,320 Speaker 1: is making this out in Brooklyn warehouse. 1096 00:51:53,360 --> 00:51:57,960 Speaker 4: Right now, you're assuming they're hipsters, so Farward hipsters. But 1097 00:51:58,040 --> 00:52:00,759 Speaker 4: I wonder if that's a stressful job, you know, with explosives, 1098 00:52:00,760 --> 00:52:03,160 Speaker 4: because you're you're sort of crafting this thing by hand. 1099 00:52:03,480 --> 00:52:05,360 Speaker 4: There was something that can explode at any moment. 1100 00:52:05,640 --> 00:52:07,080 Speaker 1: I'm sure they have good insurance. 1101 00:52:09,200 --> 00:52:11,680 Speaker 4: I don't know. Having good insurance it makes me want 1102 00:52:11,719 --> 00:52:15,640 Speaker 4: to do something dangerous. It's almost the opposite. If you 1103 00:52:15,719 --> 00:52:19,040 Speaker 4: need good insurance for something, maybe you shouldn't be doing it. 1104 00:52:19,200 --> 00:52:21,240 Speaker 1: Yeah, maybe not, But you know how it is. Everybody 1105 00:52:21,239 --> 00:52:23,840 Speaker 1: gets inspired by something different, and for some folks this 1106 00:52:23,960 --> 00:52:27,200 Speaker 1: must be like a deep passion. The mixture of chemistry 1107 00:52:27,320 --> 00:52:30,560 Speaker 1: and artistry together probably really satisfying for a lot of folks. 1108 00:52:30,640 --> 00:52:34,200 Speaker 1: And then you get to display your works, everybody goes ooh, right, 1109 00:52:34,320 --> 00:52:36,960 Speaker 1: almost everybody loves fireworks, so you must be very popular. 1110 00:52:37,000 --> 00:52:40,560 Speaker 4: That's right, almost everybody except you, I guess. But what 1111 00:52:40,640 --> 00:52:42,560 Speaker 4: about the ones that you know? Sometimes you see these 1112 00:52:42,600 --> 00:52:46,520 Speaker 4: like they explode and then the little bits explode themselves, 1113 00:52:46,560 --> 00:52:49,279 Speaker 4: you know, like like a multi tier explosion almost like 1114 00:52:49,320 --> 00:52:51,880 Speaker 4: it explodes and it gives us sparkles, but then the 1115 00:52:51,920 --> 00:52:55,640 Speaker 4: sparkles after a little bit, explode themselves into other colors. 1116 00:52:55,680 --> 00:52:56,279 Speaker 4: How do they do that? 1117 00:52:56,520 --> 00:52:58,719 Speaker 1: Yeah, that's all in the packaging. You can make, Like 1118 00:52:58,760 --> 00:53:02,040 Speaker 1: little cardboard packages have sparklers inside them, and they're surrounded 1119 00:53:02,080 --> 00:53:05,319 Speaker 1: by sparklers, and so initially the outside sparklers go and 1120 00:53:05,360 --> 00:53:07,600 Speaker 1: then when those burn after a while, they heat up 1121 00:53:07,640 --> 00:53:10,080 Speaker 1: what's inside, which can then burn. So it's all about 1122 00:53:10,120 --> 00:53:13,120 Speaker 1: timing these multi stage reactions. You do that based on 1123 00:53:13,200 --> 00:53:15,480 Speaker 1: how you're packaging this firework. 1124 00:53:15,400 --> 00:53:17,319 Speaker 4: Right, right, And something interesting you just said is that 1125 00:53:17,360 --> 00:53:19,560 Speaker 4: these things are made out of cardboard, right, Like you 1126 00:53:20,000 --> 00:53:22,600 Speaker 4: kind of have to make them out of materials that 1127 00:53:22,760 --> 00:53:25,439 Speaker 4: burn up, right, Like, you can't make a farwork put 1128 00:53:25,520 --> 00:53:27,480 Speaker 4: like a steel too or a steal plate on it, 1129 00:53:27,520 --> 00:53:29,359 Speaker 4: because that thing's going to fall back down and maybe 1130 00:53:29,400 --> 00:53:31,600 Speaker 4: hurt somebody. Everything has to be made out of paper. 1131 00:53:31,800 --> 00:53:33,399 Speaker 1: And it has to be the right strength to hold 1132 00:53:33,440 --> 00:53:36,759 Speaker 1: the stuff together, but not so strong that it can't explode, right, 1133 00:53:36,800 --> 00:53:39,319 Speaker 1: And so cardboard and paper is actually just about the 1134 00:53:39,360 --> 00:53:40,040 Speaker 1: perfect strength. 1135 00:53:40,120 --> 00:53:42,520 Speaker 4: Wow, So you need to be like a paper artisan too. 1136 00:53:44,440 --> 00:53:46,719 Speaker 1: Yeah, I don't think we're like three D printing fireworks 1137 00:53:46,800 --> 00:53:47,200 Speaker 1: or anything. 1138 00:53:47,320 --> 00:53:52,440 Speaker 4: Ooh, but not yet. You just came up with an 1139 00:53:52,440 --> 00:53:54,520 Speaker 4: interesting idea there. I wonder if you can get more 1140 00:53:54,520 --> 00:53:57,120 Speaker 4: precise sculptures if if you do three D print them. 1141 00:53:57,200 --> 00:53:59,400 Speaker 1: Yeah, you might be able to guide the sparklers and 1142 00:53:59,440 --> 00:54:01,719 Speaker 1: exactly they're right direction. You could have like tubes or 1143 00:54:01,760 --> 00:54:03,960 Speaker 1: sparkler guides or something that they get them to do 1144 00:54:04,000 --> 00:54:07,360 Speaker 1: crazy stuff. I think three D printing and computer modeling 1145 00:54:07,480 --> 00:54:09,799 Speaker 1: probably the future of artisanal fireworks. 1146 00:54:10,200 --> 00:54:13,360 Speaker 4: Wow. Yeah, you could have like a firework that explodes 1147 00:54:13,360 --> 00:54:15,600 Speaker 4: into a photo of your face or something. 1148 00:54:15,800 --> 00:54:18,920 Speaker 1: Yeah, or the cat video that everybody's been wandering and 1149 00:54:18,960 --> 00:54:19,600 Speaker 1: waiting for. 1150 00:54:19,840 --> 00:54:23,719 Speaker 4: Oh my gosh, that would be next level, like animated fireworks. 1151 00:54:23,719 --> 00:54:26,120 Speaker 4: Can you imagine like fireworks and move? 1152 00:54:26,320 --> 00:54:27,600 Speaker 1: Yeah, that would be pretty incredible. 1153 00:54:27,680 --> 00:54:29,120 Speaker 4: Sounds like something out of Harry Potter. 1154 00:54:29,200 --> 00:54:31,239 Speaker 1: Maybe, Yeah, four D fireworks. 1155 00:54:31,320 --> 00:54:33,239 Speaker 4: Well, nowadays it kind of seems like the future of 1156 00:54:33,280 --> 00:54:36,399 Speaker 4: these displays are drones. They're using drones more and more 1157 00:54:36,440 --> 00:54:38,640 Speaker 4: and they're almost kind of as And you can do 1158 00:54:38,760 --> 00:54:40,520 Speaker 4: cat videos with drones. 1159 00:54:40,280 --> 00:54:42,880 Speaker 1: Yeah, you actually can. And they're not explosive and they 1160 00:54:42,920 --> 00:54:46,000 Speaker 1: don't release toxic chemicals into the air and nobody gets 1161 00:54:46,000 --> 00:54:49,040 Speaker 1: blown up. So drones are pretty nice alternative there, like. 1162 00:54:48,960 --> 00:54:54,600 Speaker 4: The green alternative to artisical organic fireworks. They got out greened. 1163 00:54:54,800 --> 00:54:57,279 Speaker 1: And I love a fireworks display like anybody else. The 1164 00:54:57,320 --> 00:54:59,760 Speaker 1: thing that I wonder sometimes when I watch fireworks displace 1165 00:55:00,120 --> 00:55:02,960 Speaker 1: is all those people taking videos of fireworks displace. I'm 1166 00:55:02,960 --> 00:55:06,240 Speaker 1: always wondering, like, what percentage of those videos is anybody 1167 00:55:06,280 --> 00:55:07,080 Speaker 1: ever watching? 1168 00:55:08,200 --> 00:55:11,520 Speaker 4: Well, you can ask about any video ever taking, Daniel. 1169 00:55:11,880 --> 00:55:13,880 Speaker 4: If you take a video of your kid eating a 1170 00:55:13,880 --> 00:55:17,319 Speaker 4: pizza slice, you know you're not gonna watching that later, 1171 00:55:17,440 --> 00:55:18,720 Speaker 4: but you want to capture the moment. 1172 00:55:18,960 --> 00:55:21,600 Speaker 1: I do go back and watch silly videos of everyday 1173 00:55:21,600 --> 00:55:24,080 Speaker 1: moments of my kids back when they were really young, 1174 00:55:24,120 --> 00:55:26,719 Speaker 1: and I think, all that's nice to get transported back 1175 00:55:26,760 --> 00:55:29,360 Speaker 1: to that day, you remember what they were like. But 1176 00:55:29,400 --> 00:55:32,279 Speaker 1: I don't watch fireworks videos, you know, with nobody in them, 1177 00:55:32,280 --> 00:55:34,520 Speaker 1: and go, oh, yeah, I remember that explosion that was 1178 00:55:34,600 --> 00:55:35,240 Speaker 1: really cool. 1179 00:55:35,600 --> 00:55:40,640 Speaker 4: M Well that's because your fireworks grump, Daniel. Nobody would 1180 00:55:40,640 --> 00:55:43,080 Speaker 4: explain you to where he'd watched something something you don't like. 1181 00:55:44,600 --> 00:55:46,840 Speaker 4: Find more people would probably say ooh to that video 1182 00:55:46,920 --> 00:55:48,720 Speaker 4: than your kids eating pizza. 1183 00:55:48,880 --> 00:55:51,399 Speaker 1: Honestly, if I invited people over there probably rather see 1184 00:55:51,400 --> 00:55:53,719 Speaker 1: a fireworks video than an old video of my kids 1185 00:55:53,760 --> 00:55:54,280 Speaker 1: eating pizza. 1186 00:55:54,360 --> 00:55:56,520 Speaker 4: Yeah, especially your kids didn't want to see that stuff. 1187 00:55:57,840 --> 00:56:00,360 Speaker 4: All right, Well, that was an explosive conversation, full of 1188 00:56:00,800 --> 00:56:01,920 Speaker 4: sparkling conversation. 1189 00:56:02,200 --> 00:56:04,680 Speaker 1: Yeah, and we hope that illuminated for you how people 1190 00:56:04,719 --> 00:56:07,839 Speaker 1: have been using physics and chemistry to brighten up their 1191 00:56:07,880 --> 00:56:11,120 Speaker 1: lives and their celebrations even before they understood how it worked. 1192 00:56:11,160 --> 00:56:14,000 Speaker 4: And I hope that confluence of physics and chemistry I 1193 00:56:14,040 --> 00:56:16,719 Speaker 4: really add a little pop to your day there or night. 1194 00:56:16,960 --> 00:56:19,319 Speaker 1: And I hope my dis days for fireworks doesn't blow 1195 00:56:19,400 --> 00:56:20,280 Speaker 1: up your experience. 1196 00:56:20,560 --> 00:56:23,799 Speaker 4: What's not to like, Daniel. They're big, they're explosive, and 1197 00:56:23,800 --> 00:56:26,600 Speaker 4: they're bright, sort of like the universe, right, the big 1198 00:56:26,600 --> 00:56:27,920 Speaker 4: smash exactly? 1199 00:56:28,320 --> 00:56:29,239 Speaker 1: All right, I give up? 1200 00:56:29,280 --> 00:56:29,560 Speaker 9: You win? 1201 00:56:30,719 --> 00:56:33,160 Speaker 4: Yes, all right, Well, we hope you enjoyed that. Thanks 1202 00:56:33,160 --> 00:56:35,279 Speaker 4: for joining us, and we hope that next time you 1203 00:56:35,280 --> 00:56:37,440 Speaker 4: look up at the fireworks display you kind of think 1204 00:56:37,440 --> 00:56:40,759 Speaker 4: about all of the physics and chemistry that's going on then, 1205 00:56:40,880 --> 00:56:44,520 Speaker 4: all the artisanal skill that went into making those fireworks. 1206 00:56:44,080 --> 00:56:47,400 Speaker 1: And how a happy summer fireworks season everybody, and stay safe. 1207 00:56:47,440 --> 00:56:50,640 Speaker 4: Yeah, take a video and send it to Daniel. We're 1208 00:56:50,680 --> 00:56:51,440 Speaker 4: haad to enjoy it. 1209 00:56:51,520 --> 00:56:53,279 Speaker 1: I'll edit them all together and put them on my 1210 00:56:53,320 --> 00:56:55,439 Speaker 1: website for somebody to download and watch. 1211 00:56:55,480 --> 00:56:59,640 Speaker 4: Twelve hours of fireworks. That does sound pretty good. I 1212 00:56:59,640 --> 00:57:02,080 Speaker 4: think that's called the screen saver. Maybe I think they 1213 00:57:02,080 --> 00:57:05,239 Speaker 4: invented that already. Anyways, Thanks for joining us, see you 1214 00:57:05,239 --> 00:57:05,640 Speaker 4: next time. 1215 00:57:13,520 --> 00:57:16,320 Speaker 1: Thanks for listening, and remember that Daniel and Jorge explain 1216 00:57:16,400 --> 00:57:20,360 Speaker 1: the Universe is a production of iHeartRadio. For more podcasts 1217 00:57:20,400 --> 00:57:25,040 Speaker 1: from iHeartRadio, visit the iHeartRadio app, Apple Podcasts, or wherever 1218 00:57:25,120 --> 00:57:38,640 Speaker 1: you listen to your favorite shows. When you pop a 1219 00:57:38,640 --> 00:57:40,920 Speaker 1: piece of cheese into your mouth, you're probably not thinking 1220 00:57:40,960 --> 00:57:43,880 Speaker 1: about the environmental impact. But the people in the dairy 1221 00:57:43,880 --> 00:57:47,040 Speaker 1: industry are. 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